金属/陶瓷润湿性的实验表征和理论预测研究进展

doi:10.11896/cldb.18120005

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Abstract  Wettability of metal/ceramic systems is of crucial significance in many fields including metal-ceramic jointing, purification of molten metal, infiltration-based preparation and liquid-phase preparation of composite materials. The wetting of liquid metal on ceramic surface, according to its process, is a complicated physical and chemical phenomenon involving substrate dissolution, interface adsorption and interaction. Experimental characterization and theoretical estimation of wettability of metal/ceramic systems has always been a research hotspot in materials science.
    At present, the characterization methods for wettability of metal/ceramic are almost all based on measuring contact angle (calculated via the classical equation given by Thomas Young). The contact angle is highly susceptible to circumstance factors, so the relationship between contact angle and wettability has inevitable deviation in practical estimation. Moreover, few methods are adaptable for the systems of high-melting-point alloys and ceramics. Therefore, in addition to improve and optimize measurement of contact angle, considerable attempts have also been made to study wettability via theoretical calculation. However, yet no theoretical prediction can be applied to all metal/ceramic systems till now, due to controversial understanding upon wetting mechanism and insufficient research.
    Recent experimental research of metal/ceramic wettability is mainly focused onimproved sessile drop method, dispensed drop method, capillary rising method and induction melting method. Among them, the improved sessile drop method, compared to the traditional sessile drop method, can eliminate the impact of oxide film on the melt surface. Induction melting method can realize the melting of high-melting-point alloys (e.g. Ti alloy), so it has a unique superiority (as the rest of the methods mentioned above are adaptable to systems comprised of low-melting-point alloys, e.g. Al alloys or Mg alloys, and ceramics). In terms of theoretical estimation, besides the surface tension model which directly based on Young's equation, some researchers incorporate Young-Dupré equation to reveal the inherent law of reaction interface wettability from the perspectives of thermodynamics and atomic bond. This provides an alternative idea for theoretical studies though the final results are less-than-ideal. In addition, a new criterion for qualitatively analysing wettability has been proposed by researchers as well, in which wetting is regarded as a reaction phenome-non, and the change of Gibbs free energy of interface reaction and the energy change of surface phase in wetting process are taken into account. Moreover, with respect to wetting spreading dynamics, aside from directly calculating contact angle using metal nucleation theory, there have also been developed some theoretical models that deserve attention, such as hydrodynamic model, molecular dynamics model, reaction control model and diffusion control model, and can be adopted to study wetting rate.
    This reviewprovides a comprehensive description of the recent research progress, both experimental and theoretical, upon the wettability of metal/ceramic, with mechanism of wetting process, measurement of contact angle and models for estimating wettability as the major sections.

Key words： wettability metal/ceramic interface contact angle theoretical model capillary rising method induction melting method surface tension model wetting spreading kinetics

Published: 12 September 2019

CLC number:

TG148

Fund:This work was financially supported by the National Key Research and Development Plan(2017YFB0703101)

About author:: Wei Qu received her B.S. degree in Harbin Institute of Technology in 2016. She is currently pursuing her M.S. degree at State Key Laboratory of Metal Matrix Compo-sites, Shanghai Jiao Tong University under the supervision of Prof. Tongxiang Fan. Her research has focused on the wettability of metal/ceramic systems.
Tongxiang Fan received his joint Ph.D. degree from Shanghai Jiao Tong University and Osaka University. After one-year postdoctoral research at Japan Science and Technology Department, he is currently a full professor in Shanghai Jiao Tong University. He undertook funds including the National Science Fund for Distinguished Young Scholars, Program for New Century Excellent Talents in University, Fok Ying Tung Education Fund, Major Project on Basic Research of Shanghai, and Nano-research Program of Shanghai. He is appointed as director of CMRS, member of the committee of Material Science and Engineering in NFSOC, and reviewers of various domestic and foreign periodicals. His research interests are functional metal matrix composites and bio-inspired functional materials. In recent years, representative papers have been published as follows: Prog. Mater. Sci.、Adv. Mater.、Adv. Funct. Mater.、J. Mater. Chem.、Chem. Mater.、Acta Mater.、J. Am. Ceram. Soc.、J. Eur. Ceram. Soc.、Carbon、Micropor. Mesopor. Mat.、Nanotechnology、Scripta Mater.、J. Mater. Res.、Metall. Mater. Trans. A, et al.

