含碳耐火材料酚醛树脂结合剂的研究现状与展望<sup>*</sup>

doi:10.11896/j.issn.1005-023X.2017.011.013

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Abstract Owing to high thermal conductivity for better thermal shock resistance and low wettability with slag to improve corrosion resistance, carbon containing refractories are largely and diversely produced for metallurgical processes. Phenolic resin has been widely used as binder of carbon containing refractories because of compatibility with graphite, high carbon yield, environmental friendliness, high adhesive strength. However, the pyrolytic carbon derived from phenolic resin shows amorphous structure, which is brittle and easy to oxidized at elevated temperature. Many studies focus on chemical modifications of phenolic resin. Aiming to improve the anti-oxidation or/and mechanical properties or to increase yield of phenolic-resin-derived carbon, transition metal compound, nanocarbon and semiconductive ceramic particles are frequently used as catalysts, to generate carbon nanotubes (CNTs) or carbon nanofibers (CNFs) with high degree of graphitization, as well as in-situ synthesis of SiC nanowires in phenolic-resin-derived carbon.

Key words： carbon containing refractories phenolic resin binder catalytic graphitization

Published: 04 May 2018

CLC number:

TM912.9

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	Articles by authors
	DING Donghai
	YANG Shaoyu
	XIAO Guoqing

Cite this article:

DING Donghai,YANG Shaoyu,XIAO Guoqing. Progress in Phenolic Resin Binder for Carbon Containing Refractories[J]. Materials Reports, 2017, 31(11): 95-100.

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http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.011.013 OR http://www.mater-rep.com/EN/Y2017/V31/I11/95

