树枝状纤维形纳米球催化剂的研究进展

doi:10.11896/cldb.18100011

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Abstract  Dendritic fibrous silica-based nanospheres (denoted as KCC-1, similar to naming rule of MCM-41) have been regarded as another milestone in the history of mesoporous materials since MCM-41 and SBA-15. Compared with conventional mesoporous silica materials, KCC-1 with three-dimensional (3D) center-radial channels and hierarchical pores feature unique structural characteristics, including more open pore nanochannels, more highly accessible internal spaces, larger pore volumes, etc. Diverse guest species (such as noble metal nano-particles or functional biological macromolecules) could be easily transported through the radial porous architectures, achieving their efficient loading or reacting with the chemically active sites on these nanochannels as promising scaffolds/platforms to construct novel nanocatalysts. A majority of investigations have demonstrated that KCC-1 are ideal alternatives over traditional mesoporous MCM-41 or SBA-15, owing to their inherent structure superiorities.
    The successful creation of KCC-1 has aroused a wave of research upon dendritic fibrous nanospheres and the derivative catalysts. Researchers made fruitful attempts to develop dendritic fibrous nanospheres with other bulk elements, and obtained a series of analogues such as titania, silica-titania hybrid, carbon, carbon-nitrogen hybrid, silica-aluminum hybrid, silica-aluminum-copper hybrid, etc. nanospheres with dendritic fibrous structure. On the other hand, as the research further progressed, nanocatalysts with novel structures (e.g. core-shell, hollow, yolk-shell, etc.) on the basis of the original dendritic fibrous porous structure were also constructed and found to have excellent catalytic performances in specific catalyst-support systems.
    Starting with bulk elements which were utilized to construct dendritic fibrous nanospheres with 3D center-radial channels plus hierarchical pores, this article will review the worldwide recent research progress of this type of nanocatalysts, mainly classifying them, as well as summarizing individual structural characteristics, catalytic objects and performances. Last but not the least, research ideas and development trends will be analyzed and outlooked.

Key words： mesoporous material KCC-1 dendritic fibrous mesoporous nanospheres catalyst silica nanospheres titania nanospheres carbon nanospheres silica-alumina hybrid nanospheres core-shell structure hollow structure yolk-shell structure

Published: 12 September 2019

CLC number:	O611.4
	TB383

Fund:This work was financially supported by the National Natural Science Foundation of China (U1607105), the Science and Technology Projects in Qinghai Pro-vice (2018-GX-101, 2018-ZJ-722, 2019-HZ-808), Key Laboratory Project from Education Department of Shaanxi Provincial Government (16JS120); the Doctoral Research Program of Yan'an University (YDBK2017-39, YDBK2016-14), the Research Program of Yan'an University (YDQ2018-14), Shaanxi Province Training Program of Innovation and Entrepreneurship for Undergraduates (201820042), Innovation Project of Graduate Education from Yan'an University (YCX201822)

About author:: Yabin Wang received his Ph.D. degree in Chemical Engineering and Technology from Harbin Institute of Technology, in 2017. He is currently a teacher at Yan'an University. His research interests are fabrication and application of dendritic mesoporous nanoparticles, as well as synthesis and application of triazinedithiolsilane compounds.
Zhong Liu received his Ph. D. degree from Institute of Coal Chemistry, Chinese Academy of Sciences in 2012. He is an associate researcher at Qinghai Institute of Salt Lakes (CAS). His research mainly focuses on the preparation of functional materials which designed for separating useful ions from salt lakes.

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	WANG Yabin
	GUO Min
	SHI Shihui
	HU Keke
	ZHANG Yaoxia
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Cite this article:

WANG Yabin,GUO Min,SHI Shihui, et al. Research Progress of Dendritic Fibrous Nano-spheres Catalysts[J]. Materials Reports, 2019, 33(21): 3596-3605.

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http://www.mater-rep.com/EN/10.11896/cldb.18100011 OR http://www.mater-rep.com/EN/Y2019/V33/I21/3596

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