METALS AND METAL MATRIX COMPOSITES |
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Research Progress in Refractory Metal Coatings |
HAN Xueying, LIU Xinli, WU Zhuangzhi, DUAN Bohua, WANG Dezhi
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Key Laboratory of Nonferrous Metal Materials Science and Engineering of Ministry of Education, School of Materials Science and Engineering, Central South University, Changsha 410083, China |
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Abstract The surface properties of materials can directly affect whether the materials can be used in a specific environment for a long time. As a common surface modification method, surface coating technology can improve the properties of the substrate such as wear resistance, heat resistance, corrosion resistance and high temperature stability by coating one or more layers of metal or non-metal on the substrate. Refractory metals and their alloys, intermetallic compounds, carbides, nitrides, etc., have become the most potential coating materials in aerospace, defense and military industries due to their excellent high-temperature strength, good resistance to liquid metal corrosion, plastic processing and ot-her characteristics. The preparation methods for refractory metal coatings include thermal spraying, laser cladding, vapor deposition, etc., and related technologies are still being optimized and innovated to meet increasingly severe service conditions. For example, high velocity oxygen fuel spraying and supersonic plasma spraying technology have been developed on the basis of traditional thermal spraying. Researchers combined laser cladding with cold spraying technology, developed laser-assisted cold spraying technology, and also proposed a solid carburizing method to obtain refractory metal carbide coatings. On the basis of refractory metal, alloy and carbide coatings, researchers have continuously improved the wear resis-tance and high temperature resistance of the coatings through composition and process optimization. Ni-W, Ni-Mo, Ta nanocomposite film and Mo2C composite coating with unique properties and high hardness WN coating are also obtained. Due to the limitations of single coating application, the development of composite coatings with different functions have become a research hotspot, such as refractory metal sulfide composite coatings with lubricating properties, Mo2Si composite coatings, etc. According to the advantages brought by grain refinement, a variety of preparation technology for composite nanoscale film has yet to be developed. In addition, in the recovery of refractory metal coatings, the research on the recovery and extraction technology of WC coatings is more in-depth, but the proportion of refractory metal recycling in China is relatively low. The key technology for efficient and clean recovery of refractory metals from coatings needs to be developed. This article describes different types of refractory metal-containing coatings, including metal-based alloy coatings, ceramic coatings (mainly including carbide coatings, nitride coatings, silicide coatings, sulfide coatings), and refractory high entropy alloy coatings. The application fields of different coatings, preparation methods and recovery strategies of refractory metals are reviewed. The problems faced in the current research are pointed out, and the research direction of refractory metal coatings in the future is prospected.
