地聚合物固化/稳定有毒重金属及作用机理研究进展

doi:10.11896/j.issn.1005-023X.2018.11.010

Abstract
Figure/Table
References
Related Citation (11)

Download:

Full Text ( PDF ) (2307KB)
Export: BibTeX | EndNote (RIS)

Abstract As a new aluminosilicate inorganic geopolymer cementitious material, the special hydration reaction mechanism and hydration products have made more research and application in the field of immobilized/stabilized toxic heavy metal ions. In this paper, the mechanism, products, structure and properties of geopolymer reaction, the mechanism of immobilization/stabilization of toxic heavy metal ions, and the factors that affect the effect of geopolymer immobilization/stabilization of toxic heavy metal ions were reviewed.We also provided the theoretical basis and ideas for the research on making use of the low utilization efficiency industrial waste (Bayer process red mud) to synthesize geopolymer and its properties of immobilizing/stabilizing toxic heavy metal ions. Finally, the shortcomings and the future prospects of the research on utilizing geopolymer to immobilize/stabilize the toxic heavy metal ions are pointed out.

Key words： geopolymer immobilization/stabilization toxic heavy metal ions

Published: 20 July 2018

CLC number:

TU528

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	LUO Zhongtao
	LIU Lei
	KANG Shaojie
	WANG Yazhou
	YANG Jiujun

Cite this article:

LUO Zhongtao,LIU Lei,KANG Shaojie, et al. Research Progress on Immobilization/Stabilization of Toxic Heavy Metals by Geopolymers[J]. Materials Reports, 2018, 32(11): 1834-1841.

URL:

http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2018.11.010 OR http://www.mater-rep.com/EN/Y2018/V32/I11/1834

