贵金属(Pt/Pd/Ru)/分子筛在油脂加氢脱氧制备高品质烃类液体燃料中的研究进展

doi:10.11896/cldb.24040216

材料导报

2025, Vol. 39

Issue (11): 24040216-14 https://doi.org/10.11896/cldb.24040216

高分子与聚合物基复合材料

贵金属(Pt/Pd/Ru)/分子筛在油脂加氢脱氧制备高品质烃类液体燃料中的研究进展

聂懿宸^1,2,3, 李帅哲^1,2,3, KeomeesayPhidsavard¹, 顾雯^1,2,3, 张伟^1,2,3,4, 刘娜^1,2,3,4, 徐高翔^1,2,3,4, 刘莹^1,2,3,4, 李兴勇^1,2,3,4,*, 陈玉保^1,2,3,4,*

1 云南师范大学能源与环境科学学院,昆明 650500
2 云南省教育厅生物质绿色能源与平台化合物重点实验室,昆明 650500
3 云南省低碳农业绿色发展技术国际研发中心,昆明 650500
4 云南省农村能源工程重点实验室,昆明 650500

Research Progress on Noble Metals (Pt/Pd/Ru)/Molecular Sieve in the Preparation of High-quality Hydrocarbon Liquid Fuels Through Hydrodeoxygenation of Fats and Oils

NIE Yichen^1,2,3, LI Shuaizhe^1,2,3, Keomeesay Phidsavard¹, GU Wen^1,2,3, ZHANG Wei^1,2,3,4, LIU Na^1,2,3,4, XU Gaoxiang^1,2,3,4, LIU Ying^1,2,3,4, LI Xingyong^1,2,3,4,*, CHEN Yubao^1,2,3,4,*

1 School of Energy and Environmental Sciences, Yunnan Normal University, Kunming 650500, China
2 Key Laboratory of Biomass Green Energy and Platform Compounds, Yunnan Provincial Department of Education, Kunming 650500, China
3 International R&D Centre for Low Carbon Agriculture and Green Development Technology of Yunnan Province, Kunming 650500, China
4 Key Laboratory of Rural Energy Engineering of Yunnan Province, Kunming 650500, China

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摘要随着“双碳”目标的提出,发展清洁、可再生的生物烃类液体燃料变得尤为重要。油脂热催化加氢脱氧作为当前制备生物烃类燃油最受欢迎的技术之一,其关键在于催化剂的选用,贵金属催化剂因其卓越的催化效率和选择性备受关注。本文综述了近年来贵金属催化剂在油脂加氢脱氧反应中的应用和研究进展,重点讨论了油脂加氢反应过程和不同贵金属催化剂的催化机理。从分子筛的遴选、活性组分的选取和制备方法三个方面分析了影响贵金属催化剂催化性能的关键因素,着重探讨了不同种类的分子筛载体及催化剂的制备方法对催化反应的影响。最后,对贵金属催化油脂加氢面临的挑战和未来的发展方向进行了展望。

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	聂懿宸
	李帅哲
	KeomeesayPhidsavard
	顾雯
	张伟
	刘娜
	徐高翔
	刘莹
	李兴勇
	陈玉保1
	2
	3
	4

关键词: 贵金属催化剂油脂加氢脱氧催化机理烃类液体燃料

Abstract: The development of sustainable and environmentally friendly bio-hydrocarbon liquid fuels has become particularly significant since the establishment of the carbon peak and carbon neutrality targets. Thermal catalytic hydrodeoxygenation of fats and oils, one of the most prevalent methods for producing bio-hydrocarbon fuels, is critically dependent on catalyst selection, and noble metal catalysts have received a lot of attention due to their high catalytic efficiency and selectivity. This review summarizes recent applications and research advancement of noble metal catalysts in the hydrodeoxygenation of fats and oils, including the processes of fats and oils hydrogenation and the mechanism of various noble metal catalysts. The fundamental parameters influencing the effectiveness of noble metal catalysts are examined from three perspectives:molecular sieve selection, active component selection and preparation approach, particularly an emphasis on the effect of various types of molecular sieves on catalytic reactions and catalyst preparation. Furthermore, discusses the issues associated with noble metal catalyzed oil and grease hydroge-nation, as well as potential future research directions.

Key words: noble metal catalysts fats and oils hydrodeoxygenation catalytic mechanism hydrocarbon liquid fuels

发布日期: 2025-05-29

ZTFLH:

TK6

基金资助: 国家自然科学基金(22469024);云南省基础研究计划面上项目(202501CF070001);云南省国际科技特派员(个人)认定(202403AK140049);云南省基础研究计划重点项目(202301AS070011); 云南省低碳发展引导专项(云财资环[2021]135号);云南省科技人才与平台计划(202105AC160058);云南省教育厅重点实验室(云教发[2024]5号);云南省院士专家工作站(202205AF150024)

通讯作者: *李兴勇,云南师范大学能源与环境科学学院教师、硕士研究生导师。目前主要从事油脂加氢催化制备烃基生物柴油与航空煤油的研究。xingyong@ynnu.edu.cn
陈玉保,云南师范大学能源与环境科学学院教授、博士研究生导师。目前主要从事生物质开发与利用、烟草化学和能源化工等方面的研究工作。chenyubao@ynnu.edu.cn

作者简介: 聂懿宸,现为云南师范大学能源与环境科学学院硕士研究生,主要研究领域为油脂加氢脱氧制备生物航空煤油。

引用本文:

聂懿宸, 李帅哲, KeomeesayPhidsavard, 顾雯, 张伟, 刘娜, 徐高翔, 刘莹, 李兴勇, 陈玉保1,2,3,4. 贵金属(Pt/Pd/Ru)/分子筛在油脂加氢脱氧制备高品质烃类液体燃料中的研究进展[J]. 材料导报, 2025, 39(11): 24040216-14.
NIE Yichen, LI Shuaizhe, Keomeesay Phidsavard, GU Wen, ZHANG Wei, LIU Na, XU Gaoxiang, LIU Ying, LI Xingyong, CHEN Yubao. Research Progress on Noble Metals (Pt/Pd/Ru)/Molecular Sieve in the Preparation of High-quality Hydrocarbon Liquid Fuels Through Hydrodeoxygenation of Fats and Oils. Materials Reports, 2025, 39(11): 24040216-14.

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https://www.mater-rep.com/CN/10.11896/cldb.24040216 或 https://www.mater-rep.com/CN/Y2025/V39/I11/24040216

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