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Published: 24 June 2020
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Fund:National Key R & D Program of China (2018YFC1901700) |
About author:: Xueying Hanis a graduate student in the School of Materials Science and Engineering at Central South University. Her current research area is refractory metal coating. Xinli Liu, associate professor of Central South University, Master’s Supervisor. She graduated from Central South University with a doctorate in materials science in 2015. She mainly engaged in the development and recovery of refractory metal related materials, powder metallurgy porous materials. She has published more than 40 papers in scientific journals, applied for 3 patents, and obtained 2 authorized patents. |
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1 Bai S X, Niu D, Zhu L A, et al. Cemented Carbide, 2018, 35(6), 381(in Chinese). 白书欣, 牛顿, 朱利安, 等. 硬质合金, 2018, 35(6), 381. 2 Zheng X, Bai R, Wang D H, et al. Rare Metal Materials and Enginee-ring, 2011, 40(10), 1871(in Chinese). 郑欣, 白润, 王东辉, 等. 稀有金属材料科学与工程, 2011, 40(10), 1871. 3 Lian Z W, Fang X Q, Han W J, et al. Fusion Engineering and Design, 2016, 112,136. 4 Liu J J, Li T H, Hao Z B, et al. Surface Technology, 2003, 32(3), 28(in Chinese). 刘建军, 李铁虎, 郝志彪, 等. 表面技术, 2003, 32(3), 28. 5 Zhang X H, Lin C G, Cui S, et al. Acta Armamentarii, 2013, 34(3), 365(in Chinese). 张雪辉, 林晨光, 崔舜, 等. 兵工学报, 2013, 34(3), 365. 6 Kang H. Journal of Nuclear Materials, 2004, 335(1), 1. 7 Peng X M, Xia C Q, Wu A R, et al. The Chinese Journal of Nonferrous Metals, 2015, 25(6), 1567(in Chinese). 彭小敏, 夏长清, 吴安如, 等. 中国有色金属学报, 2015, 25(6), 1567. 8 Wu Y, Yu G, He X L, et al. Rare Metal Materials and Engineering, 2012, 41(7), 1211(in Chinese). 武扬, 虞钢, 何秀丽, 等. 稀有金属材料与工程, 2012, 41(7), 1211. 9 Allahyarzadeh M H, Aliofkhazraei M, Rezvanian A R, et al. Surface and Coatings Technology, 2016, 307, 978. 10 Zhang X F. Preparation and performance of plasma-oriented tungsten coating in fusion reactor. Master’s Thesis, Jingdezhen Ceramic Institute, China, 2012(in Chinese). 张小锋. 聚变堆中面向等离子体钨涂层的制备及其性能研究. 硕士学位论文, 景德镇陶瓷学院, 2012. 11 Li B S, Li D D, Mei T Y, et al. Results in Physics, 2019, 13, 102375. 12 Horwath J A. Thin Solid Films, 1980, 73(1), 79. 13 Yang Z X, Liu G M, Yan T, et al. Surface Technology, 2015, 44(5), 20(in Chinese). 杨忠须, 刘贵民, 闫涛, 等. 表面技术, 2015, 44(5), 20. 14 Liu Y S, Xu H, Li J, et al. High Power Laser and Particle Beams, 2014, 26(12), 227(in Chinese). 刘艳松, 许华, 李俊, 等. 强激光与粒子束, 2014, 26(12), 227. 15 Shetty A R, Hegde A C. Materials Science for Energy Technologies, 2018, 1, 97. 