三维石墨烯复合材料的制备及其在超级电容器领域的研究现状

doi:10.11896/j.issn.1005-023X.2017.01.004

Abstract
Figure/Table
References
Related Citation (15)

Download:

Full Text ( PDF ) (1539KB)
Export: BibTeX | EndNote (RIS)

Abstract The porous structure of three-dimensional graphene not only improves the contact area with the electrolyte but also provides a fast electron transport channels for the active materials anchored on it, therefore the electrochemical performance of the supercapacitors can be effectively enhanced, which makes them to be the promising materials for supercapacitors. This review summarizes the preparation methods of the three-dimensional graphene with a porous structure, large specific surface area, good electrical conductivity and excellent mechanical properties. In addition, the application status of the three-dimensional graphene composites in supercapacitors is described.

Key words： three-dimensional graphene preparation methods composites supercapacitor

Published: 02 May 2018

CLC number:

TM53

	Service
	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	GAO Xin
	YUE Hongyan
	GUO Erjun
	YAO Longhui
	LIN Xuanyu
	WANG Bao

Cite this article:

GAO Xin,YUE Hongyan,GUO Erjun, et al. Preparation and Applications of Three-dimensional Graphene Composites in Supercapacitors[J]. Materials Reports, 2017, 31(1): 25-29.

URL:

http://www.mater-rep.com/EN/10.11896/j.issn.1005-023X.2017.01.004 OR http://www.mater-rep.com/EN/Y2017/V31/I1/25

