溶液中镓的提取与分离研究进展<sup>*</sup>

doi:10.11896/j.issn.1005-023X.2017.015.020

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Abstract Recovering gallium from intermediate material produced in iron and steel, non-ferrous metals, coal chemical industry and phosphorous chemical industry exists the problem that extracting gallium from solution containing variety of metal ions. The present status of studies on extraction and separation of gallium from the solution are reviewed in this work. The key factors influencing separating gallium from other metal ions in the solution by the solvent extraction, liquid membrane extraction, extraction leaching resin extraction process are analyzed and discussed. The new research trend for recovery gallium from solution versatile different metal ions contained is proposed. Solvent extraction, liquid membrane extraction and extraction leaching resin are able to effectively extract gallium from solution. Synergistic extraction, liquid membrane extraction and extraction leaching resin extraction are prominent and prospective in future, owing to their high performance of selectivity and extraction rate, short process, environmental friendliness and good application prospect.

Key words： separation solvent extraction recovery rare metal gallium

Published: 04 May 2018

CLC number:

TQ028.4

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	Articles by authors
	LIAO Yalong
	CAO Lei
	WANG Yiyang
	YE Chao

Cite this article:

LIAO Yalong,CAO Lei,WANG Yiyang, et al. Review on Extraction and Separation of Gallium from Solution[J]. Materials Reports, 2017, 31(15): 133-138.

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http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.015.020 OR http://www.mater-rep.com/EN/Y2017/V31/I15/133

