伽马射线辐照改性聚丙烯腈原丝及聚丙烯腈基碳纤维的研究进展

doi:10.11896/j.issn.1005-023X.2018.07.011

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Abstract The polyacrylonitrile (PAN)-based carbon fibers have found wide application in a diverse variety of industries because of their superb performance and the facile preparation technique, while nevertheless been suffering many problems such as the extreme surface chemical inertness and the imperfect mechanical performance. This urges intensive research endeavors which have bred various modification methods to enhance the PAN-based carbon fibers. Among these methods, the γ-irradiation treatment is effective to achieve the synergetic improvement in both of the surface activities and the mechanical performance, and meanwhile can be applied to the preparation of PAN precursor fibers and the subsequent treatment process. The present paper aims to provide an overview of the γ-irradiation treatment for PAN precursor fibers and PAN-based carbon fibers, from several facets including the induced changes in the fibers’ crystalline structure, surface and interfacial properties, and mechanical properties. We make emphasis on the evolutionary course of the γ-ray-induced cross-linking of PAN precursor fiber molecules, the impact of precursor γ-irradiation to mechanical properties of the final carbon fibers, and the relationship between product’s different microzone structure evolution and mechanical properties under γ-irradiation. The review ends with a delineation of the development direction and the future prospect for this emerging technique.

Key words： carbon fiber γ-irradiation polyacrylonitrile fibers mechanical performance

Published: 11 May 2018

CLC number:

TQ342+.31

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	Articles by authors
	FENG Tingting
	LIU Liangsen
	MA Tianshuai
	XU Zhiwei
	LI Jing
	FU Hongjun
	KUANG Liyun
	LI Yinglin

Cite this article:

FENG Tingting,LIU Liangsen,MA Tianshuai, et al. Enhancing Polyacrylonitrile Precursor Fibers and Polyacrylonitrile-based Carbon Fibers via Gamma-irradiation: a Review[J]. Materials Reports, 2018, 32(7): 1114-1121.

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http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2018.07.011 OR http://www.mater-rep.com/EN/Y2018/V32/I7/1114

