| ELECTROCHEMICAL ENERGY MATERIALS AND DEVICES |
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| Progress in Preparation and Electrochemical Application of Single-wall Carbon Nanohorns |
| SU Xiankai1,2,3,†, XIE Zhipeng1,2,3,†, ZHANG Da1,2,3,*, HOU Shengping1,2,3, YANG Bin1,2,3, LIANG Feng1,2,3,*
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1 National Engineering Research Center for Vacuum Metallurgy, Kunming University of Science and Technology, Kunming 650093, China
2 Key Laboratory for Nonferrous Vacuum Metallurgy of Yunnan Province, Kunming University of Science and Technology, Kunming 650093, China
3 School of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China |
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Abstract Single-wall carbon nanohorns (SWCNHs) are hollow conical carbon nanomaterials produced by curling a single layer of graphene. SWCNHs cannot exist alone in a normal state, but instead as spherical aggregates formed by thousands of SWCNHs. Due to their excellent electrical and thermal properties, low density, and high specific surface area, SWCNHs are regarded as promising carbon nanomaterials for electrochemical application. SWCNHs are usually prepared by laser ablation, arc discharge, and joule heating methods, and these process do not use metal catalysts, so as to avoid impurity contamination, which broadens the application of SWCNHs. Over the last two decades, SWCNHs have been widely used in supercapacitors, electrochemical sensors, and lithium-ion, solar, fuel, and metal-CO2 batteries. Numerous studies have shown that SWCNH-based electrochemical devices offer high efficiency, stability, and safety. Promoting the industrial production and large-scale application of SWCNHs in the electrochemical field is of great significance to the development of new energy and high-end manufacturing industries in China. This study summarizes the structure, characteristics, and preparation methods of SWCNHs, reviews the research progress of SWCNHs in the field of electrochemistry, and prospects future research directions and development trends of SWCNHs.
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Published: 25 March 2024
Online: 2024-04-07
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| Fund:National Natural Science Foundation of China (12175089,12205127), the Key Research and Development Program of Yunnan Province (202103AF140006), the Applied Basic Research Programs of Yunnan Provincial Science and Technology Department (202001AW070004), and the Yunnan Major Scientific and Technological Projects (202202AG050003). |
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Corresponding Authors:
*zhangda@kust.edu.cn;liangfeng@kust.edu.cn
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2024, Vol. 38 
