纳米氧化钨的水热/溶剂热法制备及应用的综述

doi:10.11896/cldb.18060143

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Abstract As a kind of cheap transition metal oxide, tungsten oxide has good performance in photochromic, electrochromic, photocatalytic, and ultra-capacitor and is widely used in smart windows, catalysts, solar cells, and gas-sensitive sensing equipment, etc. Tungsten oxide with nano structure possesses many unique properties, such as the increased specific surface area, changed surface energy, and quantum limited-domain effects, which has made the fabrication of nano-tungsten oxide become a hot spot in recent years. There are many methods for preparing nano-tungsten oxide, including gas phase method, liquid phase method, solid phase method, etc. Hydrothermal/solvethermal method refers to a me-thod that crystal growth, synthesis, and sintering under the condition of high temperature and high pressure in a closed container by heating to produce a high-pressure environment. Compared with solid phase sintering, hydrothermal/solvethermal method makes the crystal less defects during the growth process for its lower synthetic temperature; compared with the atmospheric pressure heating method, hydrothermal/solvethermal method makes the crystal more crystallinity for its higher synthetic pressure, and furthermore, the method can induce the formation of new products since the properties of reactant may changed in a high-temperature and high-pressure environment. Moreover, the strong convection during hydrothermal/solvethermal can make the mass transfer more uniform and rapid, and the smaller temperature gradient can also make the crystal growth higher and more uniform.
Because of the advantages of environmental, low-cost, facile processes, and easy control of products, hydrothermal/solvethermal method are more and more popular and are becoming the main method for preparing tungsten oxide with different dimensions, morphologies and structures. In order to control the structure and morphology of oxide, people often choose different kinds of additives selectively; or change experimental conditions, parameters; even through various doping. The diversification of preparation led to the diversity of the growth mechanism, such as isotro-pic growth, preferentially grow caused by capping agent, driving force of supersaturation, self-assembling (Ostwald ripening, Gibbs-Tomso law, decreasing surface area). In addition to the traditional applications, it is also reported that tungsten oxide can be used in fluorescence sensor, bio-imaging, photochromic inks, and nuclear fuel cycle after the improvement of their structure and morphology recently. Above all, there are obviously advantages of preparation tungsten oxide by hydrothermal/solvethermal method. Thus, it is necessary to make a systematic summary of this field.
In the paper, the formation mechanism and application properties of tungsten oxide, which synthesized by hydrothermal/solvothermal method are presented and summarized based on their different structures, and also the research and develop trend are prospected.

Key words： nanometer tungsten oxide hydrothermal solvothermal

Published: 15 August 2019

CLC number:

TQ174

About author:: Linyan Zhao received her B.E. degree in material science and engineering from Beijing University of Technology in 2016. She is currently pursuing her Master degree at the Department of Material Science and Engineering, Beijing University of Technology under the supervision of Prof. Xiaoli Xi. Her research has focused on the fabrication and application of tungsten oxide.Xiaoli Xi received her B.E. and M.E. degree in nonferrous metallurgy engineering from Central South University in 1996 and 1999, respectively, and received her Ph.D. degree in material science and engineering from Beijing University of Technology in 2005. Liwen Ma received her B.E. degree in metallurgical engineering from Central South University in 2006 and received her Ph.D. degree in metallurgical physical chemistry from Central South University in 2011.

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Cite this article:

ZHAO Linyan,XI Xiaoli,FAN Youshu, et al. Review of Recent Progress in the Synthesis of Nano-tungsten Oxide via Hydrothermal/Solvothermal Method and the Application[J]. Materials Reports, 2019, 33(19): 3203-3209.

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http://www.mater-rep.com/EN/10.11896/cldb.18060143 OR http://www.mater-rep.com/EN/Y2019/V33/I19/3203