1 Zhang J J. Market and development of carbon fiber at home and abroad[J].Chemical Techno-Economics,2005,23(4):12(in Chinese).
张家杰.国内外碳纤维生产现状及发展趋势[J].化工技术经济,2005,23(4):12.
2 Lou Y F. The new situation of carbon fiber and new technology[J].New Carbon Materials,1995(4):13(in Chinese).
罗益锋.炭纤维的新形势与新技术[J].新型炭材料,1995(4):13.
3 Kobets L P, Deev I S. Carbon fibers:Structure and mechanical pro-perties of carbon fibers[J].Carbon,1998,36(4):345.
4 张开.粘合与密封材料[M].北京:化学工业出版社,1996.
5 Yu M, Xu Y, Wang C, et al. Heredity and difference of multiple-scale microstructures in PAN-based carbon fibers and their precursor fibers[J].Journal of Applied Polymer Science,2012,125(4):3159.
6 Jiang J, Yao X, Xu C, et al. Influence of electrochemical oxidation of carbon fiber on the mechanical properties of carbon fiber/graphene oxide/epoxy composites[J].Composites:Part A,2017,95:248.
7 Sun Y H T. Wettability modification of polyacrylonitrile (PAN)-based high modulus carbon fibers with epoxy resin by low temperature plasma[J].Journal of Adhesion,2013,89(3):192.
8 Xu Z, Huang Y, Min C, et al. Effect of γ-ray radiation on the polya-crylonitrile-based carbon fibers[J].Radiation Physics & Chemistry,2010,79(8):839.
9 Shin H K, Park M, Kim H Y, et al. An overview of new oxidation methods for polyacrylonitrile-based carbon fibers[J].Carbon Letters,2015,16(1):11.
10Jiao M L, Yu L W, Xiao R, et al. Behavior of electro responsive HPAN/SPI hydrogel fibers under an electric stimulus[J].Chinese Journal of Materials Research,2005,19(6):663(in Chinese).
焦明立,俞力为,肖茹,等.水解聚丙烯腈/大豆分离蛋白凝胶纤维的电刺激性能[J].材料研究学报,2005,19(6):663.
11Zhang Y H. Production technology of fire-retardant polyacrylonitrile fiber[J].China Textile Leader,2002(2):23(in Chinese).
张玉海.阻燃聚丙烯腈纤维生产技术[J].现代纺织技术,2002(2):23.
12Tan L, Wan A. Structural changes of polyacrylonitrile precursor fiber induced by γ-ray irradiation[J].Materials Letters,2011,65(19):3109.
13 Ji J Q. The effect of γ-ray irradiation of polyacrylonitrile fibers on oxidation and carbonization processes[D].Shanghai:Donghua University,2013(in Chinese).
季加强.辐照改性聚丙烯腈纤维对预氧化碳化的影响[D].上海:东华大学,2013.
14 Gao Y J. Structure of irradiated PAN original fiber and the influence on pre-oxidation process[D].Beijing:Beijing University of Chemical Technology,2015(in Chinese).
高益军.辐照PAN原丝结构及其对预氧化进程的影响[D].北京:北京化工大学,2015.
15 Liu W, Wang M, Xing Z, et al. Radiation-induced crosslinking of polyacrylonitrile fibers and the subsequent regulative effect on the preoxidation process[J].Radiation Physics & Chemistry,2012,81:622.
16 Zhao W, Yukio Yamamoto A, Tagawa S. Regulation of the thermal reactions of polyacrylonitrile by γ-irradiation[J].Chemistry of Materials,1999,11(4):1030.
17 Zhou L, Lu Y, Zhao W, et al. Effects of gamma ray irradiation on poly(acrylonitrile-co-methyl acrylate) fibers[J].Polymer Degradation & Stability,2015,128:149.
18 Zhao W, Lu Y, Jiang J, et al. The effect of γ-ray irradiation on the microstructure and thermal properties of polyacrylonitrile fibers[J].RSC Advances,2015,5(30):23508.
19 Ji J Q,Lv Y G,Zhao W Z. Effect of γ-ray irradiation on polyacrylonitrile precursor and its preoxidation process[J].Synthetic Fiber Industry,2013,36(6):1(in Chinese).
季加强,吕永根,赵卫哲.γ射线辐照对聚丙烯腈原丝及其预氧化反应的影响[J].合成纤维工业,2013,36(6):1.
20Liu S, Liu R, Han K, et al. Influence of γ-ray irradiation on structure and properties of PAN precursor fibers[J].Polymer Engineering & Science,2016,56(11):1313.
21Liu W H,Wang M H,Zhang W F, et al. Effect of γ-ray irradiation on the pre-oxidation of polyacrylonitrile fibers[J].Polymer Materials Science & Engineering,2015(5):51(in Chinese).
刘伟华,王谋华,张文发,等.γ射线辐照处理对聚丙烯腈纤维预氧化反应的影响[J].高分子材料科学与工程,2015(5):51.
22Tarakanov B M. Effect of γ-radiation on the structure and thermal properties of polyacrylonitrilefibres[J].Fibre Chemistry,1996,30(3):123.
23 Zhai J. Effect of PAN precursor modification on the structure and performance of preoxidized fibers[D].Shanghai:Donghua University,2011(in Chinese).
翟佳.原丝改性对PAN预氧化纤维结构和性能的影响[D].上海:东华大学,2011.
