基于缺陷工程改性富锂层状材料的研究现状

doi:10.11896/cldb.22070108

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Abstract With the rapid development of long-range electric vehicles, the development of high-energy-density and low-cost power batteries has become an important factor. Li-rich layered materials, with high energy density and low cost, are expected to be the next-generation commercial cathode materials. Nevertheless, the rapid voltage and capacity attenuation, caused by the transformation from the layered structure to the spinel structure during charge/discharge processes, limited their commercial applications. In regard to these challenges the crystal structure, charge-discharge mechanism, fading mechanism of voltage and capacity of Li-rich layered materials are summarized, and the modification me-thods from the perspective of defect engineering are discussed as well in this paper. Finally, the outlook for future development of Li-rich layered materials is given.

Key words： Li-rich layered material crystal structure charge-discharge mechanism vacancy defect ions doping

Published: 25 February 2024 Online: 2024-03-01

CLC number:

TM912.9

Fund:National Natural Science Foundation of China (21905124).

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	Articles by authors
	CHEN Yanli
	XIE Ziqi
	WANG Mengzhen
	MA Zihan
	LI Shanshan
	YAN Wenchao
	LI Faqiang

Cite this article:

CHEN Yanli,XIE Ziqi,WANG Mengzhen, et al. Research Status of Li-rich Layered Materials Based on Defect Engineering[J]. Materials Reports, 2024, 38(4): 22070108-9.

URL:

http://www.mater-rep.com/EN/10.11896/cldb.22070108 OR http://www.mater-rep.com/EN/Y2024/V38/I4/22070108

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