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QU Wei,FAN Tongxiang. Advances in the Wettability Research of Metal/Ceramic Systems:Experimental Characterization and Theoretical Estimation[J]. Materials Reports, 2019, 33(21): 3606-3612.

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http://www.mater-rep.com/EN/10.11896/cldb.18120005 OR http://www.mater-rep.com/EN/Y2019/V33/I21/3606

1 Xiao X, Jin W, Cheng F, et al. Journal of Materials Science, 2011, 46(10), 3424.
2 Gatzen M, Radel T, Thomy C. Journal of Materials Processing Technology, 2016, 238, 352.
3 Bhat K N, Prabhu K N, Satyanarayan. Journal of Materials Science-Materials in Electronics, 2014, 25(2SI), 864.
4 Lu J, Mu Y, Luo X. Materials Science and Engineering B, 2012, 177(20), 1759.
5 Bao S, Syvertsen M, Kvithyld A, et al. Transactions of Nonferrous Metals Society of China, 2014, 24(12), 3922.
6 Li A B, Cui X P, Wang G S. Materials Letters, 2016, 185, 351.
7 El-Sabbagh A, Soliman M, Taha M. Journal of Materials Processing Technology, 2012, 212(2), 497.
8 Ploetz S, Nowak R, Lohmueller A, et al. Advanced Engineering Mate-rials, 2016, 18(11), 1884.
9 Wang X, Wang L, Luo L. Materials & Design, 2017, 121, 335.
10 Li W, Zong J, Huang R, et al. Materials & Design, 2016, 99, 225.
11 Wu D D, Wang H, Wei Y G, et al. Applied Mechanics and Materials, 2014, 536-537, 1477.
12 Laurent V, Chatain D, Eustathopoulos N. Materials Science and Enginee-ring A, 1991, 135(91), 84.
13 Chen J. Investigation on the wettability of metal and ceramic system. Ph.D. Thesis, Chongqing University, China, 1999 (in Chinese).
陈建. 金属/陶瓷润湿性研究. 博士学位论文, 重庆大学, 1999.
14 Espié L, Drevet B, Eustathopoulos N. Metallurgical and Materials Tran-sactions A, 1994, 25A, 599.
15 Naidich Y V, Zhuravlev V S. Refractories and Industrial Ceramics, 1974, 15(1), 55.
16 Lin Q, Cao R. Computational Materials Science, 2015, 99, 29.
17 Liu X Y. Research on the wettability and interfacial interaction between Ti-Al molten alloys and ceramics. Ph.D. Thesis, Chongqing University, China, 2016 (in Chinese).
刘许旸. Ti-Al系熔体与陶瓷的润湿性及界面相互作用的行为研究,博士学位论文, 重庆大学, 2016.
18 Passerone A, Muolo M L, Valenza F, et al. Acta Materialia, 2009, 57(2), 356.
19 Liu X, Lyu X, Dong H, et al. Metallurgical and Materials Transactions A-Physical Metallurgy and Materials Science, 2015, 46A(10), 4783.
20 Klinter A J, Mendoza-Suarez G, Drew R A L. Materials Science and Engineering A, 2008, 495(1-2), 147.
21 Nowak E, Combes G, Stitt E H, et al. Powder Technology, 2013, 233, 52.
22 Liu A H. The interfacial reaction law and micromechanism between tita-nium alloy metals and ceramic mould. Ph.D. Thesis, Harbin Institute of Technology, China, 2007 (in Chinese).
刘爱辉. 钛合金熔体与陶瓷铸型界面反应规律及微观机理研究. 博士学位论文, 哈尔滨工业大学, 2007.
23 Liu A H, Li B S. Materials Science Forum, 2016, 863, 3.
24 Lin Q L, Shen P, Qiu F. Scripta Materialia, 2009,60(11), 960.
