| POLYMERS AND POLYMER MATRIX COMPOSITES |
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| Synthesis and Electrowetting Properties of Fluorine-containing Polymer Coating: a Review |
| XU Zhuofan1, PENG Shuting1, ZHOU He1, GUO Yuanyuan1, ZHOU Guofu1,2,3, XU Xuezhu1,*
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1 Guangdong Provincial Key Laboratory of Optical Information Materials and Technology & Color Dynamic Electronic Paper Display Technology Institute, South China Institute of Advanced Optoelectronics, South China Normal University,Guangzhou 510006, China
2 Shenzhen Guohua Optoelectronics Technology Co., Ltd., Shenzhen 518110, Guangdong, China
3 Shenzhen Guohua Optoelectronics Research Institute, Shenzhen 518110, Guangdong, China |
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Abstract Fluorinated polymer coatings have excellent physical properties and are widely used in the fields of microelectronics, electronic information display and various opticaldevices. In particular, fluorinated polymer films bear properties such as non-adhesiveness, highly chemical resis-tance, high stability, etc., which make it highly applicable as a hydrophobic layer material in electrowetting displays (EWD). The electrowetting (EW) is a new display driving mechanism by applying a direct voltage between a droplet and the fluorinated polymer based hydrophobic layer so that the droplet can be deformed and displaced.
The properties and lifetime of the EWD device is directly related to the dielectric properties of the fluorinated polymer layer. The fluorinated polymer solution or coating is limited by narrow solvent selection range, high glass conversion temperature, low dielectric constant and easy breakdown, which hinders the development of EWD devices. To our knowledge, these have not been evaluated and reviewed. Given that electronic materials are moving towards multi-variety and high-quality development, and fluorinated polymeric material is a functional material to meet these requirements, it appears particularly important to let researchers fully understand the characteristics, synthesis methods and dielectric wetting performance of fluorinated polymer coatings, as well as the performance requirements of EWD devices upon relevant materials.
This paper discusses the structural characteristics, performance and synthesis methods of fluorinated polymer hydrophobic materials, reviews the research progress of fluorinated polymer EWD in recent years, elaborates the key physicochemical properties of fluorinated polymer films, including dielectric constants, breakdown voltage, leakage current, wetting performance and their impacts on EW properties, summarizes the bottlenecks of fluorinated polymers and the application status of its coating on EWD devices, and prospects briefly its future research direction.
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Published: 25 August 2022
Online: 2022-08-29
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| Fund:National Key Research and Development Program (2016YFB0401501), the ‘Changjiang Scholars and Innovation Team Development Program' of the Ministry of Education (IRT_17R40), the National Youth Science Foundation Project (51903094), Guangdong Provincial Key Laboratory of Optical Information Materials and Technology (2017B030301007), National Green Optoelectronics International Joint Research Center (2016B01018) and National ‘111' Plan Optical Information Innovation Induction Base and 2019 Guangdong Overseas Famous Teacher Project (191900023). |
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