1 Xu K, Deng T, Liu J T, et al. Study on the recovery of gallium from phosphorus flue dust by leaching with spent sulfuric acid solution and precipitation[J].Hydrometallurgy,2007,86:172.
2 Liu F P, Liu Z H, Li Y H, et al. Extraction of gallium and germa-nium from zinc refinery residues by pressure acid leaching[J].Hydrometallurgy, 2016,164:313.
3 Wu X L, Wu S K, Qin W Q, et al. Reductive leaching of gallium from zinc residue[J]. Hydrometallurgy, 2012,113,114:195.
4 Zhao J G, Xing M J, Liu H. Extraction mechanism of Ga³⁺ with mono(2-ethylhexyl) 2-ethylhexyl phosphonate (P507) from hydrochloric acid solution [J]. Chin J Appl Chem,1996,13(1):101(in Chinese).
赵经贵,邢美君,刘宏.2-乙基己基膦酸单(2-乙基己基)酯从盐酸溶液中萃取Ga(Ⅲ)的机理[J].应用化学,1996,13(1):101.
5 Zhang K F, Cao Z Y, Xiao L S, et al. Extraction of gallium from sulfuric acid solutions with extractant P507[J]. Mining Metall Eng,2014,34(6):90(in Chinese).
张魁芳,曹佐英,肖连生,等.P507从硫酸体系中萃取镓的研究[J].矿冶工程,2014,34(6):90.
6 Zhang K F, Liu Z Q. Extraction and separation of gallium ion with iron and zinc ions in sulfuric acid system with P507 [J]. Chin J Process Eng, 2014,14(3):427(in Chinese).
张魁芳,刘志强.用 P507从硫酸体系中萃取分离镓与铁锌离子[J].过程工程学报,2014,14(3):427.
7 Liu G H, Li X B, Sun S X. Study on the mechanism of extraction of gallium with HDEHP [J]. Chin J Rare Met,1997,21(6):475(in Chinese).
刘桂华,李小斌,孙思修. HDEHP萃取Ga(Ⅲ)机理的研究[J]. 稀有金属,1997,21(6):475.
8 Liu G H, Yang Y H, Sun S X, et al. The extraction kinetics of Ga(Ⅲ) with HDEHP [J]. Chin J Appl Chem,1996,13(6):31(in Chinese).
刘桂华,杨永会,孙思修,等. HDEHP萃取Ga(Ⅲ)的动力学[J].应用化学,1996,13(6):31.
9 Jayachandran J, Dhadke P. Solvent extraction separation of gallium(Ⅲ) with 2-ethylhexyl phosphonic acid mono 2-ethylhexyl ester PC-88A[J]. Hydrometallurgy,1998,50:117.
10 Sasaki Y, Matsuo N, Oshima T, et al. Selective extraction of In(Ⅲ), Ga(Ⅲ) and Zn(Ⅱ) using a novel extractant with phenylphosphinic acid[J]. Chin J Chem Eng,2016,24:232.
11 Li Y L, Peng Y X, Xu Y S. Extract gallium in acid solution by extraction and backextraction[J]. Sci Technol Eng,2014,14(27):173(in Chinese).
李宇亮,彭悦欣,徐永胜.萃取-反萃取以提取酸溶液中的镓[J].科学技术与工程, 2014,14(27): 173.
12 Feng Y L, Wang H J, Li H R. Recovery of gallium from phosphorus industry flue dust using process of curbing-leaching-extracting[J]. J Central South University:Science and Technology,2008,39(1):86(in Chinese).
冯雅丽,王宏杰,李浩然,等.采用熟化-浸出-萃取法从黄磷电炉电尘浆中提取镓[J].中南大学学报:自然科学版,2008,39(1):86.
13 Ahmed I M, El-Nadi Y A, El-Hefny N E. Extraction of gallium(Ⅲ) from hydrochloric acid by Cyanex 923 and Cyanex 925[J]. Hydrometallurgy, 2013,131-132:24.
14 Gupta B, Mudhar N, Begum I Z, et al. Extraction and recovery of Ga(Ⅲ) from waste material using Cyanex 923[J]. Hydrometallurgy,2007,87:18.
15 Wang X Y, Wang Y D, Jin W X. Extraction behavior and mechanism of gallium(Ⅲ) with sec-nonylphenoxy acetic acid from sulphate media[J]. J Jilin Normal University:Nat Sci Ed,2007(4):35(in Chinese).
王秀艳,王雨东,金文旭.在硫酸介质中仲壬基苯氧基乙酸萃取镓(Ⅲ)的机制研究[J].吉林师范大学学报:自然科学版,2007(4):35.
16 Zhang X Y, Yin G Y, Tang J M. Study on extraction behavior and extraction mechanism of gallium with CA-12[J]. Chin J Rare Met, 2002,26(1):65(in Chinese).
张秀英,尹国寅,汤俊明.新型萃取剂CA-12萃取镓(Ⅲ)的研究[J].稀有金属,2002,26(1):65.
17 Zhang X Y, Yin G Y, Hu Z G. Extraction and separation of gal-lium, indium and thallium with several carboxylic acids from chloride media[J]. Talanta, 2003,59:905.
18 Huang W X, Luo Z A, Yang F. Study of Ga recovery from granulation slag[J]. Rare Met Cemented Carbides,2003,31(1):8(in Chinese).
黄文孝,罗泽安,杨飞.从水淬渣中回收镓的试验研究[J].稀有金属与硬质合金,2003,31(1):8.
19 Zhao Z, Yang Y X, Xiao Y P, et al. Recovery of gallium from Bayer liquor: A review[J]. Hydrometallurgy,2012,125-126:115.
20 Kekesi T. Gallium extraction from synthetic Bayer liquors using Kelex 100-kerosene, the effect of loading and stripping conditions on selectivity [J]. Hydrometallurgy,2007,88:170.
21 Puvvada G V K. Liquid-liquid extraction of gallium from Bayer process liquor using Kelex 100 in the presence of surfactants[J]. Hydrometallurgy, 1999,52:9.
22 Nusen S, Chairuangsri T, Zhu Z, et al. Recovery of indium and gallium from synthetic leach solution of zinc refinery residues using sy-nergistic solvent extraction with LIX63 and Versatic10 acid[J]. Hydrometallurgy,2016,60:137.
23 Sasaki Y, Oshima T, Baba Y. Mutual separation of indium(Ⅲ), gallium(Ⅲ) and zinc(Ⅱ) with alkylated aminophosphonic acids with different basicities of amine moiety[J].Separation Purification Technol,2017,173:37.
