木质素熔融沉积式3D打印的分子结构-流变学响应关系研究进展

doi:10.11896/cldb.22100182

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Abstract The development of high-value processing and utilization technology for lignin, the most abundant renewable aromatic biomass in nature, is an important way to facilitate the industrial upgrade of forest chemicals and materials. In recent years, 3D printing of lignin has flourished to construct advanced lignin-based materials. The use of 3D printing technologies enables to print lignin into composite materials with desired functional properties and the macro- and microstructures of 3D printed lignin composites can be flexible tuned to meet the requirements of energy, drug delivery, and personalized medicine. However, the unclear structure-rheological relationship caused by the diverse chemical structure, high polydispersity in molecular weight, and rigid structure of lignin greatly limits its performance and applications. Based on the development of fused deposition modeling 3D printing for lignin in last decades, this paper summarizes the structure-melt rheology relationship of lignin and its compo-sites. The lignin structure and the fused deposition modeling technology are firstly discussed and then the effects of different lignin structures and lignin/polymer blends on their melt rheological behavior and printability are vertically reviewed. Finally, the challenges and future directions of lignin fused deposition modeling 3D printing is also highlighted to better understand the structure-melt rheology relationship and to promote the high-value utilization of lignin.

Key words： lignin fused deposition modeling structure melt rheology structure-rheology relationship

Published: Online: 2024-06-25

CLC number:

O636.2

Fund:National Natural Science Foundation of China (32201500), Natural Science Foundation of Jiangsu Province (BK20220431), Natural Science Foundation of the Jiangsu Higher Education Institutions of China (21KJB220001), Forestry and Grassland Administration Key Laboratory of Plant Fiber Functional Materials(2022KFJJ05).

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	Articles by authors
	JIANG Bo
	JIAO Huan
	GUO Xinyu
	JIN Yongcan

Cite this article:

JIANG Bo,JIAO Huan,GUO Xinyu, et al. Research Progress on Lignin Structure-Melt Rheology Relationship in Fused Deposition Modeling[J]. Materials Reports, 2024, 38(11): 22100182-8.

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http://www.mater-rep.com/EN/10.11896/cldb.22100182 OR http://www.mater-rep.com/EN/Y2024/V38/I11/22100182

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