24 Zhao W, Lu Y, Zhou L, et al. Effects on the oriented structure and mechanical properties of carbon fibers by pre-irradiating polyacrylonitrile fibers with γ ray[J].Journal of Materials Science,2016,51(15):7073.
25 Li J Q, Huang Y D, Wang Z, et al. The effect on carbon fiber surface structure and tensile strength irradiated by γ-ray[J].Journal of Aeronautical Materials,2005,25(6):52(in Chinese).
李峻青,黄玉东,王卓,等.γ-射线辐照对碳纤维表面结构以及强度的影响[J].航空材料学报,2005,25(6):52.
26 Xiao H, Lu Y, Wang M, et al. Effect of gamma-irradiation on the mechanical properties of polyacrylonitrile-based carbon fiber[J].Carbon,2013,52(2):427.
27 Xu Z, Huang Y, Zhang C, et al. Influence of rare earth treatment on interfacial properties of carbon fiber/epoxy composites[J].Materials Science & Engineering A,2007,444(1):170.
28 Li B, Feng Y, Qian G, et al. The effect of gamma ray irradiation on PAN-based intermediate modulus carbon fibers[J].Journal of Nuc-lear Materials,2013,443(1):26.
29 Cataldo F, Cataldo F. A Raman study on radiation-damaged graphite by γ-rays[J].Carbon,2000,38(4):634.
30Liu L, Wu F, Yao H, et al. Investigation of surface properties of pristine and γ-irradiated PAN-based carbon fibers: Effects of fiber instinct structure and radiation medium[J].Applied Surface Science,2015,337(11):241.
31Xu Y J, Li J Q, Jiang L L, et al. The effect of carbon fiber after γ-ray irradiation on the mechanical properties of its composite[J].Synthetic Materials Aging and Application,2006,35(4):31(in Chinese).
徐用军,李峻青,姜琳琳,等.γ-射线辐照碳纤维对其复合材料力学性能的影响[J].合成材料老化与应用,2006,35(4):31.
32Xu Z, Huang Y, Zhang C, et al. Effect of γ-ray irradiation grafting on the carbon fibers and interfacial adhesion of epoxy composites[J].Composites Science & Technology,2007,67(15-16):3261.
33 Zhang H, Zhang Z. Comparison of short carbon fibre surface treatments on epoxy composites: Ⅱ. Enhancement of the wear resistance[J].Composites Science & Technology,2004,64(13-14):2021.
34 Kalantar J, Drzal L T. The bonding mechanism of aramid fibres to epoxy matrices[J].Journal of Materials Science,1990,25(10):4186.
35 Li J, Huang Y, Xu Z, et al. High-energy radiation technique treat on the surface of carbon fiber[J].Materials Chemistry & Physics,2005,94(2-3):315.
36 Tiwari S, Bijwe J, Panier S. Gamma radiation treatment of carbon fabric to improve the fiber-matrix adhesion and tribo-performance of composites[J].Wear,2011,271(9-10):2184.
37 Tiwari S, Bijwe J, Panier S. Polyetherimide composites with gamma irradiated carbon fabric: Studies on abrasive wear[J].Wear,2011,270(9-10):688.
38 Ma H Y, Huang Y D, Zhang Z Q, et al. Effect of Co⁶⁰ gamma ray irradiation for carbon fibre on interfacial properties in epoxy resin composites[J].Materials Science &Technology,2002,18(12):1585.
39 Ma H Y, Huang Y D, Zhang Z Q. The effect of γ-ray radiating carbon fiber on interfacial property of composite[J].Journal of Materials Engineering,2000(4):26(in Chinese).
马恒怡,黄玉东,张志谦.碳纤维γ射线辐照处理对其复合材料界面性能的影响[J].材料工程,2000(4):26.
40Sui X, Xu Z, Hu C, et al. Microstructure evolution in γ-irradiated carbon fibers revealed by a hierarchical model and Raman spectra from fiber section[J].Composites Science & Technology,2016,130:46.
41Bennett S C, Johnson D J. Electron-microscope studies of structural heterogeneity in PAN-based carbon fibres[J].Carbon,1979,17:25.
42Guo X, Zhang K, Fan Z, et al. Study on microstructure of transition zone and its strong contrast of single T700 carbon fibers[J].Applied Surface Science,2017,406:274.
43 Guo X, Cheng Y, Fan Z, et al. New insights into orientation distribution of high strength polyacrylonitrile-based carbon fibers with skin-core structure[J].Carbon,2016,109:444.
44 Oku T, Imamura Y, Kurumada A, et al. Effect of neutron irradiation on the microstructures and tensile properties of different carbon fibers[J].Science Reports of the Research Institutes,1997,45:63.
45 Li J Q, Xu Y J, Zhang H Z. Effect of γ-ray irradiation on the mechanical property of carbon fiber reinforced composite[J].Synthetic Fiber,2006,35(11):20(in Chinese).
李峻青,徐用军,张怀志.γ-射线辐照对碳纤维及其复合材料力学性能的影响[J].合成纤维,2006,35(11):20.