16 Yan T, Liu G M, Zhu S, et al. Materials Protection, 2018, 51(2), 31(in Chinese). 闫涛, 刘贵民, 朱硕, 等. 材料保护, 2018, 51(2), 31. 17 Siopis M, Neu Richard W. IEEE Transactions on Magnetics, 2013, 49(8), 4831. 18 Yan T, Liu G M, Wu X, et al. China Surface Engineering, 2017, 30(1), 107(in Chinese). 闫涛, 刘贵民, 吴行, 等. 中国表面工程, 2017, 30(1), 107. 19 Yan T, Liu G M, Zhu S, et al. Electroplating & Finishing, 2018, 37(2), 93(in Chinese). 闫涛, 刘贵民, 朱硕, 等. 电镀与涂饰, 2018, 37(2), 93. 20 Duan Y H. Study on interface characteristics and biological characteristics of enamel coated artificial prosthesis. Master’s Thesis, The Fourth Military Medical University, China, 2011(in Chinese). 段永宏. 钽涂层人工假体界面特性及生物学特性的研究. 硕士学位论文, 第四军医大学, 2011. 21 Yu X, Tan L, Yang H, et al. Journal of Alloys and Compounds, 2015, 644, 698. 22 Song J, Zhang P Z, Wei D B, et al. Materials Characterization, 2014, 98, 54. 23 Li C Y, Huang J F, Lu J, et al. Corrosion Science, 2012, 63(1), 182. 24 Pan T J, Chen Y, Zhang B, et al. Applied Surface Science, 2016, 369, 320. 25 Zhang C H, Zhang S, Zhang X C, et al. Rare Metals, 2004, 28(5), 852(in Chinese). 张春华, 张松, 张希川, 等. 稀有金属, 2004, 28(5), 852. 26 Dai J, Li S, Zhang H, et al. Surface and Coatings Technology, 2018, 344, 479. 27 Yang G J, Gao P H, Li C X, et al. Scripta Materialia, 2012, 66(10), 777. 28 Wang G, Gu K, Huang Z, et al. Materials Letters, 2016, 185, 363. 29 Zhao J, Chen X M, Wu Y M, et al. Ordnance Material Science and Engineering, 2017, 40(2), 100(in Chinese). 赵坚, 陈小明, 吴燕明, 等. 兵器材料科学与工程, 2017, 40(2), 100. 30 Basak A K, Celis J P, Ponthiaux P, et al. Surface & Coatings Technology, 2012, 558(16), 377. 31 Human A M, Exner H E. Materials Science and Engineering:A, 1996, 209, 180. 32 Wang G, Xing C, Tao F, et al. Surface & Coatings Technology, 2016, 305, 62. 33 Wang H B, Lu H, Song X Y, et al. Corrosion Science, 2019, 147, 372. 34 Hu R, Li J S, Li J X, et al. The Chinese Journal of Nonferrous Metals, 2001, 11(z2), 172(in Chinese). 胡锐, 李金山, 李进学, 等. 中国有色金属学报, 2001, 11(z2), 172. 35 Zhou W Y, Yi M Z, Ran L P, et al. The Chinese Journal of Nonferrous Metals, 2015, 25(4), 990(in Chinese). 周文艳, 易茂中, 冉丽萍, 等. 中国有色金属学报, 2015, 25(4), 990. 36 Zhao Z Y, Hui P F, Wang T, et al. Applied Surface Science, 2018, 462, 48. 37 Zhang E G, Huang B, Zhou Q. Journal of Ceramics, 2017, 38(1), 8(in Chinese). 张而耕, 黄彪, 周琼. 陶瓷学报, 2017, 38(1), 8. 38 He H W, Zhou K C, Xiong X. Rare Metal Materials and Engineering, 2004, 33(5), 490(in Chinese). 何捍卫, 周科朝, 熊翔. 稀有金属材料与工程, 2004, 33(5), 490. 39 Nyberg H, Tokoroyama T, Wiklund U, et al. Surface and Coatings Technology, 2013, 222, 48. 40 Yin H F, Yang Y N. Acta Materiae Compositae Sinica, 2014, 31(5), 1258(in Chinese). 尹洪峰, 杨祎诺. 复合材料学报, 2014, 31(5), 1258. 41 Wang Y, Xu Y D, Wang Y G, et al. Materials Letters, 2010, 64(19), 2068. 42 Ding M H. Preparation and evaluation of TaC and TaN based coatings on medical 316L stainless steel surfaces. Master’s Thesis, Harbin Enginee-ring University, China, 2010(in Chinese). 丁明惠. 医用316L不锈钢表面TaC及TaN基涂层的制备与评价. 硕士学位论文, 哈尔滨工程大学, 2010. 