线型酚醛树脂结构改性的研究进展

doi:10.11896/cldb.22050233

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Abstract Phenolic resin has excellent mechanical properties and high temperature resistance, and is widely used in aerospace, architecture and other fields as the matrix resin of high-performance carbon/carbon composites or carbon/phenolic ablation resistant materials. The traditional phenolic resin releases volatiles during curing process, and its cross-linking structure after curing is deficient. For example, the tightly stacked rigid aromatic rings cause its high brittleness, the easily oxidized phenolic hydroxyl groups and methylene groups reduce its heat resistance and carbon residue rate. The multi-level structure design and modification of traditional phenolic resin is the key to satisfy its application in the field of new composite molding process and high-performance thermal protection. For example, the introduction of additive functional groups like propargyl groups and allyl groups into the novolac resin can achieve additive curing by thermal polymerization process. Through hydroxyl etherification reaction, epoxidation reaction or the introduction of molybdenum, boron, silicone and other components into the resin matrix, the molecular structure of resin can be regulated through chemical bonding and physical entanglement, then the structural design modification of phenolic resin can be achieved. This type of new phenolic resin essentially avoids the escape of small molecules during the curing process, and is easier to prepare high-quality composites. In summary, this paper focuses on several typical structural modified novolac resins and their research progress in the field of ablation protection.

Key words： phenolic resin structural modification addition curing thermostability composite material

Published: 10 December 2023 Online: 2023-12-08

CLC number:

TQ323.1

Fund:Key Research and Development Plan of Shaanxi Province(2021GXLH-Z-020), Joint Fund of National Natural Science Foundation of China and Chinese Academy of Physics(U193010027) and the National Natural Science Foundation of China(51873171).

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	Articles by authors
	CHEN Shuang
	LEI Zixuan
	XU Li
	LI Jiaxuan
	CHEN Dongliang
	QIANG Junfeng
	LIU Yuhong

Cite this article:

CHEN Shuang,LEI Zixuan,XU Li, et al. Research Progress on Structural Modification of Novolac Resin[J]. Materials Reports, 2023, 37(23): 22050233-10.

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http://www.mater-rep.com/EN/10.11896/cldb.22050233 OR http://www.mater-rep.com/EN/Y2023/V37/I23/22050233

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