Ti<sub>4</sub>O<sub>7</sub>功能陶瓷材料研究与应用现状

doi:10.11896/cldb.201901016

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Abstract Ti_nO_2n-1 are considered to be a kind of high-performance conductive ceramic material, which have broad application prospect and crucial research value due to its unique physical, chemical and electrochemical properties. In addition to its own ceramic characteristics, the oxygen defects in the crystal structure endow it with the metal-like conductive properties, which break up the limitation on further application of ceramic materials because of its poor conductivity. Ti₄O₇ exhibits the best conductivity among Ti_nO_2n-1 materials, what’s more, it also have many other remarkable properties such as outstanding photoresponse, strong acid and alkali corrosion resistance and better electrochemical stability, which has aroused great concern of material researchers and has been widely used in the field of electrochemistry, thermoelectric materials, energy storage material, photocatalytic degradation and so on. Currently, by virtue of its distinguished electron conductivity and chemical stability, Ti₄O₇ was mainly used as battery electrodes and electrocatalytic support materials. The production process has been mature and commercialized.
The preparationprocess of Ti₄O₇ still have many defects. Particle size, porosity, crystallinity and other factors all exert a great influence on the performance of Ti₄O₇. The method of revivifying titanium precursor at high temperature has been commonly applied to industry. However, the Ti₄O₇ which was treated at high temperature would come out a series problems such as particle agglomeration, serious sintering and high specific surface area, resulting in the poor performance of Ti₄O₇. Therefore, researchers are trying to optimize the preparation process, and explore other synthetic methods at low temperature, but there are still some unsolved problems such as low product purity and high energy consumption. The details of the process need to be further studied. At present, three main issues consititute the majority of the research upon: Ⅰ. improving the purity of the product; Ⅱ. refining grain size and controlling particle size, Ⅲ. preparation of powder with controlled morphology.Researchers constantly introduce new technologies into the preparationprocess of Ti₄O₇. On the basis of the sol-gel method, the core-shell hollow pipe material with high specific surface area was successfully prepared via electrospining technology, while the sintering temperature was reduced by nearly 20%. The microwave heating method was firstly adopted to obtained Ti₄O₇ with controlled structures by radiating only 30 minutes under microwave. In recent two years, with the deepening of research, various excellent properties of Ti₄O₇ have been further developed and utilized. Ti₄O₇ shows superior rapid charge and discharge properties and cycle stability in lithium-ion batteries, lithium-sulfur batteries, metal-air batteries, fuel cells. What’s more, it has been applied in energy storage materials, thermoelectricity materials, photoelectricity materials and many other new energy fields.
This paper introduces the composition, structure and physicochemical properties of Ti₄O₇, summarizes the main preparation methods and typical applications of Ti₄O₇ ceramic, analyzes the advantages and disadvantages of various preparation methods and application requirements. And outlooks the future research directions and development trends in the field, which provide some references for the popularization and application of Ti₄O₇ functional ceramic material.

Key words： Ti₄O₇ functional material conductive ceramics microstructure electrode electrocatalyst support thermoelectric material lithium-sulfur battery fuel cell

Published: 24 January 2019

CLC number:

TB321

Fund:This work was financially supported by the National Natural Science Foundation of China (51535011,51675531) and Beijing Municipal Natural Science Foundation (3172038).

About author:: Yiwen Wang received his B.E. Degree in Academy of Armored Forces Engineering in 2016. He is currently pursuing his Master Degree at the National Key Lab for Remanufacturing, Army Academy of Armored Forces under the supervision of researcher Haidou Wang and research assistant Guozheng Ma. His research has focused on remanufacturing and tribology.Haidou Wang received his Ph.D. degree in Department of Mechanical Engineering from Tsinghua University in 2003. He joined the National Key Laboratory for Remanufacturing at Academy of Armored Forces from then on. He is a professor, Ph.D. supervisor and the deputy director of the laboratory. He is the National Outstan-ding Youth Science Fund Winner and Chief Scientist of National Defense 973 Program. In recent years, he has
won 12 national and provincial science and technology awards, selected as National Ten-thousand Talents Program Leaders,National Youth Science and Technology Leaders, Military Science and Technology Leaders and Beijing Science and Technology Leaders. He also has won the awards, including the National Outstanding Youth Award and National Outstanding Contributions Young and Middle-aged Experts. His current research areas cover the surface engineering, remanufacturing and tribology, especially in service life evaluation of surface coatings and solid film lubrication.

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Cite this article:

WANG Yiwen,WANG Haidou,MA Guozheng, et al. Research Progress and Application Status of Ti₄O₇, the Functional Ceramic Material[J]. Materials Reports, 2019, 33(1): 143-151.

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http://www.mater-rep.com/EN/10.11896/cldb.201901016 OR http://www.mater-rep.com/EN/Y2019/V33/I1/143

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