| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
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| Research Progress of Porous Carbon Matrix Composites Used as Anodes of Alkali Metal Ion Batteries |
| MAO Xiaoxuan1, FENG Liu2,*, WU Liqing1, XIN Wuhong2, NIU Jinye2
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1 School of Materials Science and Engineering, Shandong University of Technology, Zibo 255000, Shandong, China
2 Analysis and Testing Center, Shandong University of Technology, Zibo 255000, Shandong, China |
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Abstract As one of the most promising energy storage devices, alkali metal ion batteries (Li+, Na+ and K+ as main ions) characterized by high power density and long service life, can realize large-scale, continuous storage and release of electric energy. However, the capacity of large-scale commercial graphite in service has approached the theoretical value, thus restricting the development of batteries. Therefore, it is particularly important to develop anode materials with high capacity, good stability, long cycle life, and excellent rate performance. Porous carbon materials, with abundant pore structure, large specific surface area and excellent electrical conductivity, can be used as the anode of alkali metal ion batte-ries to improve the conductivity and electrochemical stability of batteries, as long as the low capacity problem is solved. Accordingly, the modification strategies have been studied extensively, and a series of significant breakthroughs have been achieved. In this paper, the research progress on the application of porous carbon composite materials in lithium-ion batteries, sodium-ion batteries and potassium-ion batteries anode is reviewed. The synthesis methods of porous carbon materials are summarized at first, and then three modification strategies (doping heteroatom, compositing with metal compounds, and co-compositing/doping multi-materials) widely used in recent years are reviewed. Furthermore, the prospects of porous carbon on alkali metal ion batteries are prospected.
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Published:
Online: 2023-09-06
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| Fund:National Natural Science Foundation of China (22002074) and Shandong Provincial Natural Science Foundation Youth Found Project(ZR2020QE145). |
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2023, Vol. 37 
