混合卤化物钙钛矿中的光致相分离效应

doi:10.11896/cldb.20100115

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Abstract Halide perovskite materials have attracted much attention due to their excellent photoelectronic properties and low manufacturing cost. Halide perovskite solar cells are expected to become the next generation of photovoltaic technology, because their best power conversion efficiency has increased to 25.2% in just a few years. In particular, the band gap of mixed halide perovskites can be tuned by altering the composition of halides, making them ideal materials for preparing the top absorption layer of tandem solar cells and the active layer of light-emitting diodes.
Unfortunately, mixed halide perovskites exhibit reversible halide segregation under illumination. This instability significantly affects the photophysical properties of the materials and severely limits the application prospect of mixed halide perovskites. Therefore, a large amount of research has been performed in the past five years, aiming to reveal the basic mechanism of the photoinduced halide segregation; the methods to restrain this instability were also discussed from the aspects of stoichiometry and preparation process.
Recently, it has been gradually realized that light-induced phase segregation represents an intrinsic instability by means of optical and structural measurements in mixed halide perovskites, and is affected by both thermodynamics and kinetics. Phase segregation can be mitigated by selecting suitable components and controlling illumination and temperature. In addition, the surface defects passivation and crystallinity control can also improve photostability of mixed halide perovskites. However, the understanding of the light-induced phase segregation is still incomplete, and the strategies to improve the photostability of mixed halide perovskites also have not been fully explored.
Here, we review and analyze experimental observations of light-induced phase segregation in mixed halide perovskite, especially for the typical material MAPb(I_1-xBr_x)₃. We also classify the mechanism of halide segregation combined with theoretical analysis, and finally summarize ongoing research to suppress the phenomenon. We hope this review will provide a reference for the development of photostable mixed-halide perovskite materials.

Key words： mixed halide perovskites light-induced phase segregation photostability halide ion migration

Published: 25 August 2022 Online: 2022-08-29

CLC number:

O469

Fund:National Natural Science Foundation of China (61704063, 61804062, 62074079), Jiangsu Provincial University Natural Science Research Major Program, China (20KJA510006) and Postgraduate Research & Practice Innovation Program of Jiangsu Province (HGYK202020).

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	YANG Xiao
	CAO Chenglong
	HU Shu
	GE Jiaqing
	JIANG Qingsong
	SHENG Chuanxiang

Cite this article:

YANG Xiao,CAO Chenglong,HU Shu, et al. Review of Light-induced Phase Segregation in Mixed Halide Perovskites[J]. Materials Reports, 2022, 36(16): 20100115-15.

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http://www.mater-rep.com/EN/10.11896/cldb.20100115 OR http://www.mater-rep.com/EN/Y2022/V36/I16/20100115

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