|
|
|
|
|
|
| Research Progress of Conductive Polymer Composites for Resistive Flexible Strain Sensors |
| REN Qinbo1,WANG Jingping1,,YANG Li2,LI Xiang3,WANG Xuechuan4
|
1 Key College of Chemistry and Chemical Engineering,Shaanxi University of Science & Technology,Xi'an 710021,China
2 Key Changqing Oilfield Branch Company of CNPC,The First Oil Transportation Department,Xi'an 710021,China
3 Key School of Electronic Information and Artificial Intelligence,Shaanxi University of Science & Technology,Xi'an 710021,China
4 Key College of Bioresources Chemical and Materials Engineering,Shaanxi University of Science & Technology,Xi'an 710021,China |
|
|
|
Abstract As the tentacles of the internet of things, the sensor is facing the new development opportunity. With the development of the wearable industry, the flexible resistance-strain sensor shows broad application prospects in the fields of human body wearable real-time monitoring, robot bionic skin, medical health tracking, moving limb capture and production vibration detection, etc. Conductive polymer composites are the most commonly used core materials for the flexible resistance-strain sensor, which possess the advantages of excellent flexibility, large strain detection range and low cost.
However, the resistance-strain sensors based on conductive polymer composites have several shortcomings, such as obvious hysteresis, low linearity and unstable conductive network. The conduction mechanism of conductive polymer composites during the strain process was not interpreted clearly. Therefore, many scholars have done a great deal of researches on the fields of conduction mechanism, conductive filler, polymer matrix and preparation process. Currently, the percolation theory has been widely used to explain the conductive behavior of conductive polymer composites for resistance-strain sensor. The conductive fillers of conductive polymer composites mainly include carbon and metal materials. The carbon material is the main conductive filler due to its low cost and stable pathway. The polymer matrixes of conductive polymer composites mainly include silicone rubber, natural rubber and polyurethane. The silicone rubber is often used to the low-strain sensor and the natural rubber is often used to the large-strain sensor. The preparation processes of conductive polymer composites mainly include filling-type, sandwich-type and adsorption-type. The sandwich-type and adsorption-type sensors process a low strain range and the filling-type sensor processes a large strain range.
The conduction mechanism, conductive filler, polymer matrix and preparation process of conductive polymer composites for flexible resistance-strain sensor are summarized and analyzed in this paper. The research hotspots and the future development trend of conductive polymer compo-sites are prospected.
|
|
Published: 15 January 2020
|
|
|
| Fund:This work was financially supported by the National Natural Science Foundation of China (21776169), Science and Technology Plan Project of Xi'an (2017068CG/RC031〈SXKD007〉), Ph.D. Start Fund of Shaanxi University of Science and Technology (BJ16-10). |
About author:: Qinbo Ren received his B.E. degree in Polymer mate-rials and engineering from Shaanxi University of Science & Technology in 2016. He is currently pursuing his Master's degree at the college of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology under the supervision of Associate Professor Jingping Wang. His research has focused on conductive polymer composites for resistive flexible sensors.
Jingping Wang received his B.E. degree in Polymer Materials from Dalian Polytechnic University in 1997, received his Ph.D. degree in Electronic Science and Technology from the School of Electronics and Information, Xi'an Jiaotong University, in 2011. After two-year postdoctoral research at The Hong Kong Polytechnic University, he is currently an associate professor in Shaanxi University of Science & Technology. His research interests are molding of polymer materials and energy storage polymer material and electrochemical wastewater treatment.
Xuechuan Wang received his B.E. degree in Chemical industry from Shaanxi University of Science & Technology in 1984 received his Ph.D. degree from the Sichuan University, in 2003. In 1999, he conducted a three-month cooperation visit at the BOEHME Leather Research Center in Germany. In 2007, he was elected to the National Science and Technology Department's “National Talents of the New Century Talent Project”. In 2011, he was hired as a second-level professor and was awarded “Outstanding Contribution Expert of Shaanxi Province”. In 2012, he was granted special government allowance from the State Council. In April 2015, he served as vice president Shaanxi University of Science & Technology. His research interests include Synthesis theory and mechanism of environmentally friendly fine chemicals and animal protein biomass resource and leather clean production. |
|
|
1 Wang S, Chung D D L. Carbon, 2006, 44(13),2739.
2 Gao S W, Gao D K, Liang Y, et al. Journal of Shenyang University of Technology, 2006(2), 16(in Chinese).
高松巍,高登奎,梁昱,等.沈阳工业大学学报, 2006(2), 16.
