共价有机骨架材料的合成及应用

doi:10.11896/cldb.19080093

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Abstract Covalent organic frameworks (COFs) are crystalline organic porous materials, which are constructed with organic building blocks through reversible covalent bonds. Since the first case of COFs was reported in 2005, a large number of new COFs have emerged. COFs have the advantages of light weight, low density, regular structure, adjustable pore structure, high specific surface area, and high chemical stability, which have great application potential in life science, environmental protection and energy chemical industries. Owning to functional COFs facilitate the transportation of different substances within them, researchers have successfully applied them to many fields, such as gas adsorption and storage, catalysis, drug delivery, organic electronic devices, and selective separation membrane, etc., and achieved fruitful research results. Many reports indicate that COFs are highly-efficient porous materials for storing CO₂, H₂ and CH₄. Further, COFs can be also used as catalyst support or be as catalysts directly to imporve many chemical reactions. COFs have good water dispersibility, no toxicity to cells, and show high loading and release capacities for ibuprofen, 5-fluorouracil and quercetin, etc. The highly regular π-array pores of 2D COFs are easy to form good carrier conduction paths, which make them have great potential to be the ideal candidates for semiconductor devices, supercapacitors and proton exchange membrane materials. Owning to their highly-ordered and stable nanopores, 2D COFs also can be used as nanofiltration membranes for efficient separation of dye molecules in solvents. In this work, the characteristics of COFs are summarized, and the structural design, functionalization and synthesis methods of COFs are also described in detail. Finally, the applications of COFs in gas adsorption and storage, catalysis, drug delivery, organic electronic devices and selective separation membrane are reviewed. The development trend of COFs are also prospected.

Key words： covalent organic frameworks structural design functionalization

Published: 14 July 2021

CLC number:

TB34

Fund:This work was financially supported by the National Natural Science Foundation of China (21767015), the National Key R&D Plan (2018YFC1902105).

About author:: Guanyin Zhang received his B.S. degree in resource circulation science and engineering from Faculty of Environmental Science and Engineering, Kunming University of Science and Technology in 2017. He is currently pursuing his M.S. degree at the Faculty of Environmental Science and Engineering, Kunming University of Science and Technology under the supervision of Prof. Qingqing Guan and Liang He. His research has focused on synthesis and catalytic application of covalent organic frameworks.
Liang He received his B.S. and M.S. degrees in light chemical engineering from Tianjin University of Science and Technology in 2007—2014, and received his Ph.D. degree in pulp and paper engineering from South China University of Technology in 2017. He is currently an associate professor at Kunming University of Science and Technology, and won the title of Young Talent in Yunnan Province’s “High-level Talent Introduction Program”. His research interests are biomass chemicals and materials, tobacco and cigarette new materials, papermaking process monitoring and environmental protection.

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	ZHANG Guanyin
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Cite this article:

ZHANG Guanyin,GUAN Qingqing,MIAO Rongrong, et al. Synthesis and Application of Covalent Organic Frameworks[J]. Materials Reports, 2021, 35(13): 13215-13226.

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http://www.mater-rep.com/EN/10.11896/cldb.19080093 OR http://www.mater-rep.com/EN/Y2021/V35/I13/13215

