钯催化末端炔烃羰基化研究进展

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Abstract The carbonylation of alkyne to form α, β-unsaturated carbonyl compounds is an important intermediate for many basic organic synthesis, which has great application value in drug synthesis, agricultural chemicals, spices and so on. The effective utilization of C1 resources makes the palladium-catalyzed carbonylation have atom economy and high selectivity. The first palladium catalyst system to obtain α, β-unsatura-ted carbonyl compounds was a homogeneous palladium salt system with strong acids, metal salts as cocatalysts. In the following decades, researchers used solid organic acid to reduce its pollution to the environment and equipment, then developed new ligand systems to improve the conversion and selectivity of the reaction. Homogeneous system is not easy to be separated and purification, which limits its application. In recent years, people′s focus has been on heterogeneous catalysis. Loading palladium catalyst on porous solid surface can not only increase specific surface area and have more active sites, but also solve the problem of difficult separation of product and catalyst. In this review,we mainly describe the related reports of palladium catalyzed carbonylation of terminal alkynes. The effects of solvents, promoters and ligands in homogeneous system on the products of alkyne catalyzed carbonylation are introduced. At the same time, the research progress of heterogeneous palladium catalyzed carbonylation of alkynes is also summarized. The development trend and direction of palladium catalyzed carbonylation of terminal alkynes are prospected.

Key words： palladium terminal alkynes carbonylation homogeneous reaction heterogenized catalyst

Published: 08 January 2021

CLC number:

TQ032.4

Fund:This work was financially supported by the National Natural Science Foundation of China (51863004),Science and Technology Foundation of Guizhou Pro-vince, China(Qian Ke He Ji Chu〔2019〕1158th)and the Growth of Young Scientific and Technological Talents in Guizhou Province, China(Qian Jiao He KY〔2018〕149^th).

About author:: Jingcan Zhao received her B. E. degree in applied chemistry from Wuhan Donghu University in 2017. She is currently pursuing her master′s degree under supervision of Professor Yingchun Luo and Dr. Huanjiang Wang at Guizhou Minzu University. She is mainly focused on the design and preparation of acetylene double carbonylation catalyst. Huanjiang Wang obtained his Ph. D. degree in physical chemistry from Lanzhou Institute of Chemical Phy-sics, Chinese Academy of Sciences in 2017.He presided over one provincial fund project, one project of the Department of Education, and published more than 10 academic papers. He is mainly focused on the design and application of industrial catalysts and theoretical computational chemistry. Yingchun Luo received her B.E. degree in agricultural pharmacy from Guizhou University in 2007. She is mainly focused on analytical chemistry. She has presided over five provincial and ministerial-level projects and participated in three projects of the National Natural Science Foundation of China as major members. She has published nearly 20 papers in domestic academic journals, edited two books and participated in four books.

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	ZHAO Jingcan
	WANG Huanjiang
	ZHOU Guoyong
	BAO Dongmei
	LUO Yingchun

Cite this article:

ZHAO Jingcan,WANG Huanjiang,ZHOU Guoyong, et al. Research Progress in Palladium-Catalyzed Carbonylation of Terminal Alkynes[J]. Materials Reports, 2020, 34(Z2): 543-548.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2020/V34/IZ2/543

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