固体氧化物燃料电池(SOFC)钛基钙钛矿阳极的研究进展

doi:10.11896/cldb.19050165

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Abstract Fuel cell is an efficient, environmentally friendly power generation system that converts chemical energy directly into electrical energy. The so-lid oxide fuel cell (SOFC) as the fourth generation of the fuel cell with the all-solid-state structure works at medium and high temperature. SOFC exhibits the advantages of wide fuel range, low material cost, long service life, high power generation efficiency and high waste heat utilization value.
　　The SOFC anode provides a place for the electrochemical reaction of the fuel transported from the outside and the oxygen ions transported from the cathode. Developing cost-effective anodes is essential to improve SOFC performance and reduce manufacturing costs. The frequently-used SOFC anode materials include precious metals, Ni-based, Cu-based and perovskites. However, precious metal anodes are more severely constrained by cost. Ni-based anodes tend to undergo carbon deposition when using hydrocarbon fuels, and Cu based anodes suffer the lower electrochemical activity. Perovskite anodes have attracted the attention of researchers due to their stable structure and high resistance to carbon de-position as well as sulfur poisoning, a variety of perovskite anodes have been reported in recent years.
　　Currently, titanium-based perovskites have become hotspots in SOFC anode research field due to their high catalytic activity, electrochemical stability, anti-sulfur poisoning and carbon deposition resistances. However, comparing with the traditional Ni-based anodes, titanium-based pero-vskites still have some limitations, such as low catalytic activity and electrical conductivity. Therefore, titanium-based perovskite anodes cannot meet the demand for the high-power output of SOFC. Doping and compositing are two prevailing modification methods to prepare titanium-based perovskite anode materials with good electrochemical performance.
　　In this paper, the commonly used La-doped strontium titanate, Y-doped strontium titanate and other titanium-based perovskites are outlined and analysed. The modification methods often applied for titanium-based perovskites (such as doping and compounding) are reviewed in detail. The outlooks of the titanium-based perovskites are also presented. This work can give a guideline to develop the titanium-based perovskites with high activity and stability.

Key words： solid oxide fuel cell anode titanium-based perovskite elemental doping in-situ compositing

Published: 16 January 2020

CLC number:

TM911

About author:: Peijian Linreceived his B.S. degree in engineering from Dalian Maritime University in 2017. He is currently pursuing his master's degree at Faculty of Maritime and Transportation, Ningbo University, under the supervision of Prof. Jinliang Yuan. His current research direction is reversible solid oxide fuel cells;Jinliang Yuanreceived his Ph.D. degree in materials from Lund University.He served as professor of energy science at Lund University, Sweden, currently a full professor in Ningbo University. His research interests are coupling study of transfer process and chemical reaction in fuel cell, mesoscopic multiphase transfer and phase transition process of electrode.

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	LIN Peijian
	MIAO He
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Cite this article:

LIN Peijian,MIAO He,WANG Zhouhang, et al. Research Progress on Titanium Based Perovskite Anodes for Solid Oxide Fuel Cell (SOFC)[J]. Materials Reports, 2020, 34(5): 5032-5038.

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http://www.mater-rep.com/EN/10.11896/cldb.19050165 OR http://www.mater-rep.com/EN/Y2020/V34/I5/5032

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