废弃高抗冲聚苯乙烯高值化再利用的研究进展

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (2057KB)
Export: BibTeX | EndNote (RIS)

Abstract High impact polystyrene (HIPS) plays an important role in the field of polymer plastics due to its excellent mechanical properties. In a few years, its output has been directly equal to that of ABS (acrylonitrile-butadiene-styrene copolymer) polymer resin.As a kind of excellent polymer resin material, HIPS has shown great advantages in engineering(especially in electrical and computer) material field: good dimensional stability; strong heat resistance, good impact toughness; easy processing, and can be processed into various functional materials by adding appropriate fillers. However, the development of science and technology innovation ushered in the rapid development of electronic products. The waste of plastic materials caused the loss of polymer resources and the damage to the natural environment. Therefore, the recycling technology of waste plastics including waste hips has developed rapidly, and the high value reuse of waste hips has also promoted the development of recycled plastics industry. In this paper, the research progress of high-value reuse of waste HIPS at home and abroad is reviewed. The melt blending modification, industrial recycling and incineration pyrolysis recovery of waste HIPS are discussed from the point of view of material and energy regeneration. Among them, melt blending modification is the mainway to realize recycling of waste HIPS resin in China. According to the different blending modification process, it can be divided into physical recycling and physicochemical recycling. According to the different types of blends, it has been initially clear that rubber elastomers, organic materials and inorganic nanomaterials have better single or synergistic modification effect on waste HIPS resin. Generally speaking, the high value reuse of waste HIPS has brought enormous economic and environmental benefits, and plays an active role in promoting the recycling of waste plastics.

Key words： waste HIPS melt blending modification physical regeneration,physicochemical regeneration

Published: 01 July 2020

CLC number:

TB33

Fund:This work was financially supported by Natural Science Foundation of Shanghai (16ZR1412400,15ZR1417100), Gaoyuan Discipline of Shanghai-Environmental Science and Engineering (Resource Recycling Science and Engineering), National Natural Science Foundation of China (51607109), the Key Subject of Shanghai Polytechnic University (Materials Science and Engineering,XXKYS1601).

About author:: Tongshan Zhang, a postgraduate of Shanghai Polytechnic University, participated in the school enterprise cooperation project of Shanghai Re-Mall Environmental New Materials Co., Ltd. In December 2017. In June 2017, she obtained a bachelor's degree in environmental engineering from Henan University of Engineering. In June 2020, she obtained a master's degree in environmental engineering from Shanghai Polytechnic University ; Haiping Xu, female, born in December 1966, doctor, professor. In 1988,she graduated from Tianjin University with a bachelor's degree in inorganic non-metallic materials ; in 2005, she graduated from Taiyuan University of Technology with a doctor's degree in chemical engineering and technology ; in 2007, she graduated from Beijing University of Chemical Technology with a postdoctoral degree in materials science and enginee- ring. Between July 2012 and August 2013, she was a senior visiting scholar at the Institute of Materials, Pennsylvania State University. Since 2008, she has been a teacher in the School of Environment and Material Engineering, Ministry of Engineering, Shanghai Polytechnic University. The research direction is the application and development of functional polymer and its composite materials in energy storage, electronic circuit over-current voltage protection, etc., including dielectric polymer energy storage materials and devices, polymer based thermistor materials and devices, etc. Presided over and completed one key project of basic research of Shanghai Science and Technology Commission, one key project of basic research of Shanghai Education Commission, and two “alliance plans” of Shanghai Science and Technology Promotion Commission.

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZHANG Tongshan
	XU Haiping
	XU Shihao
	LIAO Yangke
	XIONG Wei

Cite this article:

ZHANG Tongshan,XU Haiping,XU Shihao, et al. Research Progress on High Value Reuse of Waste High Impact Polystyrene[J]. Materials Reports, 2020, 34(Z1): 557-562.

URL:

