工业废料中铼元素的回收与再利用研究进展

doi:10.11896/cldb.19060090

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Abstract Metal rhenium has the physical properties of high hardness, high mechanical strength, good plasticity and good mechanical stability as well as excellent catalytic activity and corrosion resistance chemical properties,so it has important application value and broad application prospect in the fields of superalloy and petrochemical industry. However, reserves of rhenium in nature are very small, and the abundance of rhenium in the crust is about 6.57×10^-10.Rhenium resources are relatively scarce in China, and there are no rhenium deposits available for industrial exploitation. Most of these rhenium exist in the form of associated minerals, mostly distribute in molybdenite and copper-rhenium sulfide. Currently, the proved rhenium ore reserves are only about 237 tons.
With the rapid development of aerospace and petrochemical fields, the demand for rhenium resources is increasing.About 80% of rhenium in China is used in the field of superalloys, mainly used to make turbine engine blades of aerospace and aviation, and 20% of rhenium is used as catalysts for catalytic cracking reforming of petroleum.The alloy waste produced in the manufacturing process accounts for about 70% of the an-nual output.Domestic enterprises paid little attention to the recovery of rhenium secondary resources, and the recovery technology was relatively weak, which led to serious resource waste.The global resource recovery and reuse industry is developing rapidly. Western developed countries attach great importance to the recovery and reuse of rhenium secondary resources.The United States and Germany are the major countries for the recovery of rhenium resources, and the recovery amount of rhenium in superalloy in the United States reached 6 tons in 2014.The reuse of rhe-nium will aggravate the deterioration of energy and resources, so it is of great significance to study the recycling process of rhenium resources in a scientific, economic and environmental way to alleviate the problem of energy shortage in China.
There are mainly two kinds of rhenium wastes produced in industry: one is the rhenium-containing smoke, waste catalysts,superalloys and other solid waste, which can be recovered mainly by means of oxidative acid leaching, high-temperature alkali melting, electrolytic dissolution, etc, and then enriched rhenium through treatment.The second is the rhenium waste liquid produced by smelting concentrate, etc. The recovery methods mainly include ion exchange extraction, activated carbon adsorption, biological adsorption and other recovery processes. The key problem is how to improve the recovery rate of rhenium, reduce the cost and no pollution to the environment.Since rhenium and molybdenum are similar in nature, the biggest challenge for China is how to effectively separate rhenium and molybdenum and extract them in a more efficient, economical and environmentally friendly way to achieve industrialization.
Based on the specific situation of rhenium resources in industrial wastes, this paper summarizes the research progress on the recovery and reuse of rhenium secondary resources, and separately summarizes and introduces the recovery methods of rhenium in rhenium solid waste and rhenium waste liquid.Different process of rhenium secondary resources recovery characteristics and the problems are analyzed, the technology for the future development direction is forecasted, in order to realize the maximum recovery and reuse efficiency of rhenium resources and alleviate the current situation of rhenium metal material supply shortage in China.

Key words： application of rhenium rhenium secondary resource sources of waste recycling reuse

Published: 14 July 2020

CLC number:

TG146.4

Fund:This work was financially supported by Joint Fund Between Shenyang National Laboratory for Materials Science and State Key Laboratory of Advanced Proces-sing and Recycling of Nonferrous Metals (18LHZD003),Liaoning Provincial Department of Science and Technology Doctoral Research Initiation Fund Project(2019-BS-130), the PhD Startup Fund was supported by the Liaoning Institute of Science and Technology (1810B06), Research Fund Project of Liaoning Provincial Department of Education(201710311).

About author:: Chunwei Zhang received his technology bachelor's degree in Chemical engineering and technology from Qufu Normal University in 2017. He is currently pursuing his master's degree at the School of Chemistry, Liaoning University under the Researcher Fang Dawei. His research has focused on the recovery of superalloy scraps.
Yuan Sun was an associate researcher at the Institute of Metal Research, Chinese Academy of Sciences. She studied at Harbin Institute of Technology from 1996 to 2011 and obtained his bachelor's degree, master's degree and doctoral degree, studied abroad at Osaka University in Japan, and worked as a postdoctoral researcher at the Institute of Metal Research, Chinese Academy of Sciences from 2011 to 2013. Her main research field is superalloy recycling and reuse.
Dawei Fang received his B.E. degree in chemistry from Liaoning University in 2002 and received his Ph.D. degree in Qinghai Salt Lake, Chinese Academy of Scie-nces, in 2008. After two-year postdoctoral research at Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences, conducted post-doctoral research in Dalian Institute of Chemical Physics, Chinese Academy of Sciences in 2010—2012.Vice chairman of China Rare Metal Metallurgy Academic Committee,vice chairman of the Academic Committee on chemical thermodynamics and thermal analysis of the Chinese Chemical Society,vice chairman of the energy conservation and emission reduction committee of the Chinese Society of Non-ferrous Metals.Mainly engaged in the synthesis, properties and catalytic applications of ionic liquids,extraction and separation of sparse elements and high va-lueadded utilization;Research and development of resin matrix composites.

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	ZHANG Chunwei
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Cite this article:

ZHANG Chunwei,SUN Yuan,TANG Junjie, et al. Research Progress on the Recovery and Reuse of Rhenium in Industrial Waste[J]. Materials Reports, 2020, 34(15): 15145-15152.

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http://www.mater-rep.com/EN/10.11896/cldb.19060090 OR http://www.mater-rep.com/EN/Y2020/V34/I15/15145

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