非共价键化学修饰碳纳米管的分散及其机理

doi:10.11896/cldb.22040300

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Abstract Carbon nanotubes (CNTs) are one of the most representative nanomaterials with excellent performance. Their unique structure combined with their excellent mechanical, electronic and optical properties make them ideal nanomaterials, which are widely used in various fields. However, CNTs have huge surface area and aspect ratio, extremely strong van der Waals forces and π-π accumulation between tubes, which usually exist in the form of parallel tube bundles in the natural state, which greatly hinder the further research and application of CNTs. In recent years, based on the principle of non-covalent chemical modification, people have continuously studied the synthesis of appropriate dispersants for CNTs, explored the mechanism of CNTs dispersion, and attempted to solve the problem of CNTs agglomeration. However, in the field of actual industrial application, the existing scientific research results cannot meet the industrial demand for the dispersion of CNTs. This paper mainly summarized the research progress of polymeric non-covalent dispersants dispersed CNTs, introduced the principle of non-covalent dispersant dispersed CNTs, classified and analyzed the characteristics of dispersion of CNTs in solution and polymer melt. Finally, the research direction of non-covalent dispersants for dispersing CNTs in solution and the design idea of non-covalent dispersants for dispersing CNTs in polymer melt were prospected to expand the application of CNTs in the industrial field.

Key words： carbon nanotubes dispersion mechanism non-covalent chemical modification polymeric dispersant

Published: 10 September 2023 Online: 2023-09-05

CLC number:

TQ314

Fund:Launched Project for New Young Teachers in Shanghai Jiao Tong University (18X100040063).

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	CHEN Dian
	LYU Shiming
	WANG Yuling

Cite this article:

CHEN Dian,LYU Shiming,WANG Yuling. Dispersion and Mechanism of Non-covalent Chemically Modified Carbon Nanotubes[J]. Materials Reports, 2023, 37(17): 22040300-18.

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http://www.mater-rep.com/EN/10.11896/cldb.22040300 OR http://www.mater-rep.com/EN/Y2023/V37/I17/22040300

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