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材料导报  2026, Vol. 40 Issue (8): 25030059-8    https://doi.org/10.11896/cldb.25030059
  高分子与聚合物基复合材料 |
Ti3C2Tx MXene/SF-016抗紫外复合材料的制备及在模拟壁画保护中的应用研究
方媛1,*, 李豆豆1, 王佳2, 路智勇2, 曾立军1, 赵婷1, 杨文宗1,2, 朱建锋1
1 陕西科技大学材料科学与工程学院,文物保护科学与技术学院,地下文物保护材料与技术教育部重点实验室,西安 710021
2 馆藏壁画保护修复与材料科学研究国家文物局重点科研基地(陕西历史博物馆),西安 710061
Synthesis of Ti3C2Tx MXene/SF-016 UV-resistant Composite and Its Application in Simulated Mural Conservation
FANG Yuan1,*, LI Doudou1, WANG Jia2, LU Zhiyong2, ZENG Lijun1, ZHAO Ting1, YANG Wenzong1,2, ZHU Jianfeng1
1 MoE Key Laboratory of Materials and Technology for Unearthed Cultural Heritage Conservation, School of Conservation Science and Technology for Cultural Heritage, School of Materials Science and Engineering, Shaanxi University of Science and Technology, Xi'an 710021, China
2 Key Scientific Research Base of the National Cultural Heritage Administration for Conservation, Restoration and Material Science of Museum-collected Murals (Shaanxi History Museum), Xi'an 710061, China
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摘要 丙烯酸树脂Primal SF-016是壁画保护中常用的有机材料,然而在使用过程中,其在紫外线的长期照射下会出现降解等现象。为了解决这一问题,本工作运用溶液共混法,成功制备出Ti3C2Tx MXene/SF-016复合材料。运用X射线衍射仪(XRD)、透射电子显微镜(TEM)和拉曼光谱仪(Raman)等手段对其进行表征,并测试其透光性、亲水性、抗紫外老化等性能。将Ti3C2Tx MXene/SF-016复合材料应用于模拟壁画的保护,对比分析了加固前后模拟壁画的微观形貌、水蒸气透过性、亲水性、加固强度和色差等。结果表明,复合材料具有良好的亲水性和一定的抗紫外老化性能,且当Ti3C2Tx MXene浓度为0.005%(质量分数,下同)和0.01%时,复合材料在保持80%以上透光率的同时,紫外线屏蔽效率提升37%~44%。在模拟壁画保护方面,Ti3C2Tx MXene/SF-016复合材料能有效保留壁画多孔结构,改善水蒸气透过性和亲水性,提高加固强度,且在Ti3C2Tx浓度不超过0.01%时,可有效控制色差,为墓葬壁画等文物的保护提供了一种具有潜力的新型材料。
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方媛
李豆豆
王佳
路智勇
曾立军
赵婷
杨文宗
朱建锋
关键词:  Ti3C2Tx MXene  Primal SF-016  抗紫外老化  壁画保护    
Abstract: Acrylic resin Primal SF-016, a conventional polymeric consolidant for mural conservation, exhibits susceptibility to photodegradation under prolonged UV radiation. Ti3C2Tx MXene/SF-016 composites were successfully prepared through a solution blending method. X-ray diffraction (XRD), transmission electron microscopy (TEM), and Raman spectroscopy were used to investigate the structure of Ti3C2Tx MXene/SF-016 composites. The light transmittance, hydrophilicity, and UV-aging resistance were investigated. The microstructures, water vapor permeability, hydrophilicity, reinforcement strength and color differences of the simulated murals before and after consolidation by Ti3C2Tx MXene/SF-016 composites were investigated. The optimized composites demonstrated enhanced hydrophilicity and UV-aging resistance. For the composites with 0.005% and 0.01% Ti3C2Tx MXene, the UV-shielding performance improved 37%—44% while maintaining >80% visible light transmittance. After consolidation by Ti3C2Tx MXene/SF-016, the original porous morphology of the murals could be preserved, water vapor permeability, hydrophilicity and the reinforcement strength were improved. Chromatic stability was maintained at Ti3C2Tx MXene concentrations≤0.01%. The results show that Ti3C2Tx MXene/SF-016 composites have significant potential as innovative materials for mural conservation.
Key words:  Ti3C2Tx MXene    Primal SF-016    UV-aging resistance    mural conservation
出版日期:  2026-04-25      发布日期:  2026-05-06
ZTFLH:  K876.3  
  TQ437  
基金资助: 馆藏壁画保护修复与材料科学研究国家文物局重点科研基地开放课题(2023KF-02);中央引导地方科技发展资金项目(2024ZY-JCYJ-04-06);陕西省技术创新引导专项项目(2024QY-SZX-04)
通讯作者:  * 方媛,博士,陕西科技大学材料科学与工程学院副教授、硕士研究生导师。目前主要从事陶瓷基复合材料的设计、制备与性能研究、壁画文物的劣化机理研究及保护技术开发等。fangyuan@sust.edu.cn   
引用本文:    
方媛, 李豆豆, 王佳, 路智勇, 曾立军, 赵婷, 杨文宗, 朱建锋. Ti3C2Tx MXene/SF-016抗紫外复合材料的制备及在模拟壁画保护中的应用研究[J]. 材料导报, 2026, 40(8): 25030059-8.
FANG Yuan, LI Doudou, WANG Jia, LU Zhiyong, ZENG Lijun, ZHAO Ting, YANG Wenzong, ZHU Jianfeng. Synthesis of Ti3C2Tx MXene/SF-016 UV-resistant Composite and Its Application in Simulated Mural Conservation. Materials Reports, 2026, 40(8): 25030059-8.
链接本文:  
https://www.mater-rep.com/CN/10.11896/cldb.25030059  或          https://www.mater-rep.com/CN/Y2026/V40/I8/25030059
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