1 Jin M T, Lou M X, Zhang Q, et al. Study on the effect of geopolymers on the immobilization of heavy metals[J].Acta Mineralogica Sinica,2008,28(1):66.
2 Jiang J G, Xu X, Zhang Y. Investigation of leaching characteris-tics of heavy metals during cement stabilization of fly ash from municipal solid waste incinerator[J].Environment Science,2006,27(12):2564(in Chinese).
蒋建国,许鑫,张妍.城市垃圾焚烧飞灰的硅酸盐水泥稳定化效果研究[J].环境科学,2006,27(12):2564.
3 Bortnovsky O, Dědeek J, Tvarková Z, et al. Metal ions as probes for characterization of geopolymer materials[J].Journal of the Ame-rican Ceramic Society,2008,91(9):3052.
4 Davidovits J. Solidphase synthesis of a mineral blockpolymer by low temperature polycondensation of aluminosilicate polymers: Na-poly(sialate) or Na-PS and characteristics[R].Paris:Proceedings of IUPAC International Symposium on Macromolecules Stockholm,1976.
5 Dan S P, Cashion J D, Blackford M G, et al. Fe speciation in geopolymers with Si/Al molar ratio of 1~2[J].Journal of the European Ceramic Society,2007,27(7):2697.
6 Davidovits J. Geopolymer chemistry and applications[M].France:Geopolymer Institute,2008.
7 Yang L R, Wang C M, Feng X X, et al. Preparation and consolida-tion mechanism of fly ash based geopolymer incorporating slag[J].Journal of Wuhan University of Technology,2009(7):115(in Chinese).
杨立荣,王春梅,封孝信,等.粉煤灰/矿渣基地聚合物的制备及固化机理研究[J].武汉理工大学学报,2009(7):115.
8 Pan X, Yu H, Tu G. Reduction of alkalinity in bauxite residue du-ring bayer digestion in hight-ferrite diasporic bauxite[J].Hydrome-tallurgy,2015,151(1):98.
9 Deng H M, Zeng W M, Chen N Y, et al. Composition and crystal structure of Na-Al silicate slime in alumina production[J].Acta Me-tallurgica Sinica,1996,32(12):1248(in Chinese).
邓红梅,曾文明,陈念贻.氧化铝生产中“硅渣”的组成和结构研究[J].金属学报,1996,32(12):1248.
10 He J, Zhang J, Yu Y, et al. The strength and microstructure of two geopolymers derived from metakaolin and red mud-fly ash admixture: A comparative study[J].Construction and Building Materials,2012,30:80.
11 Li C, Sun H, Li L. A review: The comparison between alkali-activated slag and metakaolin cements[J].Cement and Concrete Research,2010,40(9):1341.
12 Zhang Y S, Sun W, Zheng K R, et al. In situ quantitatively tracking the hydration process of K-PSDS geopolymer with ESEM[J].Journal of Building Materials,2004,7(1):8(in Chinese).
张云升,孙伟,郑克仁,等.ESEM追踪K-PSDS型地聚合物水泥的水化[J].建筑材料学报,2004,7(1):8.
13 Criado M, Palomo A. Alkali activation of fly ash. Part Ⅲ: Effect of curing conditions on reaction and its graphical description[J].Fuel,2010,89(11):3185.
14 De V P, Midden C, Bouwhuis D. Alkali activation of fly ashes. Part 1: Effect of curing conditions on the carbonation of the reaction products[J].Fuel,2005,84(16):2048.
15 Shen J L, Ji Y S, Wang M, et al. Experimental study of material of red mud base activated by alkali[J].Journal of Binzhou University,2012,28(3):72(in Chinese).
申建立,姬永生,王猛,等.碱激发赤泥基胶凝材料的实验研究[J].滨州学院学报,2012,28(3):72.
16 Izquierdo M, Querol X, Davidovits J, et al. Coal fly ash-slag-based geopolymers: Microstructure and metal leaching[J].Journal of Ha-zardous Materials,2009,166(1):561.
17 Xu J Z, Zhou Y L, Tang R X. Study on the solidification of heavy metals by fly ash based geopolymers[J].Journal of Building Mate-rials,2006,9(3):341.
18 Zhang J, Provis J L, Feng D, et al. Geopolymers for immobilization of Cr⁶⁺, Cd²⁺, and Pb²⁺[J].Journal of Hazardous Materials,2008,157(2-3):587.
19 Chen J, Wang Y, Zhou S, et al. Reduction/immobilization processes of hexavalent chromium using metakaolin based geo-polymer[J].Journal of Environmental Chemical Engineering,2016,5(1):373.
20 Cheng T W, Lee M L, Ko M S, et al. The heavy metal adsorption characteristics on metakaolin based geopolymer[J].Applied Clay Science,2012,56(1):90.
21 Guo X, Zhang L, Huang J, et al. Detoxification and solidification of heavy metal of chromium using fly ash based geopolymer with che-mical agents[J].Construction and Building Materials,2017,151:394.
22 Jaarsveld J G S V, Deventer J S J V, Lorenzen L. Factors affecting the immobilization of metals in geopolymerized fly ash[J].Metallurgical and Materials Transactions B,1998,29(1):283.
23 Liu S F, Wang P M, Li Z J, et al. An FTIR and XPS study of immobilization of chromium with fly ash based geopolymers[J].Spectroscopy and Spectral Analysis,2008,28(1):67(in Chinese).
刘斯凤,王培铭,李宗津,等.粉煤灰地聚合物固封Cr³⁺的FTIR和XPS研究[J].光谱学与光谱分析,2008,28(1):67.
24 El-Eswed B I, Yousef R I, Alshaaer M, et al. Stabilization/solidification of heavy metals in kaolin/zeolite based geopolymers[J].International Journal of Mineral Processing,2015,137(34):34.
