铜铟镓硒太阳能电池性能提升方法

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Abstract Copper indium gallium selenium (CIGS) solar cells have the advantages of high conversion efficiency, low production cost, no decay and little pollution. It is a promising new type of thin film solar cells. Its photoelectric conversion efficiency has reached 23.35% in the laboratory. It is of great significance to explore the photoelectric conversion mechanism and device performance improvement methods of CIGS to promote the development of photovoltaic industry. This paper comprehensively analyzes the development process, principle, structure and main technical ways to improve the performance of CIGS. (1) The development of post deposition technologies for various alkali metals, such as NaF-PDT, KF-PDT, RbF-PDT and Cs-PDT is mainly introduced; (2) the application of Zn (O, S), ZnS, (Zn, Mg)O in order to optimize the structure of the buffer layer, Cd free buffer layer materials were used to replace CdS buffer layer; (3) double or three layer Mo back electrode was used to solve the problem of Mo surface defects; (4) doping other elements (such as aluminum, chlorine or boron instead of zinc cation doping) to improve the conductivity of ZnO, and then optimize the window layer. Then, the photoelectric conversion mechanism and influencing factors of CIGS solar cells are analyzed, and the process route method based on theory optimization is proposed. Finally, the development trend of CIGS thin film solar cell technology is discussed.

Key words： CIGS alkali doping buffer layer Mo window layer

Published: 09 December 2021

CLC number:

TM914.4+2

Fund:This work was supported by the Major Project of the National Natural Science Foundation of China(51590902), Shanghai Talent Development Foundation (2018039).

About author:: Suying Ding, currently studying for a master's degree in enviromental engineering at Shanghai Polytechnic University，conducts research work under the guidance of Professor Zihua Wu. The current main research area is new energy materials.
Zihua Wu, graduated from the Shanghai Institute of Ceramics, Chinese Academy of Sciences wtih a professional doctorate. He is currently the professor of Shanghai Polytechnic University. The current main research area is design and fabrication of new energy materials and devices. More than 50 SCI papers have been published in Applied Physics letter, Journal of Applied Physics and other domestic and foreign journals, and more than 20 invention patents have been applied, including 12 authorized invention patents and 2 authorized utility models.

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	DING Suying
	WU Zihua
	XIE Huaqing
	WANG Yuanyuan
	LUAN Fuyuan
	YU Siqi

Cite this article:

DING Suying,WU Zihua,XIE Huaqing, et al. Methods to Improve Performance of Copper Indium Gallium Selenium Solar Cells[J]. Materials Reports, 2021, 35(z2): 1-7.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2021/V35/Iz2/1

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