1 Balandin A A, Ghosh S, Bao W Z, et al. Superior thermal conductivity of single-layer graphene[J]. Nano Lett,2008,8(3):902.
2 Lee C, Wei X, Kysar J W, et al. Measurement of the elastic properties and intrinsic strength of monolayer graphene[J]. Science,2008,321(5887):385.
3 Novoselov K S, Geim A K, Morozov S V, et al. Electric field effect in atomically thin carbon films[J]. Science,2004,306(5696):666.
4 Li D, Müller M B, Gilje S, et al. Processable aqueous dispersions of graphene nanosheets[J]. Nat Nanotechnol,2008,3(2):101.
5 Reina A, Jia X, Ho J, et al. Large area, few-layer graphene films on arbitrary substrates by chemical vapor deposition[J]. Nano Lett,2009,9(1):30.
6 Chen Z, Ren W, Gao L, et al. Three-dimensional flexible and conductive interconnected graphene networks grown by chemical vapour deposition[J]. Nat Mater,2011,10(6):424.
7 Ji H, Zhang L, Pettes M T, et al. Ultrathin graphite foam: A three-dimensional conductive network for battery electrodes[J]. Nano Lett,2012,12(5):2446.
8 Ke Q, Wang J. Graphene-based materials for supercapacitor electrodes-A review[J]. J Materiomics,2016,2(1):37.
9 Ma Y, Chen Y. Three-dimensional graphene networks: Synthesis, properties and applications[J]. National Sci Rev,2015,2(1):40.
10 Zhou Guojun, Ye Zhikai, Shi Weiwei, et al. Applications of three dimensional graphene and its composite materials[J]. Prog Chem,2014,26(6):950(in Chinese).
周国珺, 叶志凯, 石微微, 等. 三维(3D)石墨烯及其复合材料的应用[J]. 化学进展,2014, 26(6):950.
11 Yue H Y, Huang S, Chang J, et al. ZnO nanowire arrays on 3D hierachical graphene foam: Biomarker detection of Parkinson′s di-sease[J]. ACS Nano,2014,8(2):1639.
12 Zhou M, Lin T, Huang F, et al. Highly conductive porous graphene/ceramic composites for heat transfer and thermal energy sto-rage[J]. Adv Funct Mater,2013,23(18):2263.
13 Mecklenburg M, Schuchardt A, Mishra Y K, et al. Aerographite: Ultra lightweight, flexible nanowall, carbon microtube material with outstanding mechanical performance[J]. Adv Mater,2012,24(26):3486.
14 Chen J, Sheng K, Luo P, et al. Graphene hydrogels deposited in nickel foams for high-rate electrochemical capacitors[J]. Adv Mater,2012,24(33):4569.
15 Choi B G, Yang M H, Hong W H, et al. 3D macroporous graphene frameworks for supercapacitors with high energy and power densities[J]. ACS Nano,2012,6(5):4020.
16 Meng Y, Wang K, Zhang Y, et al. Hierarchical porous graphene/polyaniline composite film with superior rate performance for flexible supercapacitors[J]. Adv Mater,2013,25(48):6985.
17 Xia X H, Tu J P, Mai Y J, et al. Graphene sheet/porous NiO hybrid film for supercapacitor applications[J]. Chemistry-A Eur J,2011,17(39):10898.
18 Zhang R, Cao Y, Li P, et al. Three-dimensional porous graphene sponges assembled with the combination of surfactant and freeze-drying[J]. Nano Res,2014,7(10):1477.
19 Sha J, Gao C, Lee S K, et al. Preparation of three-dimensional graphene foams using powder metallurgy templates[J]. ACS Nano,2016,10(1):1411.
20 Xu Y, Sheng K, Li C, et al. Self-assembled graphene hydrogel via a one-step hydrothermal process[J]. ACS Nano,2010,4(7):4324.
21 Sheng K, Sun Y, Li C, et al. Ultrahigh-rate supercapacitors based on eletrochemically reduced graphene oxide for ac line-filtering[J]. Sci Rep,2012,2:247.
22 Bai H, Li C, Wang X, et al. A pH-sensitive graphene oxide compo-site hydrogel[J]. Chem Commun,2010,46(14):2376.
23 El-Kady M F, Strong V, Dubin S, et al. Laser scribing of high-performance and flexible graphene-based electrochemical capacitors[J]. Science,2012,335(6074):1326.
24 Niu Z, Chen J, Hng H H, et al. A leavening strategy to prepare reduced graphene oxide foams[J]. Adv Mater,2012,24(30):4144.
25 Sun H, Xu Z, Gao C. Multifunctional, ultra-flyweight, synergistically assembled carbon aerogels[J]. Adv Mater,2013,25(18):2554.
26 Dong X, Wang X, Wang J, et al. Synthesis of a MnO₂-graphene foam hybrid with controlled MnO₂ particle shape and its use as a supercapacitor electrode[J]. Carbon,2012,50(13):4865.
27 Peng L, Peng X, Liu B, et al. Ultrathin two-dimensional MnO₂/graphene hybrid nanostructures for high-performance, flexible planar supercapacitors[J]. Nano Lett,2013,13(5):2151.
28 He Y M, Chen W J, Li X D, et al. Freestanding three-dimensional graphene MnO₂ composite networks as ultralight and flexible supercapacitor electrodes[J]. ACS Nano,2013,7(1):174.
29 El-Kady M F, Ihns M, Li M, et al. Engineering three-dimensional hybrid supercapacitors and microsupercapacitors for high-perfor-mance integrated energy storage[J]. PNAS,2015,112(14):4233.
30 Cao X H, Yin Z Y, Zhang H. Three-dimensional graphene mate-rials: Preparation, structures and application in supercapacitors[J]. Energy Environ Sci,2014,7:1850.
31 Wang C, Xu J, Yuen M F, et al. Hierarchical composite electrodes of nickel oxidenanoflake 3D graphene for high-performance pseudocapacitors[J]. Adv Funct Mater,2014,24(40):6372.
32 Jing M, Wang C, Hou H, et al. Ultrafine nickel oxide quantum dots enbedded with few-layer exfoliative graphene for an asymmetric supercapacitor: Enhanced capacitances by alternating voltage[J]. J Power Sources,2015,298:241.
33 Dong C X, Xu H, Wang X W, et al. 3D graphene cobalt oxide electrode for high-performance supercapacitor and enzymeless glucose detection[J]. ACS Nano,2012,6(4):3206.
34 Zhou W, Cao X, Zeng Z, et al. One-step synthesis of Ni₃S₂ nanorod @ Ni(OH)₂ nanosheet core-shell nanostructures on a three-dimensional graphene network for high-performance supercapacitors[J]. Energy Environ Sci,2013,6(7):2216.
35 Shen L, Wang J, Xu G, et al. NiCo₂S₄ nanosheets grown on nitrogen-doped carbon foams as an advanced electrode for supercapacitors[J]. Adv Energy Mater,2015,5(3):1400977.
36 Wu Q, Xu Y X, Yao Z Y, et al. Supercapacitors based on flexible graphene/polyaniline nanofiber composite films[J]. ACS Nano,2010,4(4):1963.
37 Yu P, Zhao X, Huang Z, et al. Free-standing three-dimensional graphene and polyaniline nanowire arrays hybrid foams for high-performance flexible and lightweight supercapacitors[J]. J Mater Chem A,2014,2(35):14413.
38 Xu J J, Wang K, Zu S Z, et al. Hierarchical nanocomposites of polyaniline nanowire arrays on graphene oxide sheets with synergistic effect for energy storage[J]. ACS Nano,2010,4(9):5019.
39 Mahmoud M, El-Kady M F, Hao W, et al. High-performance supercapacitors using graphene/polyaniline composites deposited on kitchen sponge[J]. Nanotechnology,2015,26(7):075702.
40 Iessa K H S, Zhang Y, Zhang G, et al. Conductive porous sponge-like ionic liquid-graphene assembly decorated with nanosized polyaniline as active electrode material for supercapacitor[J]. J Power Sources,2016,302:92.
41 Wang S, Ma L, Gan M, et al. Free-standing 3D graphene/polyaniline composite film electrodes for high-performance supercapacitors[J]. J Power Sources,2015,299:347.
42 Zhang J, Wang J, Yang J, et al. Three-dimensional macroporous graphene foam filled with mesoporous polyaniline network for high areal capacitance[J]. ACS Sustainable Chem Eng,2014,2(10):2291.
43 Cao J, Wang Y, Chen J, et al. Three-dimensional graphene oxide/polypyrrole composite electrodes fabricated by one-step electrodeposition for high performance supercapacitors[J]. J Mater Chem A,2015,3(27):14445.