导电炭黑和热处理对Al-Bi复合材料产氢性能的影响

doi:10.11896/cldb.22050247

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Abstract Al-Bi-CB composites were designed by mechanical ball milling and heat treatment, the influence of conductive carbon black and heat teatment on hydrogen generation performance of Al-Bi-CB composites was studied. The morphology and structures of the composites were investigated by sanning electron microscope (SEM) and X-ray diffraction (XRD). The experiment results indicated that the composites acquired the best hydrogen production performance when the content of conductive carbon black was 5%. At the reaction temperature of 30 ℃, 1 g Al-3%Bi-5%CB composites for 5 min resulted in a hydrogen productin amount of 865 mL and the maximum hydrogen production rate was 107.15 mL·s^-1. The main reasons for increased the hydrogen production and hydrogen production rate of Al-Bi composites by conductive carbon black are refined the powder particles, improved the electrical conductivity of Al-Bi composites and quickly exfoliated from the surface of the composites when in contact with water. After heat treatment of ball milled powder, the maximum hydrogen production of Al-3%Bi-1%CB increased from 220 mL·g^-1 to 840 mL·g^-1 in 30 min. After heat treatment, Bi which embedded in Al remelted, recrystallized and form active sites on Al surface are the main reasons for improving hydrogen production performance of the composites.

Key words： Al-Bi composite conductive carbon black atmosphere heat treatment hydrogen production performance hydrogen production mechanism

Published: 25 October 2023 Online: 2023-10-19

CLC number:

TK91

Fund:National Natural Science Foundation of China (51771071).

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	CHEN Zhuo
	XIE Zhixiong
	XIAO Shuguang
	CHEN Qi
	DONG Shijie

Cite this article:

CHEN Zhuo,XIE Zhixiong,XIAO Shuguang, et al. Effect of Conductive Carbon Black and Heat Treatment on Hydrogen Production Performance of Al-Bi Composites[J]. Materials Reports, 2023, 37(20): 22050247-8.

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http://www.mater-rep.com/EN/10.11896/cldb.22050247 OR http://www.mater-rep.com/EN/Y2023/V37/I20/22050247

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