1 Ewais E M M. Carbon based refractories[J]. J Ceram Soc Jpn,2004,112(10):517.
2 Mahato S, Pratihar S K, Behera S K. Fabrication and properties of MgO-C refractories improved with expanded graphite[J]. Ceram Int,2014,40:16535.
3 Soumya Mukherjee S P, Siddhartha M. A comprehensive review of recent advances in magnesia carbon refractories[J]. Interceram,2014,63(3):90.
4 Krivokorytov C V, Gur′ev A G, Polyak B I. High-carbon binders in refractories and corrosion-resistant ceramic technology[J]. Glass Ceram,1998,55(5-6):144.
5 Jansen H. Bonding of MgO-C bricks by catalytically activated resin [J]. Millennium Steel,2007:95.
6 Bitencourt C S, Luz A P, Pagliosa C, et al. Role of catalytic agents and processing parameters in the graphitization process of a carbon-based refractory binder[J]. Ceram Int,2015,41:13320.
7 Pilato L. Phenolic resins: 100 Years and still going strong[J]. Reactive Funct Polym,2013,73:270.
8 Emmel M. Development of active and reactive carbon bonded filter materials for steel melt filtration[D]. Freiberg: Technische Universität Bergakademie Freiberg,2014.
9 Artmann A, Bianchi O, Soares M R, et al. Rheokinetic investigations on the thermal cure of phenol-formaldehyde novolac resins[J]. Mater Sci Eng C,2010,30(8):1245.
10 Inagaki M, Kang F. Materials science and engineering of carbon fundamentals[M]. Amsterdam: Elsevier,2014:34.
11 Liang F, Li N, Li X K, et al. Effect of the addition of carbon black and carbon nanotubes on the structure and oxidation resistance of pyrolysed phenolic carbons[J]. New Carbon Mater,2012,27(4):283.
12 Wei G P, Zhu B Q, Li X C, et al. Microstructure and mechanical properties of low-carbon MgO-C refractories bonded by an Fe nanosheet-modified phenol resin[J]. Ceram Int,2015,41:1553.
13 Bartha P, Jansen H, Daldrup H G. Carbonaceous refractory shaped body with improved oxidation behavior and batch composition and method for producing the same: US, 6846766[P].2005-01-25.
14 Stamatin I, Morozan A, Dumitru A, et al. The synthesis of multi-walled carbon nanotubes (MWNTs) by catalytic pyrolysis of the phenol-formaldehyde resins[J]. Physica E,2007,37(1-2):44.
15 Zhu B Q, Wei G P, Li X C, et al. Preparation and growth mechanism of carbon nanotubes via catalytic pyrolysis of phenol resin[J]. Mater Res Innovat,2014,18(4):267.
16 Wang J K, Deng X G, Zhang H J, et al. Large-scale preparation of carbon nanotubes via catalytic pyrolysis of phenolic resin at low temperature[J]. Interceram,2015,64(3):86.
17 Hu Q H, Wang X T, Wang Z F. Preparation of graphitic carbon nanofibres by in situ catalytic graphitisation of phenolic resins[J]. Ceram Int,2013,39:8487.
18 Luo M, Li Y W, Sang S B, et al. In situ formation of carbon nanotubes and ceramic whiskers in Al₂O₃-C refractories with addition of Ni-catalyzed phenolic resin[J]. Mater Sci Eng A,2012,558:533.
19 Fang W, Zhao L, Liang F, et al. Microstructure of a carbon produced from a lignin-modified phenol-formaldehyde resin using a nickel nitrate catalyst[J]. New Carbon Mater,2015,30(4):327.
20 Zhao M, Song H H. Catalytic graphitization of phenolic resin[J]. J Mater Sci Technol,2011, 27(3):266.
21 Zhu B Q, Wei G P, Li X C, et al. Effect of carbonizaiton temperature on microstrcuture and oxidaiton resistance of carbon derived from doping modified phenol resin[J]. J Chin Ceram Soc,2014, 42(6):773(in Chinese).
朱伯铨,魏国平,李享成,等. 炭化温度对掺杂改性树脂炭结构及其抗氧化性能的影响[J]. 硅酸盐学报,2014,42(6):773.
22 Huang G R, Liu H B, Yang L, et al. Pyrolysis behavior of graphene/phenolic resin composites[J]. New Carbon Mater,2015,30(5):412(in Chinese).
黄桂荣,刘洪波,杨丽,等. 石墨烯/酚醛树脂纳米复合材料的热解行为[J]. 新型碳材料,2015, 30(5):412.
23 Wu X X, Li H X, Liu G Q, et al. Effect of KCl on growth of carbon fibres during carbonization of phenolic resin[J]. Refractories,2015,49(1):1(in Chinese).
吴小贤,李红霞,刘国齐,等. KCl对酚醛树脂炭化生长碳纤维的影响[J]. 耐火材料,2015,49(1):1.
24 Aneziris C G, Hubalkova J, Barabas R. Microstructure evaluation of MgO-C refractories with TiO₂- and Al-additions[J]. J Eur Ceram Soc,2007,27:73.
25 Wang J G, Guo Q G, Liu L, et al. Study on the microstructural evolution of high temperature adhesives for graphite bonding [J]. Carbon,2002,40(13):2447.
26 Zhang S, Yamaguch A. Effects of B₄C on the crystallization and oxidation resistance of carbon from resin[J]. J Ceram Soc Jpn,1994,102:830.
27 Wang X, Zhu B Q, Li X C, et al. Effect of metal co-doping on microstructure and oxidation resistance of carbon derived from phenol resin[J]. J Chin Ceram Soc,2015,43(3):316(in Chinese).
汪贤,朱伯铨,李享成,等. 金属共掺杂对树脂炭结构及抗氧化性能的影响[J]. 硅酸盐学报,2015,43(3):316.
28 Stein V, Aneziris C G, Gueguen E. New approach for the application of functional ceramic material in carbon bonded doloma refractories to reduce emissions[J]. Adv Eng Mater,2011,13(12):1135.
29 Stein V, Aneziris C G. A prospective way to reduce emissions in se-condary steel making metallurgy by application of functionalized doloma carbon refractories[J]. Int J Appl Ceram Technol,2012,9(3):615.
30 Stein V, Aneziris C G. Low-carbon carbon-bonded alumina refractories for functional components in steel technology[J]. J Ceram Sci Technol,2014,5(2):115.
31 Zhu T B, Li Y W, Sang S B, et al. Formation of nanocarbon structures in MgO-C refractories matrix: Influence of Al and Si additives[J]. Ceram Int,2016,42:18833.
32 Bitencourt C S, Luz A P, Pagliosab C, et al. Phase and microstructural evolution based on Al, Si and TiO₂ reactions with a MgO-C resin-bonded refractory[J]. Ceram Int,2016,42(15):16480.
33 Wang F C, Zhao L, Fang W, et al. Synthesis and characterization of silicon carbide nanowires from lignin-phenolic resin and silicon powder with an in-situ formed molten salt as catalyst[J]. New Carbon Mater,2015,30(3):222.
34 Wang F C, Zhao L, Fang W, et al. Preparation of organic/inorganic composite phenolic resin and application in Al₂O₃-C refractories[J]. Int J Appl Ceram Technol,2016,13(1):133.
35 Xu P J, Jiang X L. High carbon yield thermoset resin based on phenolic resin, hyperbranched polyborate, and paraformaldehyde[J]. Polym Adv Technol,2010,22(12):2592.
36 Li S, Han Y, Chen F H, et al. The effect of structure on thermal stability and anti-oxidation mechanism of silicone modified phenolic resin[J]. Polym Degradat Stability,2016,124:68.
37 Semchenko G D, Povshuk V V, Brazhnik D A, et al. Creation of a combined liquid phenolfomaldehyde antioxidant-modifier for improving periclase-carbon refractory life[J]. Refract Ind Ceram,2016,56(6):1573.