25 Shen P, Fujii H, Nogi K. Journal of Materials Science, 2007, 42(10), 3564.
26 Shi L, Shen P, Zhang D, et al. Journal of Materials Science, 2012, 47(24), 8372.
27 Jin P, Sui R, Li F X. Acta Metallurgica Sinica, 2017(4), 479 (in Chinese).
靳鹏,隋然,李富祥.金属学报, 2017(4), 479.
28 Shen P, Wang Y, Ren L, et al. Applied Surface Science, 2015, 355, 930.
29 Nautiyal P, Gupta A, Seal S. Acta Materialia, 2017, 126, 124.
30 Wu M, Chang L L, Lu X, et al. Transactions of Materials and Heat Treatment, 2016, 37(7), 25 (in Chinese).
吴茂,常玲玲,路新,等. 材料热处理学报, 2016, 37(7), 25.
31 Wu M, Chang L, Zhang L, et al. Surface and Coatings Technology, 2016, 287, 145.
32 Fujii H, Nakae H, Okada K. Acta Metallurgica, 1993, 41(10), 1971.
33 Chiaramonte F P, Rosenthal B N. Journal of the American Ceramic Society, 1911, 74(3), 658.
34 Xue X M, Wang J T, Quan M X. Journal of Materials Science, 1991, 26(23), 6391.
35 Nicholas M G, Mortimer D A, Jones L M. Journal of Materials Science, 1990, 25(6), 2679.
36 Halverson D C. Journal of the American Ceramic Society, 1989, 72(5), 775.
37 Ding H D, Qian Y C, Fu S L. Journal of Academy of Armored Force Engineering, 2006, 20(2), 88 (in Chinese).
丁华东,钱耀川,傅苏黎.装甲兵工程学院学报, 2006, 20(2), 88.
38 Panasyuk A D, Oreshkin V D, Maslennikova V R. Power Metallurgy and Metal Ceramics,1979, 199, 487.
39 Naidich J V. Progress in Surface and Membrane Science,1981, 14, 353.
40 Contreras A, León C A, Drew R A L. Scripta Materialia, 2003, 48(12), 1625.
41 Frumin N, Frage N, Polak M, et al. Scripta Materialia, 1997, 37(8), 1263.
42 Samsonov G V, Panasyuk A D, Kozina G K. Power Metallurgy and Metal Ceramics,1968,7, 874.
43 Bao S, Tang K, Kvithyld A. Transactions of Nonferrous Metals Society of China, 2012, 22(8), 1930.
44 Han D S, Jones H, Atkinson H V. Journal of Materials Science, 1993, 28, 2654.
45 Koehler W. Aluminium, 1975, 51, 443.
46 Shimbo M, Naka M, Okamoto I. Journal of Materials Science Letters,1989, 8, 663.
47 Mills K C, Su Y C. International Materials Reviews, 2013, 51(6), 329.
48 Bao S, Tang K, Kvithyld A. Metallurgical and Materials Transactions B, 2011, 42(6), 1358.
49 Liu J. Study on the interface reaction and wettability of C_f/Al-Si compo-sites. Master's Thesis, Harbin Institute of Technology, China, 2014 (in China).
刘钧. C_f/Al-Si复合材料界面反应与润湿性研究. 硕士学位, 哈尔滨工业大学, 2014.
50 Zhu D Y, Jin Z H, Wang Y L. Journal of Xi'an Jiaotong University, 1997(10), 96 (in Chinese).
朱定一,金志浩,王永兰.西安交通大学学报, 1997(10), 96.
51 Chidambaram P R, Edwards G R, Olson D L. Metallurgical Transactions B, 1992, 23B, 215.
52 Jian Z Y, Yang G C, Zhou Y H. Acta Materiae Composite Sinica, 1996, 13(1), 46 (in Chinese).
坚增运,杨根仓,周尧和.复合材料学报, 1996, 13(1), 46.
53 Liu X B, Yang G C, Fan J F, et al. The Chinese Journal of Nonferrous Metals, 2003(2), 349 (in Chinese).
刘新宝,杨根仓,樊建锋,等. 中国有色金属学报. 2003(2), 349.