25 Jin M T, Jin Z F, Huang C J. Immobilization of heavy metal Pb²⁺ with geopolymer[J].Journal of Environmental Science,2011,32(5):1447(in Chinese).
金漫彤,金赞芳,黄彩菊.地聚合物固化重金属Pb²⁺的研究[J].环境科学,2011,32(5):1447.
26 Guo X L, Wu L, Shi H S. Effects of different heavy metals on fly ash based geopolymer[J].Journal of Material Research,2017,31(6):437(in Chinese).
郭晓潞,伍亮,施惠生.不同重金属对粉煤灰基地聚合物的影响作用[J].材料研究学报,2017,31(6):437.
27 Zhang M, Yang C, Zhao M, et al. Immobilization potential of Cr(Ⅵ) in sodium hydroxide activated slag pastes[J].Journal of Ha-zardous Materials,2016,321:281.
28 Zhang M, Zhao M, Zhang G, et al. Durability of red mud-fly ash based geopolymer and leaching behavior of heavy metals in sulfuric acid solutions an deionized water[J].Construction and Building Materials,2016,124:373.
29 Ming L Y, Kamarudin H, Mustafa A B A M, et al. Influence of solidification process on calcined kaolin geopolymeric powder[J].Advanced Materials Research,2012,479-481:286.
30 Wang J, Ye X X, Li P F, et al. Applications of single X-ray diffraction method in functional materials research[J].Journal of Inner Mongolia Agricultural University(Natural Science),2014(3):130(in Chinese).
王俊,叶鑫鑫,李鹏飞,等.单晶X射线衍射在功能材料研究中的应用[J].内蒙古农业大学学报(自然科学版),2014(3):130.
31 Zhang Y S, Sun W, She W, et al. Synthesis and heavy metal immobilization behaviors of slag based geopolymer[J].Journal of Wuhan University of Technology,2009,24(5):819.
32 Zheng L, Wang W, Shi Y. The effects of alkaline dosage and Si/Al ratio on the immobilization of heavy metals in municipal solid waste incineration fly ash based geopolymer[J].Chemosphere,2010,79(6):665.
33 Zhang L. Slag and siudge residue geopolymer cementitious materials preparation and curing effect of heavy metals[D].Shenzhen:Shen-zhen University,2015(in Chinese).
张雷.矿渣-污泥残渣地质聚合物胶凝材料的制备及重金属固化效果的研究[D].深圳:深圳大学,2015.
34 Ge Y, Cui X, Liao C, et al. Facile fabrication of green geo-polymer/alginate hybrid spheres for efficient removal of Cu(Ⅱ) in water: Batch and column studies[J].Chemical Engineering Journal,2017:25(4):311.
35 Xu J Z, Zhou Y L, Tang R X. Study on the solidification of heavy metals by fly ash based geopolymers[J].Journal of Building Mate-rials,2006,9(3):341(in Chinese).
徐建中,周云龙,唐然肖.地聚合物水泥固化重金属的研究[J].建筑材料学报,2006,9(3):341.
36 Jaarsveld J G S V, Deventer J S J V, Schwartzman A. The potential use of geopolymeric materials to immobilise toxic metals: Part Ⅱ. Material and leaching characteristics[J].Minerals Engineering,1999,12(1):75.
37 Zhang J, Provis J L, Feng D, et al. The role of sulfide in the immobilization of Cr(Ⅵ) in fly ash geopolymers[J].Cement and Concrete Research,2008,38(5):681.
38 Guo X L, Shi H S, Xu M F. Static and dynamie leaching experiments of heavy metals from fly ash-based geopolymers[J].Journal of Wuhan University of Technology(Materials Science Edition),2013,28(5):938.
39 Lancellotti I, Kamseu E, Michelazzi M, et al. Chemical stability of geopolymers containing municipal solid waste incinerator fly ash[J].Waste Management,2010,30(4):673.
40 Deja J. Immobilization of Cr⁶⁺, Cd²⁺, Zn²⁺, and Pb²⁺,in alkali-activated slag binders[J].Cement and Concrete Research,2002,32(12):1971.
41 Guo B, Pan D, Liu B, et al. Immobilization mechanism of Pb in fly ash based geopolymer[J].Construction and Building Materials,2017,134:123.
42 Zheng L, Wang W, Shi Y. The effects of alkaline dosage and Si/Al ratio on the immobilization of heavy metals in municipal solid waste incineration fly ash based geopolymer[J].Chemosphere,2010,79(6):665.
43 Phair J W, Deventer J S J V. Characterization of fly ash based geopolymeric binders activated with sodium aluminate[J].Industrial and Engineering Chemistry Research,2002,41(17):4242.
44 Boca S R A, Soares C, Riella H G. Geopolymers with a high percentage of bottom ash for solidification/immobilization of different toxic metals[J].Journal of Hazardous Materials,2016,318:145.
45 Palomo A, Grutzeck M W, Blanco M T. Alkali-activated fly ashes: A cement for the future[J].Cement and Concrete Research,1999,29(8):1323.
46 Rees C A, Provis J L, Lukey G C, et al. In situ ATR-FTIR study of the early stages of fly ash geopolymer gel formation[J].Langmuir the ACS Journal of Surfaces and Colloids,2007,23(17):9076.
47 Luna G Y, Fernández P C, Vale J. Stabilization/solidification of a municipal solid waste incineration residue using fly ash based geopolymers[J].Journal of Hazardous Materials,2010,185(1):373.
48 Jin M T, Huang C J, Chen L, et al. Immobilization of MSWI fly ash with geopolymers[J].Advanced Materials Research,2010,150-151:1564.