INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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Effects of Solution Concentration and Composition on the Transport Rate of Chloride Ions in Cracks |
GU Chunping1,2,3, YAO Chengyang1, CHEN Shilong1, WANG Qiannan4,*
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1 College of Civil Engineering, Zhejiang University of Technology, Hangzhou 310023, China 2 Key Laboratory of Civil Engineering Structures and Disaster Prevention and Mitigation Technology of Zhejiang Province, Hangzhou 310023, China 3 Zhejiang Construction Investment Group Co., Ltd., Hangzhou 310013, China 4 School of Civil Engineering and Architecture, Zhejiang University of Science & Technology, Hangzhou 310023, China |
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Abstract Cracks are channels for the rapid transport of chloride ions in concrete, which have significant influences on concrete durability. The nature of the solution in crack is one of the main factors affecting the transport rate of chloride ions. In order to exclude the influence of the crack morphology, this study prefabricated plexiglass and cement paste straight cracks, and designed the steady-state chloride transport test in cracks. The effects of solution concentration (2%, 3.5%, 5%, 7.5%, 10% NaCl solution) and composition (3.5% NaCl solution, artificial seawater and real seawater) on chloride transport rate in cracks were studied. The results showed that the chloride transport rate in plexiglass and cement paste straight cracks with same crack width were similar. As the crack width increased, the chloride ion diffusion coefficient in crack increased. When the crack width increased from 30 μm to 300 μm, the chloride ion diffusion coefficient in crack increased significantly. When the crack width was larger, the chloride ion diffusion coefficient increased relatively slowly; with the increase of NaCl solution concentration, the chloride ion diffusion coefficient in cracks gradually increased, and the larger the crack width, the more significant the influence of NaCl solution concentration. When the crack width was smaller than 115 μm, the results of tests performed with 3.5% NaCl solution and artificial seawater were similar to that with the real seawater; when the crack width was greater than 115 μm, the results of tests with 3.5% NaCl solution were relatively higher, while the results of the tests with artificial seawater were similar to those with real seawater.
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Published: 10 October 2024
Online: 2024-10-23
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Fund:National Natural Science Foundation of China (52378272,52008372) and the Natural Science Foundation of Zhejiang Province (LY22E080014). |
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