光催化分解水制氢催化剂的研究进展

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Abstract With the decrease of non-renewable energy resources such as oil, coal and natural gas and the environmental pollution problem caused by them, the utilization of new alternatives to fossil fuels deserves intense attention. Hydrogen is a clean, renewable fuel that has the great potential to replace fossil fuels in the future. It is an efficient way to convert solar energy into hydrogen energy by photocatalytic hydrogen evolution.
However, most of the photocatalysts for hydrogen production still have problems such as low utilization of solar energy and easy recombination of photogenerated electrons and hole pairs, which leads to lower hydrogen production efficiency, thereby seriously restricting the practical application of photocatalysts. Therefore, the development of photocatalysts with low cost, environmental friendliness, visible light response and good performance has become the focus of research on photocatalytic hydrogen production.
Recent photocatalysts for hydrogen production mainly include metal oxides, metal sulfides, metal nitrogen (nitrogen and oxygen) compounds, graphite carbonitrides and novel heterostructure photocatalysts. Titanium dioxide, as a conventional photocatalyst for hydrogen production, has been studied. Metal sulfides exhibit good photocatalytic activity in hydrogen production due to their narrow band gap and good band gap positions, and the research mainly focuses on CdS, ZnS and their solid solutions. Metal nitrogen (nitrogen and oxygen) compounds have ideal visible full-hydrolysis energy band structure, which needs to be modified to show full-hydrolysis activity. Graphite carbonitride is a new type of non-metallic visible-light photocatalyst, which has been attracted widespread attention for its great potential in hydrogen production. In addition, the construction of binary or multicomponent heterostructure composite photocatalysts which can efficiently separate photogenerated carriers by semiconductor composite has also been extensively studied.
In this review, according to the research status of photocatalysts for hydrogen production at home and abroad in recent years, the research progress of photocatalysts was reviewed. The characteristics and research progress of each type of photocatalysts were summarized, and the preparation process and modification strategy of some photocatalysts were analyzed. Finally, the existing problems of photocatalysts were put forward and the future research prospects are also suggested, and is expected to provide reference for the design and preparation of efficient and stable photocatalytic materials.

Key words： solar energy water splitting hydrogen evolution photocatalysts

Published: 25 November 2019

CLC number:

O643.36

Fund:This work was financially supported by Science and Technology Planning Project of Guizhou Province (Talents of Guizhou Science and Technology Cooperation Platform [2017] 5789-02), Project of Training Objects for High-level Innovative Talents in Guizhou Province-100 Levels (0201004016004), Key Laboratory Project of Light Metal Material Technology of Guizhou Province (0201019016001).

About author:: Dabo Liu graduated from the School of Aeronautical Manufacturing Engineering in Nanchang Hangkong University in 2017, acquire the degree of Bachelor of Engineering. He is currently pursuing his Master’s degree at the College of Materials and Metallurgy, Guizhou University under the supervision of researcher Xiangdong Su. His research has focused on photocatalysts for hydrogen production.
Xiangdong Su received his B.E. degree in Department of Metallurgy from the Guizhou University of Technology in 1987 and received his Ph.D. degree in Department of Material Physics and Chemistry, Faculty of Science from Beihang University, in 2008. Later, he was a visi-ting scholar of “Light of the West” of the Institute of Process Engineering, Chinese Academy of Sciences, Vice-President of Guizhou Institute of Technology, part-time tutor of Master’s degree students of the School of Materials and Metallurgy of Guizhou University, director of the Chinese So-ciety of Materials Research, and judicial appraiser of the Ministry of Justice. He was awarded the first prize for scientific and technological achievements of Guizhou Provincial People’s Government, the first prize for scientific and technological progress of Guizhou Province, the first prize for science and technology of China’s non-ferrous metal industry, the second prize for young innovative talents of Guizhou Province, and the outstanding Communist Party members of Guizhou Direct Industry Committee.

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Cite this article:

LIU Dabo,SU Xiangdong,ZHAO Honglong. Research Progress in the Photocatalysts for Hydrogen Production by PhotocatalyticDecomposition of Water[J]. Materials Reports, 2019, 33(Z2): 13-19.

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http://www.mater-rep.com/EN/ OR http://www.mater-rep.com/EN/Y2019/V33/IZ2/13

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