3 Xie Y, Liu X L, Chen X M, et al.Instrument Technique and Sensor, 2004(9),1(in Chinese).
解源,刘晓玲,陈学梅,等.仪表技术与传感器, 2004(9),1.
4 Zhou L Z, Zheng Y, Song G B, et al. Construction and Building Mate-rials, 2019,220,615.
5 Ritwik P, Matt Z, vinary S, et al. Macromolecular Chemistry and Phy-sics, 2019, 220(17) ,n/a.
6 Habib A, Shelke A, Amjad U, et al. Applied Sciences, 2018, 8(9),1683/1.
7 Villmow T,John A, Poetschke P, et al.Polymer, 2012, 53(14), 2908.
8 Wei G F.Mixed gas detection and analysis based on micro-hot plate gas sensor. Master's Thesis, Dalian University of Technology, China, 2006 (in Chinese).
魏广芬, 基于微热板式气体传感器的混合气体检测及分析. 硕士学位论文, 大连理工大学,2006.
9 Ma J, Zhou Y L, Bai X, et al. Nanoscale, 2019, 11(34),15821.
10 Lee S W, Lee W, Lee H G, et al. Sensors and Actuators B: Chemical, 2018, 255,1788.
11 Zhu L, Zeng W. Sensors and Actuators A: Physical, 2017, 267, 242.
12 Singh E, Meyyappan M, Nalwa H S. ACS Applied Materials & Interfaces, 2017, 9(40),34544.
13 Lone M Y, Kumar S, Husain M, et al. Physica E: Low-dimensional Systems and Nanostructures, 2017, 87,261.
14 Kumar R, AvasthiD K, Kaur A. Sensors and Actuators B: Chemical, 2017, 242,461.
15 Abideen Z U, Kim J H, Lee J H, et al. Journal of the Korean Ceramic Society, 2017, 54(5),366.
16 Nishio M, Sawaya S, Akita S, et al. Applied Physics Letters, 2005, 86(13),133111.
17 Lu H Z. Study on indoor air quality detection sensor of quartz crystal microbalance. Master's thesis, Dalian University of Technology, China, 2005 (in Chinese).
卢好正. 石英晶振微天平室内空气质量检测传感器的研究. 硕士学位论文, 大连理工大学,2005.
18 Li S Y, Chen S J, Zhou B G, et al. IEEE Electron Device Letters, 2017, 38(7),975.
19 Gao X, Wang M J, Fan B W. In: 2017 International Conference on Green Energy and Sustainable Development,Chongqing, 2017,pp.1864.
20 Yamada T, Hayamizu Y, Yamamoto Y, et al.Nature Nanotechnology, 2011, 6(5),296.
21 Wang T, Feng W W, Luo D C. Techniques of Automation and Applications, 2009, 28(8), 83(in Chinese).
王婷, 冯文武, 罗德超, 等. 自动化技术与应用, 2009, 28(8),83.