Solonin Y M, Khyzhun O Y, Graivoronskaya E A. Crystal Growth & Design,2001,1(6),473.2 Huang K, Pan Q, Yang F, et al. Journal of Physics D-Applied Physics,2008,41,155417.3 Kondalkar V V, Mali S S, Kharade R R, et al. Dalton Transactions,2015,44(6),2788.4 Rout C S, Hegde M, Rao C N R. Sensors and Actuators B-Chemical,2008,128(2),488.5 Li Q, Wang L, Chu D, et al. Ceramics International,2014,40(3), 4969.6 Cao S, Chen H. Journal of Alloys and Compounds,2017,702,644.7 Li J, Liu X, Cui J, et al. ACS Applied Materials & Interfaces,2015,7(19),10108.8 Yin C, Zhu S, Yao F, et al. Journal of Nanoparticle Research,2013,15,18128.9 Epifani M, Comini E, Diaz R, et al. ACS Applied Materials & Interfaces,2014,6(19),16808.10 Zhan Y, Liu Y, Liu Q, et al. Sensors and Actuators B-Chemical,2018,255(1),290.11 Le Houx N, Pourroy G, Camerel F, et al. The Journal of Physical Che-mistry C,2009,114(1),155.12 Wang H, Ding R, Wang C, et al. CrystEngComm,2017,19(28),3979.13 Wang Y, Wang X, Xu Y, et al. Small, DOI.org/10.1002/smll.201700623.14 Zhou Y, Huang A, Ji S, et al. Chemistry-An Asian Journal,2018,13(4),457.15 Kong Y, Sun H, Zhao X, et al. Applied Catalysis A-General,2015,505,44716 Cong S, Geng F, Zhao Z. Advanced Materials,2016,28(47),10518.17 Wang J, Khoo E, Lee P S, et al. Journal of Physical Chemistry C,2008,112(37),14306.18 Phuruangrat A, Ham D J, Hong S J, et al. Journal of Materials Chemistry,2010,20(9),1683.19 Li J, Zhu J, Liu X. New Journal of Chemistry,2013,37(12),4241.20 Chen Z, Wang Q, Wang H, et al. Advanced Materials,2013,25(14),2095.21 Wang J, Khoo E, Lee P S, et al. Journal of Physical Chemistry C,2009,113(22),9655.22 He J, Liu H, Xu B, et al. Small,2015,11(9-10SI),1144.23 Guo C, Yin S, Yan M, et al. Inorganic Chemistry,2012,51(8),4763.24 Xi G, Ouyang S, Li P, et al. Angewandte Chemie-International Edition,2012,51(10),2395.25 Zhou H, Shi Y, Dong Q, et al. Journal of Physical Chemistry C,2014,118(35),20100.26 Sun Y, Wang W, Qin J, et al. Electrochimica Acta,2016,187,329.27 Zheng J Y, Song G, Kim C W, et al. Nanoscale,2013,5(12),5279.28 Ng C Y, Razak K A, Lockman Z. Journal of Alloys and Compounds,2014,588,585.29 Gu Z, Li H, Zhai T, et al. Journal of Solid State Chemistry,2007,180(1),98.30 Li X, Zhang G, Cheng F, et al. Journal of the Electrochemical Society,2006,153(7),H133.31 Guo C, Yin S, Huang Y, et al. Langmuir,2011,27(19),12172.32 Pokhrel S, Simion C E, Teodorescu V S, et al. Advanced Functional Materials,2009,19(11),1767.33 Zhou H, Shi Y, Dong Q, et al. Journal of Materials Chemistry A,2014,2(12),4347.34 Liu J, Margeat O, Dachraoui W, et al. Advanced Functional Materials,2014,24(38),6029.35 Li G, Zhang S, Guo C, et al. Nanoscale,2016,8(18),9861.36 Lian C, Xiao X, Chen Z, et al. Nano Research,2016,9(2),435.37 Zhang J, Tu J, Xia X, et al. Journal of Materials Chemistry,2011,21(14),5492.38 Zhou H, Shi Y, Wang L, et al. Chemical Communications,2013,49(69),7626.39 Late D J, Kashid R V, Rout C S, et al. Applied Physics A-Materials Science & Processing,2010,98(4),751.40 Zhu M, Meng W, Huang Y, et al. ACS Applied Materials & Interfaces,2014,6(21),18901.41 Tian Y, Cong S, Su W, et al. Nano Letters,2014,14(4),2150.42 Sun K, Peng H, Mu J, et al. Ionics,2015,21(8),2309.43 Su J, Feng X, Sloppy J D, et al. Nano Letters,2011,11(1),203.44 Wei J, Jiao X, Wang T, et al. Journal of Materials Chemistry C,2015,3(29),7597.45 Zeng W, Li Y, Miao B, et al. Physica E: Low-Dimensional Systems and Nanostructures,2014,56,183.46 Zheng J Y, Song G, Hong J, et al. Crystal Growth & Design,2014,14(11),6057.47 Huang J, Xiao L, Yang X. Materials Research Bulletin,2013,48(8),2782.48 Kondalkar V V, Kharade R R, Mali S S, et al. Superlattices and Microstructures,2014,73,290.49 Li Y, Tang Z, Zhang J, et al. Applied Catalysis B-Environmental,2017,207,207.50 Liu Y, Li Q, Gao S, et al. CrystEngComm,2014,16(32),7493.51 Hai G, Huang J, Cao L, et al. Journal of Alloys and Compounds,2017,690,239.52 Cai G F, Tu J P, Zhou D, et al. Solar Energy Materials and Solar Cells,2014,124,103.53 Huang J, Xu X, Gu C, et al. Materials Research Bulletin,2012,47(11),3224.54 Park S, Shim H, Lee C W, et al. Nano Research,2016,9(3),633.55 Li H, Bian Z, Zhu J, et al. Journal of the American Chemical Society,2007,129(27),8406.56 Bai H, Su N, Li W, et al. Journal of Materials Chemistry A,2013,1(20),6125.57 Seifollahi B M, Hojamberdiev M, Morita K, et al. Journal of the American Chemical Society,2013,135(11),4467.58 Nozik A J. Annual Review of Physical Chemistry,1978,29(1),189.59 Wang F, Di Valentin C, Pacchioni G. Journal of Physical Chemistry C,2012,116(16),8901.60 Reis K P, Ramanan A, Whittingham M S. Chemistry of Materials,1990,2(3),219.61 Griffith C S, Luca V. Chemistry of Materials,2004,16(24),4992.62 Supothina S, Rattanakam R, Suwan M. Microelectronic Engineering,2013,108,182.63 Hu W, Zhao Y, Liu Z, et al. Chemistry of Materials,2008,20(17),5657.64 Cui Z, Zeng D, Tang T, et al. Journal of Hazardous Materials,2010,183(1-3),211.65 Gui M, Zhang W, Chang Y, et al. Chemical Engineering Journal,2012,197,283.66 Guo C, Yin S, Dong Q, et al. Nanoscale,2012,4(11),3394.67 Suwan M, Supothina S. Micro & Nano Letters,2014,9(12),877.68 Supothina S, Suwan M, Wisitsoraat A. Microelectronic Engineering,2014,126,88.69 Liu G, Zhao Y, Sun C, et al. Angewandte Chemie-International Edition,2008,47(29),5277.70 Khan R, Kim T. Journal of Hazardous Materials,2009,163(2-3),1179.71 Xi G, Yue B, Cao J, et al. Chemistry-A European Journal,2011,17(18),5145.72 Mu W, Yu Q, Li X, et al. Chemical Engineering Journal,2017,319,170.73 Gao L, Qu F, Wu X. Journal of Materials Chemistry A,2014,2(20),7367.74 Gong H, Zheng F, Xu J, et al. Electrochimica Acta,2018,263,409.75 Puddu V, Mokaya R, Puma G L. Chemical Communications,2007(45),4749.76 Miyauchi M, Nukui Y, Atarashi D, et al. ACS Applied Materials & Interfaces,2013,5(19),9770.77 Li H, Tu W, Zhou Y, et al. Advanced Science, DOI: 10.1002/advs.201500389.78 Umena Y, Kawakami K, Shen J, et al. Nature,2011,473(7345),55.79 Yu J, Wanga S, Lowa J, et al. Physical Chemistry Chemical Physics,2013,15(39),16883.80 He Y, Zhang L, Wang X, et al. RSC Advances,2014,4(26),13610.81 Katsumata H, Tachi Y, Suzuki T, et al. RSC Advances,2014,4(41),21405.82 Zhao Z, Miyauchi M. Angewandte Chemie-International Edition,2008,47(37),7051.83 Zhao Z, Miyauchi M. Journal of Physical Chemistry C,2009,113(16),6539.84 Fu L, Cai W, Wang A, et al. Materials Letters,2015,142,201.85 Li F, Qin Q, Zhang N, et al. Sensors and Actuators B-Chemical,2017,244,837.86 Shen X, Wang G, Wexler D. Sensors and Actuators B: Chemical,2009,143(1),325.87 Li X, Mu W, Xie X, et al. Journal of Hazardous Materials,2014,264,386.88 Liu B, Mu W, Xie X, et al. RSC Advances,2015,5(20),15603.89 Wang Y, Thuiyan H, Duan S, et al. ACS Sustainable Chemistry & Engineering,2018,6(2),2462.90 Zhang W, Yue L, Zhang F, et al. Journal of Materials Chemistry A,2015,3(11),6102.91 Yoon S, Woo S, Jung K, et al. Journal of Alloys and Compounds,2014,613,187.92 Yu M, Sun H, Sun X, et al. Materials Letters,2013,108,29.