羟基磷灰石晶体仿生阵列的制备研究进展

doi:10.11896/cldb.19040176

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Abstract Calcium phosphates (CaPs) are ubiquitous in nature and vertebrate bones and teeth, and have high biocompatibility. The fabrication of CaPs with structures mimicking those of the bones and teeth has promising applications in clinic. The successful large-scale preparation of biomi-metic CaP, particularly hydroxyapatite (HAp), may lead to the improvement of properties and structural design of biomedical application mate-rials. Up to now, it is still difficult to synthesize bone-like and enamel-like CaP materials with highly oriented architectures.
Recently, hydroxyapatite (HAp) crystals with hierarchical structures have made great progress in clinical repair of bones and teeth. A series of strategies have been used to synthesize bionic HAp structures. The design of CaP hierarchical organization, have great potential to revolutionize the field of hard tissue engineering. Previously, a number of reviews have reported the synthesis and properties of CaP materials. However, most of them mainly focused on the characterizations and physicochemical and biological properties of HAp particles, e.g. synthesis, characteristics, application, surface modification and control of shape and size of HAp particles. There were few reviews about the control of HAp crystal biomimetic arrays.
The current state of the art for the synthesis of HAp crystals hierarchical organization were reviewed, including the molecule directing mineralization method, solution-induced calcium phosphate (CaP) formation method, hydrothermal/solvothermal method, precursor transformation methods, sol-gel methods and electrochemical deposition methods. In addition, advantages and disadvantages of these methods were discussed. Moreover, the possible directions of future research and development in this field were provided as references for the preparation of biomimetic HAp.

Key words： hydroxyapatite hierarchical structure biomimetic array

Published: 27 April 2020

CLC number:

TB332

Fund:This work was financially supported by the Yunnan University Students Innovation and Entrepreneurship Project (201910674006,201810674002).

About author:: Dingze Chuan received his bachelor’s degree in June 2017 from Xi’an University of Technology. From July 2017 to now, he has studied in School of Materials Science and Engineering, Kunming University of Science and Technology, focusing on the research of biological functional materials.
Qinghua Chen received his Ph.D. degree in Institut National des Sciences Appliquées de Lyon in 1995. He is currently a professor in Kunming University of Science and Technology (KUST). His research inte-rests are cermet composites prepared by sol-gel method and biological functional materials.

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	CHUAN Dingze
	YAN Tingting
	LIU Jinkun
	LIU Jitao
	CHEN Xiliang
	CHEN Qinghua

Cite this article:

CHUAN Dingze,YAN Tingting,LIU Jinkun, et al. Advances in Synthesis of Hydroxyapatite Crystals Biomimetic Arrays[J]. Materials Reports, 2020, 34(9): 9069-9074.

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http://www.mater-rep.com/EN/10.11896/cldb.19040176 OR http://www.mater-rep.com/EN/Y2020/V34/I9/9069

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