| MATERIALS AND SUSTAINABLE DEVELOPMENT: ADVANCED MATERIALS FOR CLEAN ENERGY UTILIZATION |
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| Construction of a Hydrogen Permeation Model and with an Application to Nb-based Hydrogen Permeable Alloy |
YAN Erhu1,2,3, HUANG Haoran1, LIU Guizhong1,2, BAN Yufeng1,
XU Fen1,2, SUN Lixian1,2
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1 School of Material Science and Engineering, Guilin University of Electronic Technology, Guilin 541004;
2 Guangxi Corpuscle Information Material Structure Activity Relation Emphasis Laboratory, Guilin University of Electronic Technology, Guilin 541004;
3 School of Material Science and Engineering, Harbin Institute of Technology, Harbin 150001 |
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Abstract Based on Fick’s second law, a new mathematical model of hydrogen permeation was derived, and the corresponding Matlab program was compiled successfully. According to this model, a new method for calculating hydrogen diffusion coefficient and solubility coefficient of Nb-based hydrogen permeable alloy was established. Based on the calculated results of Nb-based hydrogen permeable alloy at different temperatures and the comparison with experimental and literature results, the feasibility and effectiveness of the proposed model were verified.
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Published: 10 March 2018
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1 Pati S, Jat R A, Anand N S, et al. Pd-Ag-Cu dense metallic membrane for hydrogen isotope purification and recovery at low pressures[J].Journal of Membrane Science,2017,522:151.
2 Chen J, Zhu M. Progress in research of hydrogen storage materials with high capacity[J].Materials China,2009,28(5):1(in Chinese).
陈军,朱敏.高容量储氢材料的研究进展[J].中国材料进展,2009,28(5):1.
3 潘洪革.多结构、多形貌、多尺度铁氧化物/碳锂离子电池负极材料[C]∥第七届中国储能与动力电池及其关键材料学术研讨与技术交流会.桂林,2015:62.
4 Pikin F, Akyldz H, ztürk T. Ti modified Pd-Ag membranes for hydrogen separation[J].International Journal of Hydrogen Energy,2015,40:7553.
5 李星国,谢镭,曲江兰,等.纳米结构储氢材料的合成和性能研究[C]∥第七届中国功能材料及其应用学术会议.长沙,2010:437.
6 Li X Z, Huang F F, Liu D M, et al. V-Cr-Cu dual-phase alloy membranes for hydrogen separation: An excellent combination of ductility, hydrogen permeability and embrittlement resistance[J].Journal of Membrane Science,2017,524:354.
7 Dolan M D. Non-Pd BCC alloy membranes for industrial hydrogen separation[J].Journal of Membrane Science,2010,362:12.
8 Paglieri S N, Pal N K, Dolan M D, et al. Hydrogen permeability, thermal stability and hydrogen embrittlement of Ni-Nb-Zr and Ni-Nb-Ta-Zr amorphous alloy membranes[J].Journal of Membrane Science,2011,378:42.
9 Yukawa H, Tsukada C, Nambu T, et al. Hydrogen solubility and permeability of V-W-Mo alloy membrane for hydrogen separation and purification[J].Journal of Alloys and Compounds,2013,580:S386.
10 Hashi K, Ishikawa K, Matsuda T, et al. Hydrogen permeation characteristics of (V,Ta)-Ti-Ni alloys[J].Journal of Alloys and Compounds,2005,404:273.
11 Basile A, Iulianeli A. Advances in hydrogen production, storage and distribution[M].England:Woodhead Publishing,2014:341.
12 Wu Z F. Fabrication and characterization of Pd/porous TiAl alloy composite membrane for hydrogen separation[D].Changsha:Central South University of Technology,2008(in Chinese).
武治锋.Pd/多孔TiAl合金复合透氢膜制备与性能研究[D].长沙:中南工业大学,2008.
13 Jeon S I, Magnone E, Park J H, et al. The effect of temperature and pressure on the hydrogen permeation through Pd-coated Ti26Ni21-V53 alloy membrane under different atmospheres[J].Materials Letters,2011,65:2495.
14 Hashi K, Ishikawa K, Matsuda T, et al. Hydrogen permeation cha-racteristics of multi-phase Ni-Ti-Nb alloys[J].Journal of Alloys and Compounds,2004,368:215.
15 Dolan M D, Kellam M E, McLennan K G, et al. Hydrogen transport properties of several vanadium-based binary alloys[J].International Journal of Hydrogen Energy,2013,38:9794.
16 Magnone E, Jeon S, Parka J H, et al. Relationship between microstructure and hydrogen permeation properties in the multiphase Ni21-Ti23Nb56 alloy membranes[J].Journal of Membrane Science,2011,384:136.
17 Hashi K, Ishikawa K, Matsuda T, et al. Microstructure and hydrogen permeability in Nb-Ti-Co multiphase alloys[J].Journal of Alloys and Compounds,2006,425:284.
18 Kamakoti P, Sholl D S. Towards first principles-based identification of ternary alloys for hydrogen purification membranes[J].Journal of Membrane Science,2006,279:94.
19 Shi F, Song X P. Effect of Hf/Ni ratio on microstructure and hydrogen permeation of Nb-Hf-Ni ternary alloys[J].Journal of Alloys and Compounds,2011,509:L134.
20 Liu F, Wang Z M, Huang H W, et al. Phase structure and hydrogen diffusion properties of Nb-Ti-Ni alloys[J].Journal of Central South University(Science and Technology),2012,43(9):82(in Chinese).
刘菲,王仲民,黄贺伟,等.Nb-Ti-Ni体系合金的结构及其氢渗透性能[J].中南大学学报自然科学版,2012,43(9):82.
21 Takano T, Ishikawa K, Matsuda T, et al. Hydrogen Permeation of eutectic Nb-Zr-Ni alloy membranes containing primary phases[J].Materials Transactions,2004,45:3360.
22 Ishikawa K, Takano T, Matsuda T, et al. High hydrogen permeability in the Nb-Zr-Ni eutectic alloy containing the primary body-centered-cubic(Nb, Zr) phase[J].Applied Physics Letters,2005,87:819061.
23 Shi F. Microstructure and hydrogen permeability of Nb40Hf30Ni30 ternary alloy[J].International Journal of Hydrogen Energy,2010,35:10556.
24 Shi F, Song X P. Effect of niobium on the microstructure, hydrogen embrittlement, and hydrogen permeability of NbxHf(1-x)/2Ni(1-x)/2 ternary alloys[J].International Journal of Hydrogen Energy,2010,35:10620.
25 Yan E H, Sun L X, Xu F, et al. Changes in microstructure, solidification path and hydrogen permeability of Nb-Hf-Co alloy by adjusting Hf/Co ratio[J].International Journal of Hydrogen Energy,2016,41:1391.
26 Li Y F. Feature of penetration of hydrogen in steel and the researches on the mechanism of the coating oxygen permeation resistance[D].Shanghai:East China University of Science and Technology,2012(in Chinese).
李勇峰.氢在钢中的渗透特性及镀层阻氧渗透机理的研究[D].上海:华东理工大学,2012.
27 Zhang Y, Ozaki T, Komaki M, et al. Hydrogen permeation of Pd-Ag alloy coated V-15Ni composite membrane: effects of overlayer composition[J].Journal of Membrane Science,2003,224:81.
28 Ishikawa K, Seki Y, Kita K, et al. Hydrogen permeation in rapidly quenched amorphous and crystallized Nb20Ti40Ni40 alloy ribbons[J].International Journal of Hydrogen Energy,2011,36:1784. |
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2018, Vol. 32 
