二氧化碳电化学还原技术研究进展

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Abstract Carbon dioxide is a major greenhouse gas which is released into the atmosphere along with the rapid consumption of coal, oil, natural gas and other traditional fossil fuels, causing global warming, environmental pollution and other problems. As an inexhaustible resource, carbon dio-xide could be turned into high value-added chemical products. Nowadays, thermochemical reduction, photochemical reduction, photoelectrocatalytic reduction and electrochemical reduction are widely used for the resource utilization of carbon dioxide. Among them, electrochemical reduction considered to be a green and promising CO₂ disposal method has attracted great attention because of its mild reaction conditions, using of clean energy, a high catalytic efficiency, capable of synthesizing variety of carbon-containing compounds, and able to regulate the target products by controlling the electrolytic conditions. However, high energy consumption, low product selectivity, low catalyst activity and the high price of catalyst limited its extensive application. This study first introduces the general principles of carbon dioxide electrochemical reduction. Next, the influe-nce factors of electrochemical reduction such as electrodes, electrolytes and catalysts has been discussed, and the latest progress relating to electrocatalytic catalysts has been reviewed also. Finally, the challenges and prospects for further development of carbon dioxide electrochemical have been presented.

Key words： carbon dioxide electrochemical reduction electrocatalyst reaction mechanism

Published: 05 July 2019

CLC number:

X511

About author:: Xin Qian received her B.S. degree in bioscience from Anhui Normal University in 2017. She is currently pursuing her M.S. degree at the Nano Science and Technology Institute, University of Science and Technology of China and Guangzhou Institute of Energy Conversion, CAS Key Laboratory of Renewable Energy, Chinese Academy of Sciences, under the supervision of Prof. Hao-ran Yuan, associate Prof. Lifang Deng and Kaiju Wei. Her research has focused on solid waste functionalization and carbon dioxide electrochemical reduction.Haoran Yuan received his B.E. degree in thermal engineering from Hefei University of Technology in 2003 and received his Ph.D. degree in engineering from the Guangzhou Institute of energy conversion, Chinese Academy of Sciences, in 2010. His research interests include high value clean utilization of combustible solid waste, low carbon emission utilization of organic waste and transformation of coal-fired boilers, etc.

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	QIAN Xin
	DENG Lifang
	WANG Lufeng
	SHAN Rui
	YUAN Haoran

Cite this article:

QIAN Xin,DENG Lifang,WANG Lufeng, et al. Recent Progress in the Electrochemical Reduction Technology of Carbon Dioxide[J]. Materials Reports, 2019, 33(z1): 102-107.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2019/V33/Iz1/102

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