INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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Chloride Ion Diffusion and Sulfate Resistance of Graphene Nanosheet Plate Reinforced Cement Mortar |
YING Jingwei1,2,*, SU Feiming1, XI Xiaoying1, LIU Jianhui1
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1 School of Civil Engineering and Architecture, Guangxi University, Nanning 530004, China 2 Institute of Science and Technology for Carbon Peak and Neutrality, Guangxi University, Nanning 530004, China |
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Abstract The influence of graphene nanosheet plate (GNP) on chloride ion diffusion resistance and sulfate corrosion resistance of cement mortar was studied in this work. The micro-morphology and classification of hydration products of GNP composite cement mortar were characterized by thermogravimetry, mercury intrusion analysis, X-ray diffraction, scanning electron microscopy and energy spectrum analysis, and the mechanism of GNP enhancing chloride ion diffusion resistance and sulfate corrosion resistance of cement mortar was explained. The results show that compared with common cement mortar, the compressive and flexural strength of cement mortar increased by 11.1% and 12.7%, respectively, after adding 0.1% GNP by 28 days, and the apparent chloride ion concentration and diffusion coefficient decreased by 36.8% and 11.3%, respectively. GNP has no effect on the product category of cement hydration, but GNP can promote the hydration reaction of cement and refine the pore size in cement mortar; as a nano additive in cement, GNP can be filled near cement clinker, increasing the compact of the cement mortar, and the large specific surface area and two-dimensional plate structure of GNP can also serve as a physical barrier for corrosive ions.
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Published: 10 May 2024
Online: 2024-05-13
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Fund:National Natural Science Foundation of China (52168015,51768005), Guangxi Science and Technology Projects of China (2023GXNSFAA026472, AB16380030). |
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