1	Li J R, Kuppler R J, Zhou H C. Chemical Society Reviews,2009,38(5),1477.
2	Choi K M, Jeong H M, Park J H, et al. ACS Nano,2014,8(7),7451.
3	Cote A P, Benin A I, Ockwig N W, et al. Science,2005,310(5751),1166.
4	Kuhn P A, Thomas A M. Angewandte Chemie,2008,47(18),3450.
5	Feng X, Ding X, Jiang D. Chemical Society Reviews,2012,41(18),6010.
6	Uribe-Romo F J, Hunt J R, Furukawa H, et al. Journal of the American Chemical Society,2009,131(13),4570.
7	Uribe-Romo F J, Doonan C J, Furukawa H, et al. Journal of the American Chemical Society,2011,133(30),11478.
8	Kandambeth S, Mallick A, Lukose B, et al. Journal of the American Chemical Society,2012,134(48),19524.
9	Fang Q, Qiu S, Yan Y, et al. Nature communications,2014,5,4503.
10	Ding X S, Guo J, Feng X, et al. Angewandte Chemie,2011,123(6),1325.
11	Feng X, Liu L, Honsho Y, et al. Angewandte Chemie ,2012,51(11),2618.
12	Li Y, Yang R T. AIChE Journal,2008,54(1),269.
13	Lanni L M, Tilford R W, Bharathy M, et al. Journal of the American Chemical Society,2011,133(35),13975.
14	El-Kaderi H M, Hunt J R, Mendoza-Cortes J L, et al. Science,2007,316(5822),268.
15	Spitler E L, Koo B T, Novotney J L, et al. Journal of the American Che-mical Society,2011,133(48),19416.
16	Baldwin L A, Crowe J W, Pyles D A, et al. Journal of the American Chemical Society,2016,138(46),15134.
17	Xu H, Gao J, Jiang D. Nature chemistry,2015,7(11),905.
18	Du Y, Yang H, Whiteley J M, et al. Angewandte Chemie,2016,128(5),1769.
19	Wan S, Gándara F, Asano A, et al. Chemistry of Materials,2011,23(18),4094.
20	Lin G, Ding H, Chen R, et al. Journal of the American Chemical Society,2017,139(25),8705.
21	Ding S, Wang W. Chemical Society Reviews,2013,42(2),548.
22	Ding S, Gao J, Wang Q, et al. Journal of the American Chemical Society,2011,133(49),19816.
23	Pachfule P, Kandambeth S, Díaz D, et al. Chemical Communications,2014,50(24),3169.
24	Wang X, Han X, Zhang J, et al. Journal of the American Chemical Society,2016,138(38),12332.
25	Peng Y W, Hu Z G, Gao Y J, et al. ChemSusChem,2015,8(19),3208.
26	Wan S, Guo J, Kim J, et al. Angewandte Chemie,2009,48(30),5439.
27	Wan S, Guo J, Kim J, et al. Angewandte Chemie,2008,120(46),8958.
28	Zhang W, Zhang L, Zhao H, et al. Journal of Materials Chemistry A,2018,6,13331.
29	Feng X, Chen L, Dong Y, et al. Chemical Communications,2011,47(7),1979.
30	José L S, María J M, Félix Z. Chemical Society Reviews,2016,45,5635.
31	Smith B J, Overholts A C, Hwang N, et al. Chemical Communications,2016,52(18),3690.
32	Lin G, Ding H, Yuan D, et al. Journal of the American Chemical Society,2016,138(10),3302.
33	Zhang W, Li C, Yuan Y P, et al. Journal of Materials Chemistry,2010,20(31),6413.
34	Guan X, Ma Y, Li H, et al. Journal of the American Chemical Society,2018,140(13),4494.
35	Campbell N L, Clowes R, Ritchie L K, et al. Chemistry of Materials,2009,21(2),204.
36	Ren S, Bojdys M J, Dawson R, et al. Advanced Materials,2012,24(17),2357.
37	Biswal B P, Chandra S, Kandambeth S, et al. Journal of the American Chemical Society,2013,135(14),5328.
38	Karak S, Kandambeth S, Biswal B P, et al. Journal of the American Chemical Society,2017,139(5),1856.
39	Medina D D, Rotter J M, Hu Y, et al. Journal of the American Chemical Society,2015,137(3),1016.
40	Zwaneveld N A A, Pawlak R, Abel M, et al. Journal of the American Chemical Society,2008,130(21),6678.
41	Furukawa H, Yaghi O M. Journal of the American Chemical Society,2009,131(25),8875.
42	Dey S, Bhunia A, Esquivel M D, et al. Journal of Materials Chemistry A,2016,4(17),6259.
43	Zhao Y, Yao K X, Teng B, et al. Energy & Environmental Science,2013,6(12),3684.
44	Wang K, Huang H, Liu D, et al. Environmental Science & Technology,2016,50(9),4869.
45	Ma Y, Li Z, Wei L, et al. Journal of the American Chemical Society,2017,139(14),4995.
46	Cao D, Lan J, Wang W, et al. Angewandte Chemie,2010,48(26),4730.
47	Kalidindi S B, Oh H, Hirscher M, et al. Chemistry-A European Journal,2012,18(35),10848.
48	Neti V S P K, Wu X, Deng S, et al. CrystEngComm,2013,15(35),6892.
49	Zeng Y, Zou R, Zhao Y. Advanced Materials,2016,28(15),2855.
50	Mendoza-Cortes J L, Pascal T A, Goddard W A. The Journal of Physical Chemistry A,2011,115(47),13852.
51	Pachfule P, Panda M K, Kandambeth S, et al. Journal of Materials Chemistry A,2014,2(21),7944.
52	Lu S, Hu Y, Wan S, et al. Journal of the American Chemical Society,2017,139(47),17082.
53	Wu Y, Xu H, Chen X, et al. Chemical Communications,2015,51(50),10096.
54	Fang Q, Gu S, Zheng J, et al. Angewandte Chemie,2014,126(11),2922.
55	Fang Q, Wang J, Gu S, et al. Journal of the American Chemical Society,2015,137(26),8352.
56	Bai L, Phua S Z, Lim W Q, et al. Chemical Communications,2016,52(22),4128.
57	Vyas V S, Vishwakarma M, Moudrakovski I, et al. Advanced Materials,2016,28(39),8749.
58	Mitra S, Sasmal H S, Kundu T, et al. Journal of the American Chemical Society,2017,139(12),4513.
59	Deblase C R, Kenneth H B, et al. ACS Nano,2015,9(3),3178.
60	Wang S, Wang Q, Shao P, et al. Journal of the American Chemical Society,2017,139(12),4258.
61	Sun B, Zhu C H, Liu Y, et al. Chemistry of Materials,2017,29(10),4367.
62	Sasmal H S, Aiyappa H B, Bhange S N, et al. Angewandte Chemie,2018,57(34),10894.
63	Fan H, Gu J, Meng H, et al. Angewandte Chemie,2018,57(15),4083.
64	Kandambeth S, Biswal B P, Chaudhari H D, et al. Advanced Materials,2017,29(2),1603945.