双马来酰亚胺树脂增韧改性研究进展

doi:10.11896/cldb.21020082

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Abstract Bismaleimide (BMI) resin is widely used in the aerospace field owing to its excellent high-temperature resistance, especially in the BMI resin-based composite materials and BMI structural adhesive manufacturing fields. However, BMI resins without toughening modification have shortcomings of high melting point, poor solubility and high brittleness in cured products. For example, high brittleness severely limits the BMI resin application. Therefore, it is necessary to toughen and modify BMI before use. This paper reviews the research progress of toughening modification of BMI resin from three main aspects: internal toughening, external toughening and synergistic toughening modifications. The internal toughening modification methods include using chain extenders for chain extension and toughening modification of BMI, introducing flexible groups into BMI molecular structure for intramolecular toughening modification, and using allyl and propenyl compounds for BMI toughening modification through copolymerization. The external toughening modification method mainly achieves the toughening effect by introducing a toughening agent into the BMI resin. The external toughening agent includes rubber elastomers, inorganic functional materials, thermoplastic resins and thermosetting resins. The synergistic toughening modification utilizes the synergistic effect of various toughening methods to strengthen and toughen BMI. The paper ends with a brief discussion about the future research trends of this field.

Key words： bismaleimide toughening modification high-temperature resistance composites

Published: Online: 2022-10-26

CLC number:

TB332

Fund:Natural Science Foundation for Distinguished Young Scholars of Heilongjiang Province (JC2017015), Natural Science Foundation of Heilongjiang Province (TD2020E003), the National Natural Science Foundation of China (21875054) and Pre-research Foundation of Heilongjiang Academy of Sciences (YY2021SH01).

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	Articles by authors
	ZHAO Liwei
	YANG Haidong
	WANG Dezhi
	QU Chunyan
	FENG Hao
	LI Hongfeng
	XIAO Wanbao

Cite this article:

ZHAO Liwei,YANG Haidong,WANG Dezhi, et al. Research Progress in Toughness Modification of Bismaleimide Resin[J]. Materials Reports, 2022, 36(20): 21020082-7.

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http://www.mater-rep.com/EN/10.11896/cldb.21020082 OR http://www.mater-rep.com/EN/Y2022/V36/I20/21020082

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