22 Wang H M, Li D, Zhong W. et al. ACS Applied Materials & Interfaces, 2019, 11(37),34251.
23 Sun L J, Chen S, Guo Y F, et al. Nano Energy, 2019, 63,103847.
24 Peng Y J, Yan B, Li Y S, et al. Journal of Materials Science, 2019, 55(3),1280.
25 Wang Y J, JiaY Y, Zhou Y J, et al. Journal of Materials Chemistry C, 2018, 6(30), 8160.
26 Nie M, Xia Y H, Yang H S.Cluster Computing, 2019, 22(4), 8217.
27 Li Y Q, Huang P, Zhu W B, et al.Scientific Reports, 2017, 7,45013.
28 Wang H T, Tong Y H, Zhao X L, et al.Organic Electronics, 2018,61, 304.
29 Park S J, Kim J, Chu M, et al.Advanced Materials Technologies, 2016, 1(5), n/a.
30 Wang Z, Huang Y, Sun J, et al.ACS Applied Materials & Interfaces, 2016, 8(37), 24837.
31 Yu X G, Li Y Q, Zhu W B, et al.Nanoscale, 2017, 9(20),6680.
32 Midya A, Gogurla N, Ray S K.Current Applied Physics, 2015, 15(6),706.
33 Hu Y G.Nano Research, 2018, 11(4),1938.
34 Hurtado N M C, Zarifi M H, Daneshmand M, et al. IEEE Sensors Journal, 2017, 99,1.
35 Yi H X.Construction and test of wearable wireless network based on knitted flexible sensor. Master's thesis, Donghua University, China, 2015 (in Chinese).
易红霞. 基于针织柔性传感器可穿戴式无线网络的构建与测试. 硕士学位论文,东华大学,2015.
36 Pegan J D, Zhang J, Chu M, et al.Nanoscale, 2016, 8(39), 17295.
37 Zhang B, Li B, Jiang S.Journal of Electronic Materials, 2017, 46(10),5737.
38 Yokota T, Zalar P, Kaltenbrunner M, et al.Science Advances, 2016, 2(4),e150156.
39 Roh E, Hwang B U, Kim D, et al. ACS Nano, 2015, 9(6),6252.
40 Li Z, Jiao W H, Qian L H, et al. Nano Research, 2015, 8(9),2978.
41 Lu J R, Wu D J, Chen G H.Plastics, 2004,33(5),43(in Chinese).
卢金荣, 吴大军, 陈国华. 塑料, 2004, 33(5),43.
42 Yang J G, Liu C C,Shi K.Modern Chemical Research, 2006(2),13 (in Chinese).
杨建高, 刘成岑, 施凯.化工中间体, 2006(2),13.
43 Tang H, Chen X F, Luo Y X. Polymer Materials Science and Enginee-ring, 1996, 12(2),1 (in Chinese).
汤浩, 陈欣方, 罗云霞. 高分子材料科学与工程, 1996, 12(2),1.
44 Liang Z J, Yang S S.Journal of South China University of Technology(Natural Science Edition), 2007(8),84 (in Chinese).
梁基照, 杨铨铨.华南理工大学学报(自然科学版), 2007(8),84.
45 Ye M Q, He L L, Han A J,et al. New Chemical Materials, 2008, 36(11),13 (in Chinese).
叶明泉, 贺丽丽, 韩爱军, 等.化工新型材料, 2008, 36(11),13.
46 Liu S J, Xue Q Z.Journal of China University of Petroleum(Edition of Natural Science), 2005, 29(1),140 (in Chinese).
刘金世, 薛庆忠.石油大学学报(自然科学版), 2005, 29(1),140.
47 Diwan P, Chandra A.Polymer Composites, 2012, 33(10),1750.
48 Aharoni, Shaul M.Journal of Applied Physics, 1972, 43(5),2463.
49 Shao P W, Lian T M, Zhong H S, et al.Journal of Wuhan University of Technology-Materials Science Edition, 2002, 17(4),69.
50 Liang J Z, Yang S S.Shanghai Plastics, 2010(1),1 (in Chinese).
梁基照, 杨铨铨.上海塑料, 2010(1),1.
51 Zhang X W, Huang R. Functional Materials, 1994(6),492 (in Chinese).
张雄伟, 黄锐.功能材料, 1994(6),492.
52 Yang S S, Liang J Z.Shanghai Plastics, 2009(4), 4(in Chinese).
杨铨铨, 梁基照.上海塑料, 2009(4), 4.
53 Van Beek L K H, Van Pul B I C F.Rubber Chemistry and Technology, 1963, 36(3),740.
54 Zhu C C, Guan H, Luo Y. Journal of Yunnan University(Natural Sciences Edition), 1992(S1),166(in Chinese).
朱长纯, 关辉, 罗援.云南大学学报:自然科学版, 1992(S1),166.
