铅酸电池负极添加剂的研究进展

doi:10.11896/cldb.19010081

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Abstract In recent years, the environmental pollution and scarcity of fossil energy have led to the continuous development and updation of energy sto-rage equipment. As a new energy storage device, the battery has many advantages in the energy supply. At present, the lithium ion batteries and lead-acid batteries are the most widely used in the secondary battery market. Correspondingly, lithium ion batteries have the advantages of high energy density and low volume and a tendency to surpass lead-acid batteries. However, there are obvious limitations for lithium ion batteries due to the serious attenuation of low-temperature capacity and high-temperature explosion, and the reliability over wide temperature range and low price of lead-acid batteries make them more versatile in the energy industries.
　　The mainly failure modes of lead-acid battery are related to the early capacity loss of positive and negative plates, grid corrosion and lead sulfate sulphation at negative plate. As the common power source for hybrid vehicles, the lead-acid battery needs to be operated at high-rate partial state of charge (HRPSoC) state, where the factor determining the life mainly stems from the invalidation of the negative electrode. The invalidation of the negative plate would result into sharp drop in battery performance and shortened life, and negative additives could solve the negative plate failure problems in different aspects to a certain extent.
　　In this review, recent progress on the study of negative additives for lead-acid battery and existing problems are summarized while the future development tendency is also forecasted. Typical negative additives, which primarily contain carbon materials, conducting polymer, inorganic or metal oxides, could enhance the utilization rate of negative electrode active material (NAM), improve the discharge performance under large current and low temperature situations, and so on. Meanwhile, negative conducting additives could participate part of charge current to slow down the adverse impact under large current. Furthermore, failure mechanism of negative plate including lead sulfation, cycle stability, electrolyte loss could be solved to some extent. Meantime, the disadvantages of the negative additives are also discussed in the review.

Key words： lead-acid battery failure mechanism negative additives battery performance

Published: 16 January 2020

CLC number:

TM912

About author:: Xiaobo Li received his B.E. Degree in engineering from Lanzhou University of Technology in 2017. He is currently pursuing his Master at College of Me-tallurgy and Energy Engineering, Kunming University of Science and Technology under the supervision of Prof. Hui Huang. His research is focused on energy storage electrode materials;Hui Huang received her B.E. degree in Polymer Scie-nce from Sichuan University in 2000, M.S. degree in inorganic material in Yunnan University, and obtained her PhD degree in Metallurgical Physical Chemistry from Kunming University of Science and Technology. She was as a visiting scholar in Florida University from 2014 to 2015. She is currently a full professor in Kunming University of Science and Technology, technical director of Kunming Hendera Technology Co., Ltd., deputy director of Yunnan Metallurgical Electrode Materials Engineering Technology Research Center. Her current research interests include conductive energy-saving polymer anode materials, special functional powder mate-rials, metallurgical electrochemical and hydrometallurgical new materials. At present, she has applied for 21 national invention patents, published 3 academic books and 47 researchpapers, including 35 SCI and EI. She has won many titles including first prize of China Nonferrous Metals Industry Science and Technology Award, third prize of Yunnan Natural Science Award, and third prize of Yunnan Science and Technology Invention Award, Yunling Industrial Technology Leading Talents, yunnan province Young and Middle-aged Technical Innovation Talents of Yunnan Province and Young and Middle-aged Academic and Technical Lea-ders of Kunming;Zhongcheng Guo received his B.E. degree in Non-ferrous Metallurgy from Kunming University of Science and Technology in 1987 and received his PhD. degree from Kunming University of Science and Technology in 2001. In 1998 and 2006, he went to the Department of Materials at Monash University in Australia and the Center for Corrosion and Protection Research at University of Manchester, UK as a visiting scholar. He is currently a professor in Kunming University of Science and Technology, the chairman of Kunming Hendera Technology Co., Ltd., director of Yunnan Metallurgical Electrode Materials Engineering Technology Research Center, director of China Surface Engineering Association, and executive director of China Surface Engineering Association Electroplating Branch. His current research fields cover the research development and achievement transformation in metallurgical physical chemistry, metallurgical new materials, non-ferrous metal special powder materials, surface enginee-ring, materials physical chemistry and other fields. He has won 27 national invention patents and 7 provincial and ministerial-level scientific and technolo-gical achievements awards, published 8 monographs, and published more than 200 academic papers. He has won National Hundred Excellent Doctoral Dissertation Awards from the Ministry of Education, the first prize of the China Nonferrous Metals Industry Science and Technology Award twice, the special prize of Invention and Entrepreneurship Award of China Invention Association, National Ten Thousand Plan (National Innovation and Entrepreneurship Talents), the National New Century Talent Project, the winner of the New Century Excellent Talents Support Program of the Ministry of Education, the Yunnan Provincial Government Special Allowance Winner, and the Yunnan Young and Middle-aged Academic and Technical Leader.

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	LI Xiaobo
	ZHANG Panpan
	HE Yapeng
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Cite this article:

LI Xiaobo,ZHANG Panpan,HE Yapeng, et al. Research Progress in Negative Additives for Lead-acid Batteries[J]. Materials Reports, 2020, 34(5): 5039-5047.

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http://www.mater-rep.com/EN/10.11896/cldb.19010081 OR http://www.mater-rep.com/EN/Y2020/V34/I5/5039

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