http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2020/V34/IZ1/557

1 李志丹.四官能度过氧化物在高抗冲聚苯乙烯制备中的应用.硕士学位论文,浙江大学,2017.
2 乔冰.废弃家电HIPS和ABS共混体系相容性能与力学性能的研究.博士学位论文,中北大学,2016.
3 Stenvall E, Tostar S, Boldizar A, et al. Waste Management,2013,33(4),16.
4 罗京科,李志杰.橡塑技术与装备,2019,45(4),45.
5 王盼.废旧高抗冲聚苯乙烯的高值化回收再利用.硕士学位论文,中北大学,2016.
6 Cafiero L, Fabbri D, Trinca E, et al. Journal of Thermal Analysis & Ca-lorimetry,2015,121(3),1.
7 秦黎明.石化技术,2012(3),21.
8 次立杰,时伟,高岩磊,等.化工新型材料,2010,38(6),76.
9 时伟,刘占荣,李中秋,等.塑料科技,2015,43(7),36.
10 刘振洋,揣成智.塑料,2016,45(2),51.
11 赵静,魏东亚,王兆波.特种橡胶制品,2013,28(5),9.
12 赵洪玲,王兆波.合成橡胶工业,2010,33(4),289.
13 官习鹏,周魏华,诸泉,等.工程塑料应用,2011,39(1),21.
14 刘晶如,夏阳阳,高力群,等.材料工程,2017,51(5),13.
15 Corrêa A C, De Santi C R, Manrich S. Macromolecular Symposia,2006,245-246(1),611.
16 吴晓露,李迎春,武海花,等.材料导报:研究篇,2018,32(7),183.
17 戴坤添,安瑛,李长金.塑料,2017,86(1),77.
18 王盼,李迎春.高分子材料科学与工程,2015,31(5),77.
19 王盼,李迎春,贺茂勇,等.高分子材料科学与工程,2015,31(5),77.
20 吴晓露.基于老化降解机理的废旧ABS、HIPS改性研究.硕士学位论文,中北大学,2018.
21 Chatterjee A, Mishra S. Journal of Polymer Research,2013,20(10),249.
22 陈烈强,胡亚林.2015年中国环境科学学会学术年会,广州,2010.
23 刘志维,苑会林.塑料工业,2009,37(8),41.
24 张艺馨. HIPS/BRTPV及HIPS/WGRTTPE的制备、结构与性能研究.硕士学位论文,青岛科技大学,2012.
25 Stenvall E, Tostar S, Boldizar A, et al. Waste Management,2013,33(4),915.
26 Hirayama D, Saron C. Waste Management & Research,2015,33(6),543.
27 Miloudi M, Dascalescu L, Li J, et al. IEEE Transactions on Dielectrics and Electrical Insulation,2013,20(5),1510.
28 Hirayama D, Saron C. Polymer,2018,135,271.
29 Perrin D, Mantaux O, Ienny P, et al. Waste Management,2016,DOI:S0956053X16303609.
30 Vazquez Y V, Barbosa S E. Journal of Polymers and the Environment,2016,21(32),31.
31 孔宇飞,李迎春,宋晶晶,等.功能材料,2015,33(24),1.
32 孔宇飞.增容废弃家电PP和HIPS共混体系的结构与性能研究.博士学位论文,中北大学,2018.
33 Kong Y, Li Y, Hu G, et al. Polymer,2018,2(51),31.
34 李迎春,贺茂勇.材料导报:研究篇,2017,63(4),41.
35 李婷婷.HIPS/红麻纤维复合材料性能研究.硕士学位论文,大连工业大学,2013.
36 陈尔凡,白宇,马驰,等.化工新型材料,2016(4),196.
37 罗少刚,王静荣,徐海萍,等.上海第二工业大学学报,2016,33(2),122.
38 Mousavi M, H?gsaa B, Fini E H. Applied Surface Science,2019,473,750.
39 李志杰,罗京科.再生资源与循环经济,2019,12(7),30.
40 Grause G, Fonseca J D, Tanaka H, et al. Polymer Degradation and Stability,2015,112,86.
41 Peng S, Liang S, Yu M, et al. Journal of Material Cycles and Waste Management,2014,16(1),178.
42 Sekhar V C, Nampoothiri K, Mohan A J, et al. Journal of Hazardous Materials,2016,5(398),46.
43 Zulfi A, Munir M M, Hapidin D A,et al. Materials Research Express,2014,5(3),35.
44 Haryono A, Harmami S B. Advanced Materials Research,2012,486,426.
45 Senthil Kumar K, Baskar K. Journal of Hazardous, Toxic, and Radioactive Waste,2015,19(3),04014042.
46 Dachowski R, Kostrzewa P. Procedia Engineering,2016,161,754.
47 Alston S M, Clark A D, Arnold J C, et al. Environmental Science & Technology,2011,45(21),9380.
48 Salbidegoitia J A, Fuentes E G, María P. Journal of Material Cycles & Waste Management,2016,19(2),1.
49 Acomb J C, Nahil M A, Williams P T. Journal of Analytical and Applied Pyrolysis,2013,103,320.
50 Antonakou E V, Kalogiannis K G, Stephanidis S D, et al. Waste Management,2014,34(12),2487.