磁性聚苯胺复合材料对工业废水中重金属吸附的研究进展

doi:10.11896/cldb.19050056

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Abstract With the rapid development of industry, a large number of wastewater containing heavy metal ions are discharged from metal plating, fertilizer manufacturing, batteries, mining and other industries, which not only seriously pollutes the environment but also endangers human health. Therefore, the preparation of new adsorbents with good adsorption effect, simple operation and recoverable has always been the focus of research.
In recent years, there have been many methods to remove heavy metal ions from wastewater, such as redox method, chemical precipitation method, ion exchange method, membrane separation method and adsorption method. Among many methods available, adsorption is considered to be a very promising technique for heavy metals removal since its easy synthetise, low cost and high efficiency. However, conventional adsorbents are difficult to meet the increasingly stringent environmental regulations to treat the heavy metal wastewaters. Therefore, development of new adsorbent material with good adsorption efficiency, simple operation and recoverable has always been the focus of research.
Magnetic nanoparticles with large surface areas, high adsorption capacities and good magnetic properties, which can be quickly separated from liquid phase with external magnetic forces and no secondary pollution. However, magnetic nanoparticles are prone to agglomeration in solution due to their high surface activities and magnetic interaction, which limits the application of magnetic nanoparticles as adsorbents in wastewater treatment. Polyaniline is a polyamine polymer with good adsorption properties for heavy metal ions. The introduction of polyaniline into magnetic nanoparticles can not only improve the dispersion and stability of magnetic nanoparticles, but also improve the adsorption performance of magne-tic nanoparticles for heavy metal ions in wastewater.
In this paper, the structure, properties and preparation methods of magnetic polyaniline composites are summarized. The factors influencing the adsorption of heavy metal ions by magnetic polyaniline composites, such as the synthesis conditions, morphology and adsorption conditions of magnetic polyaniline composites, are also discussed. Finally, the problems to be solved in the treatment of industrial wastewater by magnetic polyaniline composites are analyzed, and the development trend of the material is prospected, which will provide more sufficient theoretical basis for the treatment of wastewater containing heavy metal ions.

Key words： magnetic nanoparticle polyaniline industrial wastewater adsorption heavy metal ions

Published: 27 April 2020

CLC number:

O482.54

Fund:This work was financially suported by the National Natural Science Foundation of China (51703088),Gansu University Research Project (2017A-010),Key Laboratory of Polymer Materials Opening Fund Project in 2018 (KF-18-03),Hongliu Youth Fund of Lanzhou University of Technology(061805),Doctoral Research Start-up Fee (061602).

About author:: Wenjuan Zhang is an associate researcher and master’s supervisor in the State Key Laboratory for Advanced Processing and Reuse of Nonferrous Metals, Lanzhou University of Technology. In 2015, she received her Ph. D. degree from Akita Prefectural University in Japan. Her research interests are mainly on preparation and application of magnetic nanomaterials.
Youliang Wang received his Ph.D. in the Akita Prefectural University, Akita, Japan in 2016. After that he works as a lecturer in the School of Mechanical and Electronical Engineering, Lanzhou University of Technology, Lanzhou, China. His research interests are mainly on the preparation and application of nanometer magnetic materials.

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	ZHANG Wenjuan
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Cite this article:

ZHANG Wenjuan,FEI Yulong,WANG Youliang, et al. Research Progress on the Adsorption of Heavy Metals in Industrial Wastewater by Magnetic Polyaniline Composites[J]. Materials Reports, 2020, 34(9): 9012-9018.

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http://www.mater-rep.com/EN/10.11896/cldb.19050056 OR http://www.mater-rep.com/EN/Y2020/V34/I9/9012

