碳纳米管表面处理及其在铜基复合材料中的应用

doi:10.11896/j.issn.1005-023X.2018.17.006

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Abstract  The excellent properties of carbon nanotubes (CNTs) derived from the special structure have attracted extensive attentions from researchers at home and abroad. The preparation of CNTs reinforced Cu matrix composites is an effective way to simultaneously achieve high strength and high conductivity of the copper conductor. Nonetheless, the high specific surface energy and poor reaction activity of CNTs have brought about two great challenges during the preparation of the CNTs/Cu composites, namely the agglomeration of CNTs and the poor interfacial bonding of the composites, which hinders the realization of high performance of CNTs/Cu composites. Surface treatment of CNTs can improve the surface structure and reactivity of CNTs, and further achieve a uniform CNTs dispersion and a strong interface bonding in the copper matrix composites, thus enhancing the efficiency of CNTs and high performance CNTs/Cu composites can be obtained.
   However, surface treatment may degrade the intrinsic properties and reinforcement efficiency of CNTs by damaging their structural integrity. Meanwhile, the impurities introduced by surface treatment may do harm to the electrical and thermal conductivity of the CNTs/Cu composites. As a result, the effects of CNTs surface treatment on both the properties of CNTs and the performance of CNTs/Cu composites should be taken into account seriously. Fortunately, researchers have broken through the key points in the preparation process of CNTs/Cu composites by optimizing the surface treatment process of CNTs in recent years. As a result, the mechanical properties of CNTs/Cu composites have been greatly improved and simultaneously the electrical and thermal conductivity of the CNTs/Cu composites have been achieved.
   Generally, there are four main methods of the surface treatment of CNTs, including mechanical ball milling, chemical surface modification, surface coating and combined surface treatment. Among them, the traditional mechanical ball milling would greatly damage the structure of CNTs. Chemical surface modification can be divided into covalent surface modification and non-covalent surface modification. The non-covalent surface modification can enhance the dispersion of the CNTs in solution while maintain their intact tubular structure and excellent properties. However, when it is applied to preparing the composites, a large number of organic impurities introduced cannot be completely removed, which limits the properties enhancement of the composites. Covalent surface modification and surface coating are the most commonly used and effective surface treatment methods in the preparation of copper matrix composites. They can improve the reactivity and dispersion performance of CNTs in the matrix, thus forming a strong reaction interface between CNTs and copper matrix. As a result, both the mechanical properties and the conductivity of CNTs/Cu composites would be enhanced. Moreover, a variety of surface treatment methods can be jointly used to take full advantage of each me-thod and obtain a better modification effect.
   In this article, research and application progress of surface treatment of carbon nanotubes in copper matrix composites are pre-sented based on different surface treatment approaches of CNTs and their effects on the structure and properties of the copper matrix composites, and the future directions regarding to the surface treatment study are proposed.

Key words： carbon nanotube surface treatment copper matrix composite

Published: 19 September 2018

CLC number:

TB333

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	WANG Jingwen
	ZHANG Jingjing
	FAN Tongxiang

Cite this article:

WANG Jingwen,ZHANG Jingjing,FAN Tongxiang. Process in Surface Treatment of Carbon Nanotubes and Its Applications to Copper Matrix Composites[J]. Materials Reports, 2018, 32(17): 2932-2939.

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http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2018.17.006 OR http://www.mater-rep.com/EN/Y2018/V32/I17/2932