43 Wang L. The effect of tungsten content on the tribological properties of CrWN coating under different lubrication conditions. Master’s Thesis, China University of Geosciences, China, 2018(in Chinese). 王莉. 钨含量对CrWN涂层在不同润滑条件下的摩擦学性能影响研究. 硕士学位论文,中国地质大学, 2018. 44 Hsieh T H, Zhu Y J, Yu Z H, et al. Journal of Nanoscience and Nanotechnology, 2017, 17(7), 5031. 45 Wu F B, Tien S K, Lee J W, et al. Surface and Coatings Technology, 2006, 200(10), 3194. 46 Bao G L, Zhang D T, Qiu C, et al. Hot Working Technology, 2018, 47(24), 119(in Chinese). 包改磊, 张大童, 邱诚, 等. 热加工工艺, 2018, 47(24), 119. 47 Zhang J, Zheng R B, Zhang Z, et al. Hot Working Technology, 2015, 44(14), 207(in Chinese). 张杰, 郑荣部, 张政, 等. 热加工工艺, 2015, 44(14), 207. 48 Yang K M, Wang J X, Yang S Y, et al. Ceramics International, 2015, 354, 324. 49 Zhao Y, Zhou L, Zhang T, et al. Journal of Chongqing University of Technology(Natural Science), 2019, 33(3),155(in Chinese). 赵洋, 周林, 张涛, 等. 重庆理工大学学报(自然科学), 2019, 33(3), 155. 50 Sakidja R, Perepezko J H, Kim S, et al. Acta Materialia, 2008, 56(18), 5223. 51 Ouyang G Y, Ray P K, Srinivasa T, et al. Applied Surface Science, 2019, 470, 289. 52 Xiao L R, Li W, Xu L L, et al. Materials Science and Engineering of Powder Metallurgy, 2011, 16(6), 843(in Chinese). 肖来荣, 李威, 许谅亮, 等. 粉末冶金材料科学与工程, 2011, 16(6), 843. 53 Mao X Z. Study on the properties of Mo5Si3 enhanced MoSi2-based nano/nano gradient composite coatings. Master’s Thesis, Nanjing University of Aeronautics and Astronautics, China, 2012(in Chinese). 毛相震. Mo5Si3增强MoSi2基纳米/纳米梯度复合涂层性能的研究. 硕士学位论文, 南京航空航天大学, 2012. 54 Deng W, Zhao X Q, Li S J, et al. China Surface Engineering, 2017, 30(5), 110(in Chinese). 邓雯, 赵晓琴, 李双建, 等.中国表面工程, 2017, 30(5), 110. 55 Li Y C, Qiu M, Miao Y W, et al. Modern Manufacturing Engineering, 2015(6), 22(in Chinese). 李迎春, 邱明, 苗艳伟, 等. 现代制造工程, 2015(6), 22. 56 Gao G Y, Cao J. Paint & Coatings Industry, 2017, 47(5), 34(in Chinese). 高刚毅, 曹均. 涂料工业, 2017, 47(5), 34. 57 Lian Y, Chen H, Deng J, et al. International Journal of Refractory Me-tals and Hard Materials, 2018, 72, 286. 58 Wang Y, Shang X J, Tian X Q, et al. Rare Metals and Cemented Carbides, 2018, 46(5), 30(in Chinese). 王茵, 尚晓娟, 田兴强, 等. 稀有金属与硬质合金, 2018, 46(5), 30. 59 Long Q, Luo J, Li X L, et al. Electroplating & Finishing, 2018, 37(8), 359(in Chinese). 龙琼, 罗君, 李小丽, 等. 电镀与涂饰, 2018, 37(8), 359. 60 Li D L, Zhou F, Yu S H. High Power Laser and Particle Beams, 2016, 28(2), 190(in Chinese). 李栋梁, 周芳, 余师豪. 强激光与粒子束, 2016, 28(2), 190. 61 Cheng J B, Liang X B, Xu B S. Surface and Coatings Technology, 2014, 240,184. 62 An X L, Liu Q B, Zheng B. Infrared and Laser Engineering, 2014, 43(4), 1140(in Chinese). 安旭龙, 刘其斌, 郑波. 红外与激光工程, 2014, 43(4), 1140. 63 Zhou F, Liu Q B, Zheng B. High Power Laser and Particle Beams, 2015, 27(11), 272(in Chinese). 周芳, 刘其斌, 郑波. 强激光与粒子束, 2015, 27(11), 272. 64 Tunes M A, Vishnyakov V M. Materials & Design, 2019, 170, 107692. 65 Zhang F. Preparation of refractory metal coatings by plasma spraying and their microstructure and properties. Master’s Thesis, Lanzhou University of Technology, China, 2018(in Chinese). 