METALS AND METAL MATRIX COMPOSITES |
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Influence of Plating Parameters on Microstructure and Properties of the Ni-TiN Nanocoating Prepared by Pulse Electrodeposition |
XIA Fafeng, YANG Anna, MA Chunyang
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College of Mechanical Science and Engineering, Northeast Petroleum University, Daqing 163318 |
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Abstract Electrodeposition technology is a kind of convenient, efficient, low cost method for preparing metal matrix nanocoatings, and the plating parameters directly determine the microstructure and properties of the coating. In order to investigate the influence of plating parameters on surface morphology, microstructure, mechanical properties and wear resistance of metal matrix nanocoatings, Ni-TiN nanocoatings were successfully prepared by using pulse electrodeposition method in this paper, and the influence of plating parameters on microstructure, microhardness and properties of the coating was investigated with the use of transmission electron microscopy (TEM), atomic force microscopy (AFM), X-ray diffraction (XRD) and friction wear testing machine. The results showed that the Ni-TiN nanocoating obtained at 4 A/dm2 current density exhibited an optimum microhardness and TiN content values of 984.7HV and 8.69 wt%, respectively. Ni-TiN nanocoatings prepared at different pulse frequencies exhibited fcc structure in different directions. The average grain diameters of Ni and TiN in the nanocoating prepared at 200 Hz were 87.2 nm and 34.6 nm, respectively. The nanocoating prepared at 20% duty cycle showed an optimum microhardness and average wear of 980HV and 7.56 mg/mm2, respectively.
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Published: 31 July 2018
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1 Fang Xiaohong. Research progress for ultrasound-assisted electroplating of Ni and Ni-based composite coatings[J]. Materials Protection,2008,41(5):58(in Chinese). 方小红.超声波电镀镍及镍基复合镀层的研究进展[J].材料保护,2008,41(5):58. 2 Xia F, Tian J, Ma C, et al. Effect of pulse frequency on microstructural, nanomechanical, and wear properties of electrodeposited Ni-TiN composite coatings[J]. Journal of Applied Physics,2014,116(23):9279. 3 Amadeh A, Rahimi A, Farshchian B, et al. Corrosion behavior of pulse electrodeposited nanostructure Ni-SiC composite coatings[J]. Journal of Nanoscience and Nanotechnology,2010,10(8):5383. 4 Abdel A. Hard and corrosion resistant nanocomposite coating for Al alloy[J]. Materials Science and Engineering A,2008,474:181. 5 Ma C, Guo X, Leang J, et al. Synthesis and characterization of Ni-P-TiN nanocomposites fabricated by magnetic electrodeposition technology[J]. Ceramics International,2016,42(11):10428. 6 Li X Y, Zhu Y Y, Xiao G R. Application of arti-cial neural networks to predict sliding wear resistance of Ni-TiN nanocomposite coatings deposited by pulse electrodeposition[J]. Ceramics International,2014,40(8):11767. 7 Li X Y. Prediction of TiN particle composite of Ni-TiN coatings based on AR model[J]. Journal of Synthetic Crystals,2016,45(6):1703(in Chinese). 李兴远.基于AR模型的Ni-TiN复合镀层TiN粒子复合量预测研究[J].人工晶体学报,2016,45(6):1703. 8 Xia F F, Huang M, Ma C Y, et al. Effect of electrodeposition met-hods on corrosion resistance of Ni-SiC nanocomposite coatings[J]. Journal of Functional Materials,2013,44(16):2429(in Chinese). 夏法锋,黄明,马春阳,等.电沉积方式对Ni-SiC纳米镀层耐腐蚀性能的影响[J].功能材料,2013,44(16):2429. 9 Wang Y, Zhou Q, Li K, et al. Preparation of Ni-W-SiO2 nanocomposite coating and evaluation of its hardness and corrosion resistance[J]. Ceramics International,2015,41(1):79. 10 Meng K L, Yao P P. Effect of α-SiC particle size on friction and wear properties of copper-matrix friction material[J]. Materials Science & Engineering of Powder Metallurgy,2010,15(3):294(in Chinese). 孟康龙,姚萍屏.α-SiC的粒度对铜基摩擦材料摩擦磨损的影响[J].粉末冶金材料科学与工程,2010,15(3):294. 11 Lee H K, Lee H Y, Jeon J M. Codeposition of micro-and nano-sized SiC particles in the nickel matrix composite coatings obtained by electroplating[J]. Surface and Coatings Technology,2007,201:4711. 12 Ma C Y, Ding J J, Chu D Q. Effect of pulse electrodeposition parameters on the performance of Ni-SiC composite coatings[J]. Ordnance Material Science & Engineering,2012,35(4):65(in Chinese). 马春阳,丁俊杰,楚殿庆.脉冲电沉积工艺参数对Ni-SiC复合镀层性能的影响[J].兵器材料科学与工程,2012,35(4):65. 13 Wu Menghua, Li Lintai, Wang Yuangang, et al. Microstructure and wear resistance of nano TiN/Ni composite coatings prepared by different electrodeposition methods[J]. Mechanical Engineering Materials,2016,40(12):78(in Chinese). 吴蒙华,李霖泰,王元刚,等.不同方式电沉积纳米TiN/Ni复合镀层的组织和耐磨损性能[J].机械工程材料,2016,40(12):78. 14 Xia F, Yue W, Wang J D,et al. Synthesis of Ni-TiN composite nanocoatings by magnetic pulse current deposition[J]. Ceramics International,2015,41(9):11445. |
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