1 Kim C, Lim B, Kim B, et al. Strengthening of copper matrix composites by nickel-coated single-walled carbon nanotube reinforcements[J].Synthetic Metals,2009,159(5-6):424.
2 Li Y, Xiao Z, Li Z, et al. Microstructure and properties of a novel Cu-Mg-Ca alloy with high strength and high electrical conductivity[J].Journal of Alloys & Compounds,2017,723:1162.
3 Arnaud C, Lecouturier F, Mesguich D, et al. High strength-high conductivity nanostructured copper wires prepared by spark plasma sintering and room-temperature severe plastic deformation[J].Materials Science & Engineering A,2016,649:209.
4 Jayathilaka W A D M, Chinnappan A, Ramakrishna S. A review of properties influencing the conductivity of CNT/Cu composites and their applications in wearable/flexible electronics[J].Journal of Materials Chemistry C,2017,5(36):9209.
5 Lu L, Shen Y, Chen X, et al. Ultrahigh strength and high electrical conductivity in copper[J].Science,2004,304(5669):422.
6 Treacy M M J, Ebbesen T W, Gibson J M. Exceptionally high Young’s modulus observed for individual carbon nanotubes[J].Nature,1996,381(6584):678.
7 Yu M F, Lourie O, Dyer M J, et al. Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load[J].Science,2000,287(5453):637.
8 Shukla A K, Nayan N, Murty S V S N, et al. Processing of copper-carbon nanotube composites by vacuum hot pressing technique[J].Materials Science & Engineering A Structural Materials Properties Microstructure & Processing,2013,560(560):365.
9 de Volder M F, Tawfick S H, Baughman R H, et al. Carbon nanotubes: Present and future commercial applications[J].Science,2013,339(6119):535.
10 Qian D, Dickey E C, Andrews R, et al. Load transfer and deformation mechanisms in carbon nanotube-polystyrene composites[J].Applied Physics Letters,2000,76(20):2868.
11 Habisreutinger S N, Leijtens T, Eperon G E, et al. Carbon nanotube/polymer composites as a highly stable hole collection layer in perovskite solar cells[J].Nano Letters,2014,14(10):5561.
12 Pierard N, Fonseca A, Konya Z, et al. Production of short carbon nanotubes with open tips by ball milling[J].Chemical Physics Letters,2001,335(1):1.
13 Tucho W M, Mauroy H, Walmsley J C, et al. The effects of ball milling intensity on morphology of multiwall carbon nanotubes[J].Scripta Materialia,2010,63(6):637.
14 Soares O S G P, Gonçalves A G, Delgado J J, et al. Modification of carbon nanotubes by ball-milling to be used as ozonation catalysts[J].Catalysis Today,2015,249:199.
15 Soares O S G P, Rocha R P, Gonçalves A G, et al. Easy method to prepare N-doped carbon nanotubes by ball milling[J].Carbon,2015,91:114.
16 Cai X L, Wang Z Y, Zhang W Z, et al. Preparation of multiwalled carbon nanotubes embedded in copper composite powders[J].Integrated Ferroelectrics,2015,164(1):122.
17 Bor A, Ichinkhorloo B, Uyanga B, et al. Cu/CNT nanocomposite fabrication with different raw material properties using a planetary ball milling process[J].Powder Technology,2016,323:563.
18 Maqbool A, Hussain M A, Khalid F A, et al. Mechanical characte-rization of copper coated carbon nanotubes reinforced aluminum matrix composites[J].Materials Characterization,2013,86(8):39.
19 Sang W K, Kim T, Kim Y S, et al. Surface modifications for the effective dispersion of carbon nanotubes in solvents and polymers[J].Carbon,2012,50(1):3.
20 Tsang S C, Chen Y K, Harris P J F, et al. A simple chemical met-hod of opening and filling carbon nanotubes[J].Nature,1994,372(6502):159.
21 Yao Y X, Tan X L, Tan X L, et al. Removal and adsorption of p-nitrophenol from aqueous solutions using carbon nanotubes and their composites[J].Journal of Nanomaterials,2014,2014(1):84.
22 Neubauer E, Kitzmantel M, Hulman M, et al. Potential and challenges of metal-matrix-composites reinforced with carbon nanofibers and carbon nanotubes[J].Composites Science & Technology,2010,70(16):2228.
23 Cha S I, Kim K T, Arshad S N, et al. Extraordinary strengthening effect of carbon nanotubes in metal-matrix nanocomposites processed by molecular-level mixing[J].Advanced Materials,2005,17(11):1377.
24 Cho S, Kikuchi K, Miyazaki T, et al. Multiwalled carbon nanotubes as a contributing reinforcement phase for the improvement of thermal conductivity in copper matrix composites[J].Scripta Materialia,2010,63(4):375.
25 Yang M, Weng L, Zhu H, et al. Simultaneously enhancing the strength, ductility and conductivity of copper matrix composites with graphene nanoribbons[J].Carbon,2017,118:250.
