MATERIALS AND SUSTAINABLE DEVELOPMENT:ENVIRONMENT-FRIENDLY MATERIALS AND MATERIALS FOR ENVIRONMENTAL REMEDIATION |
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Recent Advances of Aerogels Based Oil Adsorption Materials |
LIU Wei1,2, CUI Sheng1,2,3, LI Jianping4, YE Xin1,2, SHANG Sisi1,2, YANG Zhaojun4, SHEN Xiaodong1,2,3
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1 College of Materials Science and Engineering, Nanjing Tech University,Nanjing 211800, China 2 Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites, Nanjing 211800, China 3 Suqian Advanced Materials Institute, Nanjing Tech University, Suqian 223800, China 4 Suqian Meida Purification Technology Co., Ltd, Suqian 223800, China |
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Abstract Oil pollution has caused serious damage to water, and its treatment has always been a research hotspot at domestic and abroad. In-situ bur-ning, microbial degradation, and adsorption methods are often used in the treatment of oil pollution. Among them, the adsorption of oil causes widespread concern due to low cost, high efficiency, easy to recycle, and has no negative impact on the environment. Traditional oil adsorption materials, natural organic adsorbents such as kapok fiber has low oil absorption capacity and poor hydrophilicity, inorganic adsorbents such as zeolite exhibit poor floatability and slow kinetics, Synthetic organic adsorbents such as polypropylene fibers are non-biodegradable. Therefore, there is an urgent need to develop an adsorbent having excellent selective adsorption, high adsorption capacity, and appropriate recyclability. Compared with traditional adsorption materials, aerogels have the advantages of light weight, large adsorption capacity and high selective adsorption, which have become the hotspots in recent years. Research on aerogels based oil adsorption materials mainly include: SiO2 aerogel, cellulose aerogel, carbon aerogel and graphene aerogel. The above four aerogel oil-absorbing materials have their own advantages and disadvantages. SiO2 aerogel has low cost, but its oil adsorption capacity is much lower than other types of aerogels. Bio-based aerogel has wide source and environmental friendliness, but it’s mechanical strength is low and fragile. Carbon aerogels are chemically inert and not easily contaminated, but equipment and processes are complex and some raw materials are toxic. Graphene aerogel has the largest adsorption capacity in aerogels, but its high cost limits its large-scale use. Researchers have promoted the application of aerogels in actual oil treatment through the combination of different materials, the choice of raw mate-rials and the simplification of the process. In this paper, the research progress of various aerogels in oil adsorption is summarized. The modification process and oil absorption perfor-mance of aerogels are introduced. The adsorption properties and adsorption kinetics of organic/inorganic silicon based aerogel and graphene ae-rogel for oils are discussed and compared. In addition, the future development of aerogels based oil adsorption materials are also prospected.
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Published: 27 April 2020
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Fund:This work was financially supported by the Major Projects of Natural Science Research in Universities in Jiangsu Province (15KJA430005), Key Research and Development (Industry Prospect and Common Key Technologies) Projects of Jiangsu Province (BE2016171, BE2017151), Suqian Science and Technology Project (M201704). |
About author:: Wei Liu received her B.S. degree in applied chemistry from Southwest University of Science and Technology in 2018. He is currently pursuing her master’s degree at the College of Materials Science and Engineering, Nanjing Tech University under the supervision of Prof. Sheng Cui. Her research has focused on Aerogel oil absorption. Sheng Cui, professor, Ph.D. supervisor and asso-ciate dean of the School of Materials Science and Enginee-ring, Nanjing Tech University. The young and middle-aged science and technology leader of the “333 Project” in Jiangsu Province and the outstanding young backbone teacher of the Qinglan Project in Jiangsu Province. In June 2002, he graduated from the School of Materials Science and Engineering of Nanjing Tech University. In December 2006, he obtained a Ph.D. in Materials Science from Nanjing Tech University, and a postdoctoral research at Nanjing Tech University from 2007 to 2008. He is a visiting research scientist at the Georgia Institute of Technology in the United States. He is mainly engaged in the research of aerogels, functional composites and nanomaterials, He has won the second prize of technical invention of the Ministry of Education. He has published more than 200 research papers in academic journals such as Energy & Environmental Science, Chemical Communications, Cellulose, Chemical Engineering Journal, Applied Energy. Xiaodong Shen, the professor, Ph.D. supervisor and dean of the School of Materials Science and Enginee-ring, Nanjing Tech University. The chief scientist of the national “973” project, the director of the education minister Jiang Scholar and the head of the innovation planning team. He is also the vice president of the China Thermal Insulation Materials Association, the chief expert, the president of the aerogel material branch, the vice chairman of the China Silicate Society Cement Branch, and the vice chairman of the Thermal Insulation Branch. Vice Chairman of the Jiangsu Institute of Silicate, etc. He has published more than 300 academic papers, and has been authorized to have 40 invention patents in China, 5 invention patents in the United States, Japan and Europe, and 5 monographs. He has won the second prize of National Science and Technology Progress Award, the second prize of technical invention of the Ministry of Education, and the first prize of Jiangsu Science and Technology Progress Award. The main research direction is advanced silicate materials, including low energy consumption preparation and high efficiency application of cement, research and application of nano aerogel materials. |
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