塑晶材料及其压卡效应研究发展与展望

doi:10.11896/cldb.22080087

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Abstract With the rapid development of economy and the increasing warming of global climate, the impact of refrigeration technology on modern society is more and more in-depth. The use of perfluorocarbons (CFCs) and hydrochlorofluorocarbons (HCFCs) freon refrigerants is at primary position in traditional gas compression refrigeration, however, will aggravate the greenhouse effect. To achieve global carbon neutralization, seeking high efficiency and environmentally friendly refrigeration schemes has become the key research direction for scientists, while the solid-state phase change technology based on field induction provides a promising scheme. Among them, the barocaloric eects have attracted much attention. In recent years, scientists have found the colossal barocaloric effects in a series of materials named plastic crystal, in which the entropy change is one order of magnitude higher than that of the traditional solid-state phase change refrigeration materials. Since then, the research on the barocaloric effects of plastic crystal materials has gradually increased in the scientific research community, and new plastic crystal materials with excellent performance have been continuously explored as the working medium of barocaloric effects refrigeration technology. This has greatly promoted the development of barocaloric effects refrigeration technology and provided more possibilities for realizing green and environmentally friendly high-efficiency refrigeration technology in the future. This paper will briefly explain the physical mechanism of the barocaloric effects in the plastic crystal, compare the comprehensive performance of several typical plastic crystal materials such as C₅H₁₂O₂ (NPG), (NH₂)C(CH₂OH)₃ (TRIS) and carborane, etc. and furthermore, and prospect the application of plastic crystal barocaloric effects in new solid-state refrigeration technology.

Key words： solid-state phase transition colossal barocaloric effects barocaloric refrigeration technology plastic crystals

Published: 10 March 2024 Online: 2024-03-18

CLC number:	TB64
	O59

Fund:National Natural Science Foundation of China (11864031)and Program for Young Talents of Science and Techno-logy in Universities of Inner Mongolia Autonomous Region (NJYT-18-B15).

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	FAN Xiaoyan
	ZHAO Xueting
	OU Zhiqiang

Cite this article:

FAN Xiaoyan,ZHAO Xueting,OU Zhiqiang. Development and Prospect of Research on Plastic Crystals and Its Barocaloric Effects[J]. Materials Reports, 2024, 38(5): 22080087-8.

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http://www.mater-rep.com/EN/10.11896/cldb.22080087 OR http://www.mater-rep.com/EN/Y2024/V38/I5/22080087

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