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材料导报  2026, Vol. 40 Issue (8): 25030039-10    https://doi.org/10.11896/cldb.25030039
  金属与金属基复合材料 |
低温回火的SIMP钢在铅铋共晶合金下的液态金属脆化敏感性研究
张洁1, 秦博1,2, 付晓刚1, 龙斌1,2,*
1 中国原子能科学研究院反应堆工程技术研究所,北京 102413
2 国家原子能机构核材料创新中心,北京 102413
Study on Embrittlement Sensitivity of SIMP Tempered at Low Temperature in Liquid Metal Under Lead-Bismuth Eutectic Alloy
ZHANG Jie1, QIN Bo1,2, FU Xiaogang1, LONG Bin1,2,*
1 Department of Reactor Engineering and Technology, China Institute of Atomic Energy, Beijing 102413, China
2 Innovation Center of Nuclear Materials, China Atomic Energy Authority, Beijing 102413, China
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摘要 本研究聚焦于含硅铁素体/马氏体钢SIMP钢,着力探究铅铋共晶合金(LBE)的温度与应变速率如何对其液态金属脆化效应(LME)敏感性产生影响,揭示背后的作用机制。研究采用经过较低回火温度(500 ℃)处理的SIMP钢,以此模拟辐照硬化状态,进而获取硬化后材料在LBE环境中的LME敏感性。通过在不同温度的氩气和饱和氧LBE环境中,以不同应变速率对低温回火(500 ℃)的SIMP钢开展慢应变速率拉伸试验(SSRT),并与正常回火(760 ℃)的SIMP钢进行对比分析。研究结果表明,500 ℃回火后的试样在350 ℃和400 ℃的LBE中呈现出显著的LME效应,具体表现为总断裂伸长率显著降低以及断口表面呈现准解理断裂特征;而当温度升高至550 ℃时,试样的总断裂伸长率完全恢复,断口呈现韧性断裂,表明此时LME现象消失。此外,正常回火(760 ℃)的SIMP钢在相同试验条件下未出现LME现象。同时,针对应变速率对 500 ℃回火的SIMP钢LME敏感性的影响规律研究发现,在低应变速率(2×10-6 s-1)和高应变速率(1×10-5 s-1)时均会发生LME,但低应变速率下LME敏感性更高。研究结论为深入理解SIMP钢在LBE环境中的服役性能提供了重要依据。
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张洁
秦博
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龙斌
关键词:  SIMP钢  液态金属脆化  铅铋共晶合金  慢应变速率拉伸测试    
Abstract: This work systematically examines the effects of temperature and strain rate on liquid metal embrittlement (LME) susceptibility of silicon-enhanced ferritic/martensitic SIMP steel in lead-bismuth eutectic (LBE) environments, with emphasis on elucidating the underlying mechanisms. To simulate irradiation-induced hardening, SIMP steel was tempered at 500 ℃, a reduced temperature compared to conventional proces-sing. Slow strain rate tensile (SSRT) tests were conducted on 500 ℃-tempered specimens in both argon and oxygen-saturated LBE at temperatures ranging from 350 ℃ to 550 ℃, with strain rates varying between 2×10-6 s-1 and 1×10-5 s-1. Comparative analyses were performed against reference specimens tempered at 760 ℃. Results demonstrated threre is a pronounced LME susceptibility in 500 ℃-tempered specimens at 350 ℃ and 400 ℃, evidenced by a marked reduction in total elongation and quasi-brittle fracture morphology. Notably, this embrittlement vanishes at 550 ℃, where ductile fracture characteristics and full elongation recovery are observed. In contrast, 760 ℃-tempered specimens exhibited no LME across all tested conditions. Strain rate dependence studies reveal that LME persists at both low (2×10-6 s-1) and high (1×10-5 s-1) strain rates for 500 ℃-tempered steel; however, sensitivity is significantly amplified at lower strain rates. The research results should provide an important basis for understanding the service performance of SIMP steel in LBE environment.
Key words:  SIMP steel    liquid metal embrittlement    lead-bismuth eutectic    slow strain rate tensile tests
出版日期:  2026-04-25      发布日期:  2026-05-06
ZTFLH:  TL341  
基金资助: 中核集团领创科研项目(FJ222508000702)
通讯作者:  * 龙斌,博士,中国原子能科学研究院研究员,核工业研究生院教授,主要从事反应堆结构材料以及快堆液态金属冷却剂技术研究。binlong@ciae.ac.cn   
作者简介:  张洁,目前在中国原子能科学研究院攻读博士学位,研究方向包括结构材料与液态铅铋的相容性验证以及耐腐蚀氧化膜的微观结构表征。
引用本文:    
张洁, 秦博, 付晓刚, 龙斌. 低温回火的SIMP钢在铅铋共晶合金下的液态金属脆化敏感性研究[J]. 材料导报, 2026, 40(8): 25030039-10.
