碳材料促进硝基/卤素取代类有机污染物还原降解的研究进展

doi:10.11896/cldb.19030083

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Abstract Due to the advantages of high surface area, heterogeneous surface properties, excellent electron conductivity and electron storage capacity, carbon materials, including nano-carbon (e.g. graphene, carbon nano-tube, etc.) and amorphous carbon (including active carbon, biochar and black carbon, etc.) has been largely used in chemical industry, energy conservation, and environmental protection. In environmental application, carbon materials were mostly used as adsorbents. While in the last decade, carbon materials as the electron shuttle or redox mediator to facilitate electron transfer from electron donors (e.g. sulfide, iron/sulfide-reducing bacteria, etc) to electron acceptors (e.g. organic compounds, ≡Fe^III, etc) has received increasingly concern. The electron transfer mechanisms by carbon materials are essential to the understanding of the environmental processes of organic pollutants and to the development of environmental remediation technologies for those compounds.
Current researches mostly focused on the performance of carbon materials to the reductive transformation of nitro-aromatic compounds (NACs) and halo-substituted organic compounds (R-X). However, the mechanisms are varied depending on the properties of electron donors, organic compounds and carbon materials. Generally, three mechanisms have been accepted in different systems: Ⅰ. The oxygen functional groups on carbon surface play as the redox mediators to facilitate electron transfer. Ⅱ. The graphitic region and defect sites of carbon surface are highly conductive for electron transfer. Ⅲ. In the sulfide reduction conditions, carbon-sulfide intermediates would be the reactive sites for reductive degradation. In addition, surface area, porous structure and surface electric heterogeneous of carbon materials, as well as the structural properties of organic pollutants, the biotic/abiotic reaction systems would directly or indirectly influence the principle mechanisms. Since the matrix and surface of carbon materials have heterogeneous and complicated properties, the properties which control the electron transfer process have not yet fully understood. This review summarizes the reaction mechanisms that carbon materials mediated reductive transformation of NACs and R-X, upon which basis, modifications of carbon materials to further enhance the catalytic performance are also mentioned with the aim of application purposes. For the nano-carbon materials, surface modification and surface doping usually can facilitate the mass transfer efficiency and energy utilizing efficiency. For the porous carbon, chemical activation (by H₃PO₄ or ZnCl₂) and thermal activation would induce porous structure, large surface area, high electric conductivity and electron storage capacity. All of those modifications make the carbon materials more efficiently to catalyst NACs and R-X reduction degradation. It provides theoretical guidelines for the extensive requirement in groundwater remediation.
The environmental significance of this process stands on first, multi-forms of carbon in nature would directly or indirectly influence the environmental fate of organic compounds and element cycling. Second, carbon materials have great potential for the application in environmental reme-diation as for its environmental friendliness. It is expected that carbon materials could play more significant roles as the environmentally functional materials, for the elimination of NACs and R-X in anoxic groundwater.

Key words： carbon materials electron transfer mechanism nitro-aromatic compounds halo-substituted organic compounds redox process

Published: 03 January 2020

CLC number:

X703

Fund:This work was financially supported by the Natural Science Foundation of Jiangsu Province of China (BK20170634) and the Grants from Key Laboratory of Soil Environment and Pollution Remediation, Institute of Soil Science, Chinese Academy of Sciences(SEPR201708).

About author:: Xianhui Yue received her B.S. degree in Environmental Science from Guizhou University in 2016. She is currently a master degree candidate in the School of the Environment Nanjing University under the supervision of Prof. Cheng Gu. Her research program is about the enhanced reductive transformation of organic pollutants by charcoals;Cheng Gu received his Ph.D. degree in University of Wisconsin-Madison in 2006, after five-year postdoctoral research at Michigan State University. He has been selected as “The Second Junior Scientist” and been fun-ded by National Natural Science Foundation of China in 2012. His research interests include the pollutants and biomolecule's behavior at the interfacial environment, the synthesis of novel nanomaterials by the natural clay mineral as templates.

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Cite this article:

YUE Xianhui,JIN Xin,GU Cheng. Carbon Materials on Promoting Reductive Degradation of Nitro-/Halo-substituted Organic Pollutants:A Review[J]. Materials Reports, 2020, 34(3): 3028-3036.

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http://www.mater-rep.com/EN/10.11896/cldb.19030083 OR http://www.mater-rep.com/EN/Y2020/V34/I3/3028

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