24 Su L F, Lin J S, Li X L. Study on a new process for extraction of gallium and germanium[J]. China Resources Comprehensive Utilization, 2013,31(10):7(in Chinese).
苏立峰,林江顺,李相良.稀散金属镓锗提取新工艺研究[J].中国资源综合利用,2013,31(10):7.
25 Yu J F, Liu D F. Studies on interfacial characteristics and micellization for a new extraction system of gallium[J]. Chemical J Chinese Universities, 1994,15(7):1068(in Chinese).
於静芬,刘涤非.Ga³⁺的新萃取体系的界面特性和胶团化作用研究[J].高等学校化学学报,1994,15(7):1068.
26 Jiang Y P, Zhao L, Wang H B, et al. Experimental study on recovering gallium and germanium from gallium & germanium-leaching solution at high-pressure [J]. China Resources Comprehensive Utilization,2012,30(6):25(in Chinese).
蒋应平,赵磊,王海北,等.从高压浸出镓锗液中回收镓锗的试验研究[J].中国资源综合利用,2012,30(6):25.
27 Lin J S, Wang H B, Gao Y J, et al. Preparation and application of a novel extractant for gallium and germanium[J]. Nonferrous Met,2009,61(2):84(in Chinese).
林江顺,王海北,高颖剑,等.一种新镓锗萃取剂的研制与应用[J].有色金属,2009,61(2):84.
28 Shi T H, Wang X D, Wan Y H, et al. Study on synergistic extraction of Ga³⁺ from sulfuric acid medium with D₂EHPA and C_5-7 oximine acid (Ⅰ) [J]. Membrane Sci Technol,1999,19(3):25(in Chinese).
石太宏,王向德,万印华,等. D₂EHPA与C_5-7羟肟酸自硫酸介质中协同萃取Ga³⁺的液膜理论基础研究(Ⅰ) [J]. 膜科学与技术,1999,19(3):25.
29 Ma H H, Lei Y, et al. An extraction study of gallium, in-dium, and zinc with mixtures of sec-octylphenoxyacetic acid and primary amine N1923[J]. Separation Purification Technol,2011,80:351.
30 Fan S J, Jia Q, et al. Synergistic extraction study of in-dium from chloride medium by mixtures of sec-nonylphenoxy acetic acid and trialkyl amine[J].Separation Purification Technol,2010,75:76.
31 Dantas T N C, Neto M H D, Neto A A D, et al. New surfactant for gallium and aluminum extraction by microemulsion[J]. Ind Eng Chem Res,2005,44(17):6784.
32 De Castro Dantas T N, De Lucena Neto M H, et al. Gallium extraction by microemulsions[J]. Talanta,2002,56(6):1089.
33 Saidia M, Khalafb H. Using microemulsion for recovery of uranium from phosphoric acid of Annaba (Algeria) [J]. Hydrometallurgy,2004, 74(1-2):85.
34 Wang J S, Chiu K H. Metal extraction from solid matrices using a two-surfactant micro-emulsion in neat supercritical carbon dioxide[J]. Microchimica Acta, 2009,167(1-2):61.
35 Zhao X D, Lu Y M, Yang Y Z. Study on the extraction of gallium by micro-emulsions[J]. J Shandong University:Natural Science,2010,45(9):109(in Chinese).
赵西丹,卢艳敏,杨延钊.微乳液萃取镓的研究[J].山东大学学报(理学版),2010,45(9):109.
36 Kumbasar R A, Tutkun O. Separation and concentration of gallium from acidic leach solutions containing various metal ions by emulsion type of liquid membranes using TOPO as mobile carrier[J]. Hydrometallurgy,2004,75:111.
37 Liu J S, Zhou B X, Cai W M. Study on adsorption properties and mechanism of gallium by D2EHPA levextrel resin[J]. Ion Exchange Adsorption, 2002,18(3):267(in Chinese).
刘军深,周保学,蔡伟民.CL-P204萃淋树脂吸萃镓的性能和机理[J].离子交换与吸附,2002,18(3):267.
38 Liu J S, Zhou B X, Yang Z C, et al.Separation of In(Ⅲ), Ga(Ⅲ) and Zn(Ⅱ)by CL-P204 levetrel resin[J]. Chin Appl Chem,1999,16(3):76(in Chinese).
刘军深,周保学,杨子超,等.CL-P204萃淋树脂分离铟(Ⅲ)镓(Ⅲ)锌(Ⅱ)[J].应用化学,1999,16(3):76.
39 Liu J, Yan Y T, Shao H X, et al. Study on adsorption and separation of gallium with CL-TBP extraction resin[J].Chemistry,2001,64(2):119(in Chinese).
刘建,闫英桃,邵海欣,等.CL-TBP萃淋树脂吸附分离镓(Ga)研究[J].化学通报,2001,64(2):119.
40 Liu J, Yan Y T, Hu X L. Study on the performance and application of absorbing and separation of gallium with CL-TBP levextre resin[J]. Chin J Rare Met,2000,24(2):157(in Chinese) .
刘建,闫英桃,胡小玲.CL-TBP萃淋树脂吸附镓的性能及应用研究[J].稀有金属,2000,24(2):157.
41 Lin J J, Zhong Y J, Chen J R, et al. Adsorption of gallium with N503 levextrel resin [J]. Chin J Nonferrous Met,1996,6(1):40(in Chinese).
林建军,钟依均,陈建荣,等.N503萃淋树脂吸附镓的研究[J].中国有色金属学报,1996,6(1):40.
42 Liu J S, He Z G, Cai W M. Separation and recovery of In and Ga with CL-P204 resin [J]. Nonferrous Met,2003,55(supp):85(in Chinese).
刘军深,何争光,蔡伟民.萃淋树脂分步洗脱法分离回收铟和镓[J].有色金属,2003,55(supp):85.
43 Zhang K F, Cao Z Y, Xiao L S, et al. Extraction of gallium from high concentration sulfuric acid leaching solution of zinc replacing slag by HBL121[J].Chin J Nonferrous Met,2014,24(9):2400(in Chinese).
张魁芳,曹佐英,肖连生,等.采用HBL121从锌置换渣高浓度硫酸浸出液中萃取回收镓[J].中国有色金属学报,2014,24(9):2400.