55 Huang Q A, Xiang T.Electronic devices, 1994(3), 20 (in Chinese).
黄庆安, 向涛.电子器件, 1994(3), 20.
56 Liu S Y, Huang Y M.Journal of Mechanical Engineering, 2011, 47(17),141 (in Chinese).
刘蜀阳, 黄玉美.机械工程学报, 2011, 47(17),141.
57 Hu H, Zhao L, Liu J, et al.Polymer, 2012, 53(15),3378.
58 Natarajan T S, Eshwaran S B, St Ckelhuber K W, et al.ACS Applied Materials & Interfaces, 2017, 9(5),4860.
59 Wang L, Ma F, Shi Q, et al.Sensors & Actuators A Physical, 2011, 165(2),207.
60 Luheng W, Tianhuai D, Peng W.Sensors and Actuators A: Physical, 2007, 135(2),587.
61 Knite M, Teteris V, Kiploka A, et al.Sensors and Actuators A (Physical), 2004, 110(1-3),142.
62 Job A E, Oliveira F A, Alves N, et al.Synthetic Metals, 2003, 135,99.
63 Wang L H, Ding T H, Peng W.Carbon, 2009, 47(14),3151.
64 Novák I, Krupa I, Janigová I. Carbon, 2005, 43(4),841.
65 Devaraj H, Yellapantula K, Stratta M, et al. Sensors and Actuators A: Physical, 2019, 285, 645.
66 Gao Y, Fang X, Tan J, et al.Nanotechnology, 2018,29(23), 235501/1.
67 Li Q, Li J, Tran D, et al. Journal of Materials Chemistry C: Materials for Optical and Electronic Devices, 2017, 5(42), 11092.