ZHANG Jie, QIN Bo, FU Xiaogang, LONG Bin. Study on Embrittlement Sensitivity of SIMP Tempered at Low Temperature in Liquid Metal Under Lead-Bismuth Eutectic Alloy. Materials Reports, 2026, 40(8): 25030039-10.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25030039  或          https://www.mater-rep.com/CN/Y2026/V40/I8/25030039
1 Murty K L, Charit I. Journal of Nuclear Materials, 2008, 383(1-2), 189.
2 Alberto P, Fradera J, Sadaba S, et al. Fusion Engineering and Design, 2022, 178, 113.
3 Zhang J. Corrosion Science, 2009, 51(6), 1207.
4 Colombo M, Cammi A, Memoli V, et al. Progress in Nuclear Energy, 2010, 52(8), 715.
5 Lorusso P, Bassini S, et al. Progress in Nuclear Energy, 2018(105), 318.
6 Aiello A, Azzati M, et al. Journal of Nuclear Materials, 2004, 335(2), 169.
7 Van den Bosch J, Bosch R W, et al. Journal of Nuclear Materials, 2008, 376(3), 322.
8 Gong X, Chen H, Wang Z, et al. Journal of Nuclear Materials, 2022, 563, 153641.
9 Van den Bosch J, Coen G, et al. Journal of Nuclear Materials, 2012, 429(1-3), 105.
10 Legris A, Nicaise G, Vogt J B, et al. Journal of Nuclear Materials, 2002, 301(1), 70.
11 Stoloff N S, Johnston T L. Acta Metallurgica, 1963, 11(4), 251.
12 Westwood A R C, Kamdar M H. Philosophical Magazine, 1963, 8(89), 787.
13 Lynch S P. Metallurgical and Materials Transactions A, 2013, 44(3), 1209.
14 Hancock P C, Ives M B. Quarterly, 1971, 10(3), 207.
15 Glickman E E. Interface Science, 2003, 11, 451.
16 Gordon P, An H H. Metallurgical Transactions A, 1982, 13, 457.
17 Dmukhovskaya I G, Popovich V V. Materials Science, 1983, 18(6), 461.
18 Long B, Dai Y. Journal of Nuclear Materials, 2008, 376(3), 341.
19 Long B, Tong Z, Gröschel F, et al. Journal of Nuclear Materials, 2008, 377(1), 219.
20 Huang Z Y, Xiao Y, Hou Q Y, et al. Iron & Steel, 2015, 50(8), 6(in Chinese).
黄贞益, 肖亚, 侯清宇, 等. 钢铁, 2015, 50(8), 6.
21 Ganeev A, Nikitina M, Sitdikov V, et al. Materials, 2018, 11(4), 627.
22 Liu J, Yan W, Sha W, et al. Journal of Nuclear Materials, 2016, 473, 189.
23 Zhang L L. A study on the role and mechanism of Si in nuclear SIMP steel. Ph. D. Thesis, University of Science and Technology of China, China, 2021(in Chinese).
张玲玲. 核用SIMP钢中Si元素的作用机理研究. 博士学位论文, 中国科学技术大学, 2021.
24 Chen Z X, Xu X C, Wang B, et al. Chinese Journal of Engineering, 2012, 34(3), 7(in Chinese).
陈振湘, 许晓嫦, 王斌, 等. 工程科学学报, 2012, 34(3), 7.
25 Huang B, Guo Z B, Shuai L T, et al. Failure Analysis and Prevention, 2021, 16(6), 5(in Chinese).
黄蓓, 郭占兵, 帅林涛, 等. 失效分析与预防, 2021, 16(6), 5.
26 Sarikaya M, Jhingan A K, Thomas G. Metallurgical Transactions A, 1983, 14(5), 1121.
27 Xu Z Y. Martensitic transformation and martensite, Beijing Science Press, China, 1999, pp. 66(in Chinese).
徐祖耀. 马氏体相变与马氏体, 北京科学出版社, 1999, pp. 66.
28 Wang H, Yan W, Shi Q Q, et al. Heat Treatment of Metals, 2018, 43(5), 7(in Chinese).
王海, 严伟, 石全强, 等. 金属热处理, 2018, 43(5), 7.
29 Zhang L, Wang Z P, Liu J N, et al. Foundry Technology, 2003, 24(6), 3(in Chinese).
张路, 王正品, 刘江南, 等. 铸造技术, 2003, 24(6), 3.
30 Gong X, Sun L, Zhang F, et al. Corrosion Science, 2022, 208, 110522.
31 Gong X, Hu F, Chen J, Wang H, et al. Journal of Nuclear Materials, 2020, 537, 152196.
32 Gong X, Marmy P, Qin L, et al. Journal of Nuclear Materials, 2016, 468, 35.
33 Hadjem-Hamouche Z, Auger T, Guillot I. Corrosion Science, 2009, 51(11), 2580.
34 Dai Y, Long B, Groeschel F. Journal of Nuclear Materials, 2006, 356(1-3), 222.
35 Ersoy F, Verbeken K, Gavrilov S. Materials Science and Engineering: A, 2021, 800, 140259.
36 Ye C, Vogt J B, Serre I P. Materials Science and Engineering: A, 2014, 608, 242.
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