26 Garg A, Sinnott S B. Effect of chemical functionalization on the mechanical properties of carbon nanotubes[J].Chemical Physics Letters,1998,295(4):273.
27 Firkowska I, Boden A, Vogt A M, et al. Effect of carbon nanotube surface modification on thermal properties of copper-CNT compo-sites[J].Journal of Materials Chemistry,2011,21(43):17541.
28 Liu C H, Fan S S. Effects of chemical modifications on the thermal conductivity of carbon nanotube composites[J].Applied Physics Letters,2005,86(12):215502.
29 Martin C A, Sandler J K W, Windle A H, et al. Electric field-induced aligned multi-wall carbon nanotube networks in epoxy composites[J].Polymer,2005,46(3):877.
30 Strano M S, Moore V C, Miller M K, et al. The role of surfactant adsorption during ultrasonication in the dispersion of single-walled carbon nanotubes[J].Journal of Nanoscience & Nanotechnology,2003,3(1-2):81.
31 Moore V C, Strano M S, Haroz E H, et al. Individually suspended single-walled carbon nanotubes in various surfactants[J].Nano Letters,2003,3(10):1379.
32 Zhang X, Zhang J, Wang R, et al. Cationic surfactant directed polya-niline/CNT nanocables: Synthesis, characterization, and enhanced electrical properties[J].Carbon,2004,42(8-9):1455.
33 O’Connell M J, Bachilo S M, Huffman C B, et al. Band gap fluorescence from individual single-walled carbon nanotubes[J].Science,2002,297(5581):593.
34 Jung M S, Ko Y K, Jung D H, et al. Effects of surface modification of carbon nanotubes on the microstructure and electrical properties of carbon nanotubes/rubber nanocomposites[J].Chemical Physics Letters,2008,457(4-6):352.
35 Park O K, Jeevananda T, Kim N H, et al. Effects of surface modification on the dispersion and electrical conductivity of carbon nanotube/polyaniline composites[J].Scripta Materialia,2009,60(7):551.
36 Jiang L, Fan G, Li Z, et al. An approach to the uniform dispersion of a high volume fraction of carbon nanotubes in aluminum powder[J].Carbon,2011,49(6):1965.
37 Li Z, Jiang L, Fan G, et al. High volume fraction and uniform dispersion of carbon nanotubes in aluminium powders[J].IET Micro & Nano Letters,2010,5(6):379.
38 Chowdhury T, Rohan J F. Influence of carbon nanotubes on the electrodeposition of copper interconnects[J].ECS Transactions,2010,25(38):37.
39 Geng H Z, Kim K K, So K P, et al. Effect of acid treatment on carbon nanotube-based flexible transparent conducting films[J].Journal of the American Chemical Society,2007,129(25):7758.
40 Kang P S, Lee I H, Duong D L, et al. Improving the wettability of aluminum on carbon nanotubes[J].Acta Materialia,2011,59(9):3313.
41 Wang F, Arai S, Endo M. Metallization of multi-walled carbon nanotubes with copper by an electroless deposition process[J].Electrochemistry Communications,2004,6(10):1042.
42 Laha T, Kuchibhatla S, Seal S, et al. Interfacial phenomena in thermally sprayed multiwalled carbon nanotube reinforced aluminum nanocomposite[J].Acta Materialia,2007,55(3):1059.
43 Li Q, Fan S, Han W, et al. Coating of carbon nanotube with nickel by electroless plating method[J].Japanese Journal of Applied Phy-sics,1997,36(4):L501.
44 Jagannatham M, Sankaran S, Prathap H. Electroless nickel plating of arc discharge synthesized carbon nanotubes for metal matrix composites[J].Applied Surface Science,2015,324:475.
45 Chen X, Xia J, Peng J, et al. Carbon-nanotube metal-matrix compo-sites prepared by electroless plating[J].Composites Science & Technology,2000,60(2):301.
46 Koppad P G, Ram H R A, Kashyap K T. On shear-lag and thermal mismatch model in multiwalled carbon nanotube/copper matrix nanocomposites[J].Journal of Alloys & Compounds,2013,549(2):82.
47 Daoush W M, Lim B K, Mo C B, et al. Electrical and mechanical properties of carbon nanotube reinforced copper nanocomposites fabricated by electroless deposition process[J].Materials Science & Engineering A,2009,s 513-514(11):247.
48 Wang H, Zhang Z H, Hu Z Y, et al. Synergistic strengthening effect of nanocrystalline copper reinforced with carbon nanotubes[J].Scientific Reports,2016,6:26258.
49 Sahraei A A, Fathi A, Givi M K B, et al. Fabricating and improving properties of copper matrix nanocomposites by electroless copper-coated MWCNTs[J].Applied Physics A,2014,116(4):1677.