1 Xu X, Cao Z, Zhang Z. Marine Pollution Bulletin,2016,110,596.
2 Yang C M, Wu Y Q, Zhang F, Chemical Speciation & Bioavailability,2016,28,133.
3 Zhang Z, Li J Y, Mamat Z, Ecotoxicology and Environmental Safety,2016,126,94.
4 Li X G, Dou Q, Huang M R, Progress Chemistry,2008,20(2/3),228(in Chinese).
李新贵,窦强,黄美荣.化学进展,2008,20(2/3),228.
5 Fang X H. Preparation of polyaniline/carbon composites and their performances in heavy metal removal from water. Master’s Thesis, Dalian University of Technology, China,2013(in Chinese).
房晓红.聚苯胺/碳复合材料的制备及去除水中重金属的性能研究.硕士学位论文,大连理工大学,2013.
6 Jain M, Garg V K, Kadirvelu K. International Journal of Environmental Science and Technology,2016,13,493.
7 Zarghamia Z, Akbaria A, Latifib A M. Bioresource Technology,2016,205,230.
8 Jiang J, Ai L H. Materials Letters,2008,62,3643.
9 Yang F, Chen J, Wu S, et al. New Chemical Materials,2018,46(11),234(in Chinese).
杨帆,陈均,吴思,等.化工新型材料,2018,46(11),234.
10 Xu Y. Product of HCl doped polyaniline/attapulgite nanocompo-sites and study on adsorption properties. Master’s Thesis, Lanzhou University of Technology, China,2011(in Chinese).
徐垚.盐酸掺杂聚苯胺/凹凸棒土纳米复合材料的制备及其吸附性能的研究.硕士学位论文,兰州理工大学,2011.
11 Ehsan Nazarzadeh Zare, Ahmad Motahari. Environmental Research,2018,162,173.
12 Gu S Y, Ren J. Polymer matrix composites, Chemical Industry Publisher,2007(in Chinese).
顾书英, 任杰.聚合物基复合材料,化学工业出版社,2007.
13 Bao L, Jiang J S. Physica B,200,367,182.
14 Tang B Z, Geng Y H, Sun Q H, et al. Pure and Applied Chemistry,2000,72(1-2),57.
15 Deng J G, He C L, Peng Y X, et al. Synthetic Metals,2003,139,295.
16 Deng J G, Din X B, Zhang W C, et al. Polymer,2002,43,2179.
17 Zhang Yijing, Lin Yenwen, Chang Chiachih, et al. Synthetic Metals,2010,160,1086.
18 Ding X F, Han D X, Wang Z J, et al. Journal of Colloid and Interface Science,2008,320,341.
19 Zhang Z M, Wan M X. Synthetic Metals,2003,132,205.
20 Singh K, O hl an A, Kotnala R K, et al. Materials Chemistry and Physica,2008,112,651.
21 Song E P. The research on preparation and absorption properties of polyaniline. Master’s Thesis, Xidian University, China,2014(in Chinese).
宋恩鹏.聚苯胺的合成及其吸收特性的研究.硕士学位论文,西安电子科技大学,2014.
22 Chen P C. Preparation of magnetic modified polyaniline and its adsorption of heavy metals. Master’s Thesis, Chengdu University of Technology,China,2018(in Chinese).
陈萍超.磁性改性聚苯胺的制备及其吸附重金属.硕士学位论文,成都理工大学,2018.
23 Li R J. Adsorptive removal of Hg(Ⅱ), Cr(Ⅵ) and Pb(Ⅱ) ions from aqueous solutions using nitrogen-containing conductive polymer composites. Ph.D. Thesis, Dalian University of Technology,China,2016(in Chinese).
李仁杰.含氮导电聚合物复合吸附材料去除水中Hg(Ⅱ)、Cr(Ⅵ)和Pb(Ⅱ)离子.博士学位论文,大连理工大学,2016.
24 Manish Chowalla, Hyeon Suk Shin, Goki Eda. Nature Chemistry,2013,5(4),263.
25 Zeng X W, Zhao D L. Function Materials,2004,35(s),605(in Chinese).
曾宪伟,赵东林.功能材料,2004,35(s),605.
26 Luo M N, He X M, Chen F, et al. Applied Chemical Industry,2018,47(9),1847(in Chinese).
罗米娜,何雪梅,陈馥,等.应用化工,2018,47(9),1847.
27 Zhang L, Chen L, Qi B, et al. RSC Advance,2015,5(3),1680.
28 Zhang Z K. Study on the synthesis and adsorption properties of tubular polyaniline. Master’s Thesis, Yangzhou University,2008(in Chinese).
张之魁.管状聚苯胺的合成及吸附性能研究.硕士学位论文,扬州大学,2008.
29 Zhao X, Li J. Journal of Jilin University,2015,53(5),1035(in Chinese).
赵霞,李佳.吉林大学学报,2015,53(5),1035.
30 Zhong W B, Xiong C L. Journal of Hunan University,2017,44(12),70(in Chinese).
钟文斌,熊昌伦.湖南大学学报,2017,44(12),70.
31 Hong X Q. Synthesis of micro/Nano structured conducting polymer/clay composites and their application for removal of Cr (Ⅵ) in aqoeous solution. Master’s Thesis, Anhui University of Technology,China,2014(in Chinese).
洪小琴.微/纳米结构导电聚合物/黏土复合材料的合成及其对水中六价铬的吸附性能研究.硕士学位论文,安徽工业大学,2014.
32 Luo J P, Fan X, Lu W, et al. Polymer Materials Science and Enginee-ring,2017,33(3),85(in Chinese).
罗健萍,樊新,陆唯,等.高分子材料科学与工程,2017,33(3),85.
33 Jonathan N. Coleman, Mustafa Lotya, Arlene O. Neill, Science,2011,331(6017),568.
34 Cui J J. The research on the modification of magnetic chitosan and its adsorption performance of copper ions. Master’s Thesis, Hunan University, China,2016(in Chinese).
崔京京.磁性壳聚糖改性及其对铜离子吸附性能的研究.硕士学位论文,湖南大学,2016.