68 Nela L, Tang J, Cao Q, et al.Nano Letters, 2018,18(3), 2054.
69 Saetia K, Schnorr J M, Mannarino M M , et al.Advanced Functional Materials, 2014, 24(4), 492..
70 Zhang M, Wang C, Wang Q, et al.ACS Applied Materials & Interfaces, 2016, 8(32), 20894.
71 Park J J, Hyun W J, Mun S C, et al.ACS Applied Materials & Interfaces, 2015, 7(11),6317.
72 Hua Z, Gong T X, Wen H, et al.Electronic Components and Materials, 2018,37(9),27.
73 Ma Z L, Wei A J, Ma J Z, et al. Nanoscale, 2018, 10(15), 7116.
74 Ren J S, Wang C X, Zhang X, et al. Carbon, 2017, 111,622.
75 QinY Y, Peng Q Y, Ding Y J, et al. ACS Nano, 2015, 9(9), 8933.
76 Di W H, Zhang G, Zhao Z D, et al.Polymer International, 2004, 53(4),449.
77 Duan Q Y, Wang J P, Ren Q B, et al. Journal of Applied Polymer Science, 2018, 135(35), n/a.
78 Kim S W, Kwon S N, Na S I.Composites Part B: Engineering, 2019, 167,573.
79 Zhang S J, Zhang H L, Yao G, et al. Journal of Alloys and Compounds, 2015, 652,48.
80 Tee C K, Wang C, Allen R, et al.Nature Nanotechnology, 2012, 7(12),825.
81 Amjadi M, Pichitpajongkit A, Lee S, et al.ACS Nano, 2014, 8(5),5154.
82 Gong S, Daniel T H L, Su B, et al. Advanced Electronic Materials, 2015, 1(4),1400063/1.
83 Li M F, Li H Y, Zhong W, et al.ACS Applied Materials & Interfaces, 2014, 6(2),1313.
84 Fan X, Wang N, Yan F, et al.Advanced Materials Technologies, 2018, 3(6),1800030.
85 Liu K N, Zhou Z Q, Yan X W, et al. Polymers (Basel), 2019, 11(7), 11.
86 Yan S C, Saleem M F, Ma H R, et al. ChemistrySelect, 2019. 4(14), 4407.
87 Tang L, Liu Z, Wujcik E K.ACS Applied Materials & Interfaces, 2019, 11(22),20453.
88 Liu S Y, Lian L, Pan J, et al.IEEE Transactions on Electron Devices, 2018, 65(5),1939.
89 Huang Y, Gao L, Zhao Y, et al.Journal of Applied Polymer Science, 2017, 134(39),45340.
90 Zhao Y N, Huang Y, Hu W, et al. Smart Materials and Structures, 2019. 28(3), 035004.
91 Asada T, Wang J J. Rubber Translations, 1985(3),39 (in Chinese).
浅田泰司, 王金鉴.橡胶译丛, 1985(3),39.
92 Chen B, Gu Z T.High Power Laser and Particle Beams, 2015, 27(8),27089003 (in Chinese).
陈薄, 古忠涛.强激光与粒子束, 2015, 27(8),27089003.
93 Jing X, Zhao W, Lan L.Journal of Materials Science Letters, 2000, 19(5),377.
94 Cochrane, Cédric, Lewandowski M, et al. Sensors, 2010, 10(9),8291.
95 Li Y, Wang S F, Zhang Y,et al. China Plastic, 2004(10),63 (in Chinese).
李莹, 王仕峰, 张勇,等.中国塑料, 2004(10),63.
96 Yazdani H, Hatami K, Khosravi E, et al.Carbon, 2014, 79,393.
97 Bai J B, Allaoui A.Composites Part A:Applied Science and Manufactu-ring, 2003, 34(8),689.
98 Zheng Y, Li Y, Dai K, et al.Composites Part A: Applied Science and Manufacturing, 2017,101,41.
99 Liu H, Li Q, Zhang S, et al. Journal of Materials Chemistry C, 2018, 6(45),12121.
100 Geim A K.Science, 2009, 324(5934),1530.
101 Jeong Y R, Park H, Jin S W, et al. Advanced Functional Materials, 2015, 25(27),4228.
102 Jiao Y, Young C, Yang S, et al.IEEE Sensors Journal, 2016, 16(22), 7870.
103 Stankovich S, Dikin D A, Dommett G H B, et al.Nature, 2006, 442(7100),282.
104 Dhand V, Rhee K Y, Ju Kim H, et al.Journal of Nanomaterials, 2013, 2013,1.
105 Zhang S J, Zhang H L, Yao G, et al. Journal of Alloys and Compounds, 2015, 652,48.
106 Gong S, Zhao Y, Yap L W, et al.Advanced Electronic Materials, 2016, 2(7), n/a.
107 Ying H, Chao H, Jian L, et al.Sensor Review, 2019, 39(2), 233.
108 Xu C, Hu S, Zhang R, et al.Polymer Bulletin, DOI: 10.1007/s00289-019-02705-2.
109 Huang Y, Wang W, Sun Z, et al.Journal of Materials Research, 2015, 30(12),1869.
110 Kim J H, Kim Y J, Baek W K, et al.Proceedings of SPIE-The International Society for Optical Engineering, 2010, 7646,76460N.
111 Liu P, Pan W D, Liu Y, et al. Composites Science and Technology, 2018, 159, 42.
112 Huang Y, Zhao Y, Wang Y, et al.Smart Materials and Structures, 2018, 27(3),035013.
113 Boland C S, Khan U, Backes C, et al. ACS Nano, 2014, 8(9),8819.
114 Zheng Y, Li Y, Dai K, et al.Composites Science and Technology, 2018, 156, 276.
115 Ali M M, Maddipatla D, Narakathu B B, et al.Sensors and Actuators A Physical, 2018, 274, 109.
116 Chen S, Wei Y, Wei S, et al.ACS Applied Materials & Interfaces, 2016,8(38), 25563.
117 Dong D D, Ma J Z, Ma Z L, et al. Composites Part A: Applied Science and Manufacturing, 2019,123, 222. |
|
|
|
渝公网安备50019002502923号 © Editorial Office of Materials Reports.
2020, Vol. 34 