50 Huang Jianhua, Sun Xiaogang, Li Jing, et al. Research of carbon nanotubes with electroless plating of cobalt[J].Materials Review,2008,22(z1):109(in Chinese).
黄建华,孙晓刚,李静,等.碳纳米管表面化学镀Co的研究[J].材料导报,2008,22(z1):109.
51 Rajukumar L P, Belmonte M, Slimak J E, et al. Covalent networks: 3D nanocomposites of covalently interconnected multiwalled carbon nanotubes with SiC with enhanced thermal and electrical properties[J].Advanced Functional Materials,2015,25(31):4922.
52 Tan Z, Li Z, Fan G, et al. Two-dimensional distribution of carbon nanotubes in copper flake powders[J].Nanotechnology,2011,22(22):225603.
53 Cho S, Kikuchi K, Miyazaki T, et al. Epitaxial growth of chromium carbide nanostructures on multiwalled carbon nanotubes (MWCNTs) in MWCNT-copper composites[J].Acta Materialia,2013,61(2):708.
54 Cho S, Kikuchi K, Kawasaki A et al. Effective load transfer by a chromium carbide nanostructure in a multi-walled carbon nanotube/copper matrix composite[J].Nanotechnology,2012,23(31):315705.
55 Estili M, Kawasaki A. Engineering Strong intergraphene shear resistance in multi-walled carbon nanotubes and dramatic tensile improvements[J].Advanced Materials,2010,22(5):607.
56 Kim K T, Cha S I, Gemming T, et al. The role of interfacial oxygen atoms in the enhanced mechanical properties of carbon-nanotube-reinforced metal matrix nanocomposites[J].Small,2008,4(11):1936.
57 Cha S I, Kim K T, Arshad S N, et al. Field-emission behavior of a carbon-nanotube-implanted Co nanocomposite fabricated from pearl-necklace-structured carbon nanotube/Co powders[J].Advanced Materials,2010,18(5):553.
58 Cha S I, Kim K T, Lee K H, et al. Strengthening and toughening of carbon nanotube reinforced alumina nanocomposite fabricated by molecular level mixing process[J].Scripta Materialia,2005,53(7):793.
59 Park M, Kim B H, Kim S, et al. Improved binding between copper and carbon nanotubes in a composite using oxygen-containing functional groups[J].Carbon,2011,49(3):811.60 Cho S, Kikuchi K, Kawasaki A. On the role of amorphous intergranular and interfacial layers in the thermal conductivity of a multi-walled carbon nanotube-copper matrix composite[J].Acta Materialia,2012,60(2):726.
61 Nie J, Jia C, Jia X, et al. Fabrication, microstructures, and properties of copper matrix composites reinforced by molybdenum-coated carbon nanotubes[J].Rare Metals,2011,30(4):401.
62 Akbarpour M R. Analysis of load transfer mechanism in Cu reinforced with carbon nanotubes fabricated by powder metallurgy route[J].Journal of Materials Engineering & Performance,2016,25(5):1.
63 Chen B, Li S, Imai H, et al. Load transfer strengthening in carbon nanotubes reinforced metal matrix composites via in-situ tensile tests[J].Composites Science & Technology,2015,113:1.
64 Wang F C, Zhang Z H, Sun Y J, et al. Rapid and low temperature spark plasma sintering synthesis of novel carbon nanotube reinforced titanium matrix composites[J].Carbon,2015,95:396.
65 Kim K T, Cha S I, Hong S H. Hardness and wear resistance of carbon nanotube reinforced Cu matrix nanocomposites[J].Materials Science & Engineering A,2007,449(12):46.
66 Kim K T, Eckert J, Menzel S B, et al. Grain refinement assisted strengthening of carbon nanotube reinforced copper matrix nanocomposites[J].Applied Physics Letters,2008,92(12):31.
67 Xue Z W, Wang L D, Zhao P T, et al. Microstructures and tensile behavior of carbon nanotubes reinforced Cu matrix composites with molecular-level dispersion[J].Materials & Design,2012,34:298.
68 Arai S, Saito T, Endo M. Effects of additives on Cu-MWCNT composite plating films[J].Journal of the Electrochemical Society,2010,157(3):D127.
69 Subramaniam C, Yamada T, Kobashi K, et al. One hundred fold increase in current carrying capacity in a carbon nanotube-copper composite[J].Nature Communications,2013,4(3):2202.
70 Dong Q, Shen L, Cao F, et al. Effect of thermomechanical proces-sing on the microstructure and properties of a Cu-Fe-P alloy[J].Journal of Materials Engineering & Performance,2015,24(4):1531.
71 Shangina D, Maksimenkova Y, Bochvar N, et al. Influence of alloying with hafnium on the microstructure, texture, and properties of Cu-Cr alloy after equal channel angular pressing[J].Journal of Materials Science,2016,51(11):5493.
72 An Z, Toda M, Ono T. Comparative investigation into surface charged multi-walled carbon nanotubes reinforced Cu nanocompo-sites for interconnect applications[J].Composites Part B Enginee-ring,2016,95:137.