INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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Tensile Properties Deterioration of BFRP Bars in Real Seawater Sea-sand Concrete Pore Solution Immersion Environment |
ZHU Deju1,2,*, CHU Kaidan1, GUO Shuaicheng1,2, SHI Caijun1
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1 Key Laboratory for Green & Advanced Civil Engineering Materials and Application Technology of Hunan Province, College of Civil Engineering, Hunan University, Changsha 410082, China 2 International Science Innovation Collaboration Base for Green & Advanced Civil Engineering Materials of Hunan Province, Hunan University, Changsha 410082, China |
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Abstract In order to study the long-term mechanical properties of basalt fiber reinforced polymer (BFRP) bars in seawater sea-sand concrete (SSC) environment, this paper investigates the evolution of BFRP bar tensile properties immersed in real SSC pore solution environment. Soaking solutions based on normal seawater cement slurry pore solution (NA) and low alkalinity seawater cement slurry pore solution (LA) were prepared by pore solution extrusion and ion concentration analysis, and the test results were also compared with those in ACI 440.3R specification recommended soaking solution (ACI) through accelerated aging. The BFRP bars prepared with epoxy resin (B/E bars) and vinyl ester resin (B/V bars) were utilized in the tests. The change of tensile mechanical property of BFRP bars was evaluated by tensile tests after accelerated aging at different temperatures and immersion durations, and the degradation mechanism was analyzed by using microstructural characterization. The test results showed that reducing the alkalinity of the pore solution was more effectively than reducing the chloride ion concentration for delaying the degradation of long-term mechanical property of BFRP bars, and the effect of increasing temperature on the mechanical property degradation of B/V bars was more significant than that of B/E bars. The tensile strength degradation of BFRP bars during aging process was higher than their elastic modulus. Meanwhile the difference in elastic modulus of B/E bars before and after accelerated aging in the three environments was not significant. The corrosion resistance of vinyl resin was better than that of epoxy resin, but its weaker interfacial properties with basalt fibers resulted in worse durability of B/V bars than that of B/E bars in the simulated SSC pore solution.
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Published:
Online: 2024-06-25
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Fund:National Natural Science Foundation of China-Shandong Joint Fund (U1806225), the National Natural Science Foundation of China (52208246), and the Natural Science Foundation of Changsha (kq2202160). |
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