张帆. 等离子喷涂制备难熔金属涂层及其组织和性能的研究. 硕士学位论文, 兰州理工大学, 2018. 66 Yang E B, Jia G, Wang B M, et al. Hot Working Technology, 2018, 47(20),160(in Chinese). 杨二斌, 贾刚, 王伯铭, 等. 热加工工艺, 2018, 47(20), 160. 67 Jian Z H, Ma Z, Wang F C, et al. Ordnance Material Science and Engineering, 2007, 30(2), 27(in Chinese). 简中华, 马壮, 王富耻, 等. 兵器材料科学与工程, 2007, 30(2), 27. 68 Lv Y H, Zhang Q F. Powder Metallurgy Industry, 2018, 28(4), 31(in Chinese). 吕艳红, 张启富. 粉末冶金工业, 2018, 28(4), 31. 69 Wu Y M, Chen X M, Zhou X L, et al. Transactions of Materials and Heat Treatment, 2016, 37(10), 165(in Chinese). 吴燕明, 陈小明, 周夏凉, 等. 材料热处理学报, 2016, 37(10), 165. 70 Huang P K, Yeh J W, Shun T T, et al. Advanced Engineering Materials, 2004, 6(1-2), 74. 71 King D J M, Middleburgh S C, Mcgregor A G, et al. Acta Materialia, 2016, 104, 172. 72 Liu K, Li Y J, Wang J, et al. Materials & Design, 2015, 87, 66. 73 Zhang M N, Zhou X L, Yu X N, et al. Surface and Coatings Technology, 2017, 311, 321. 74 Qi P B, Liang X B, Tong Y G, et al. Applied Laser, 2018, 38(3), 382(in Chinese). 漆陪部, 梁秀兵, 仝永刚, 等. 应用激光, 2018, 38(3), 382. 75 Du J H, Li Z X, Zhou H, et al. Cemented Carbide, 2003, 20(3), 165(in Chinese). 杜继红, 李争显, 周慧, 等. 硬质合金, 2003, 20(3), 165. 76 Zhang Z L, Li Z S, He Q B, et al. Surface Technology, 2005, 34(4), 43(in Chinese). 张昭林, 李忠盛, 何庆兵, 等. 表面技术, 2005, 34(4), 43. 77 Liu Y H, Zhang Y C, Ge C C. Materials Science and Engineering of Powder Metallurgy, 2011, 16(3), 315(in Chinese). 刘艳红, 张迎春, 葛昌纯. 粉末冶金材料科学与工程, 2011, 16(3), 315. 78 Ganne T, Jérme Crépin, Serror S, et al. Acta Materialia, 2002, 50(16), 4149. 79 Maier H, Luthin J, Balden M, et al. Surface & Coatings Technology, 2001, 142-144, 733. 80 Tsai M H, Yeh J W, Gan J Y. Thin Solid Films, 2008, 516(16), 5527. 81 Jones M, Cockburn A, Lupoi R, et al. Materials Letters, 2014, 134, 295. 82 Li Z H, Yang L J, Li B, et al. Chinese Journal of Lasers, 2015, 42(11), 158(in Chinese). 李祉宏, 杨理京, 李波, 等. 中国激光, 2015, 42(11), 158. 83 Wang W Z. Research on aging and peeling of thermal insulation coatings for power motor cores. Master’s Thesis, Hefei University of Technology, China, 2018(in Chinese). 王文哲. 动力电机铁芯再制造绝缘涂层老化与剥离研究. 硕士学位论文, 合肥工业大学, 2018. 84 Li X F. Cemented Carbide, 2001(3), 167(in Chinese). 李学芳. 硬质合金, 2001(3), 167. 85 Shemi A, Magumise A, Ndlovu S, et al. Minerals Engineering, 2018, 122, 195. 86 Freemantle C S, Sacks N. Journal of the Southern African Institute of Mining and Metallurgy, 2015, 115(12), 1207. 87 Luo L, Miyazaki T, Shibayama A, et al. Minerals Engineering, 2003, 16(7), 665. 88 Li M, Xi X, Nie Z, et al. Recovery of tungsten from WC-Co hard metal scraps using molten salts electrolysis. Journal of Materials Research and Technology, 2018, 10, 10. 89 Dai Y Y, Zhong H, Zhong H Y. Nonferrous Metals, 2009, 61(3), 87(in Chinese). 戴艳阳, 钟晖, 钟海云. 有色金属, 2009, 61(3), 87. 90 Wang J J, Wang X H, Zhang Y, et al. Rare Metals, 2015, 39(3), 251(in Chinese). 汪加军, 王晓辉, 张盈, 等. 稀有金属, 2015, 39(3), 251. |
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