铅炭电池负极添加剂研究进展

doi:10.11896/cldb.22030203

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Abstract High performance lead-carbon batteries are developed from lead-acid batteries; carbon materials, which are porous with a high specific surface area, are selected as negative additives. Carbon materials provide reaction surfaces for lead sulfate (PbSO₄) produced during battery discharge, which can inhibit sulfation and prolong the cycle life of the batteries. However, the low hydrogen evolution potential of carbon results in an excessive hydrogen evolution rate. Recently, the focus of research on anode additives of lead-carbon batteries was moved from carbon materials with different structures and hydrogen evolution inhibitors to various carbon composite materials (e.g., C/Pb, C/conductive polymer, and C/H evolution inhibitor). The primary reason is that the addition of carbon composite materials can effectively solve the problems of rapid hydrogen evolution caused by carbon materials and poor compatibility between lead and additives, while prolonging the cycle life of batteries. This paper mainly reviews the research progress of negative electrode additives for lead-carbon batteries in recent years and analyses carbon additives, hydrogen evolution inhibitors, and composite additives. Further, the problems that may be encountered in the future are detailed and possible research directions are outlined.

Key words： lead-carbon battery sulfation carbon materials hydrogen evolution inhibitors composites cycle life

Published: 25 November 2023 Online: 2023-11-21

CLC number:

TM912

Fund:University Natural Science Research Project of Anhui Provincial Department of Education (KJ2018ZD049).

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	Articles by authors
	XIE Fazhi
	SONG Hengshuai
	ZHANG Daode
	YANG Shaohua
	ZHANG Meng
	FANG Liang
	SHAO Yonggang

Cite this article:

XIE Fazhi,SONG Hengshuai,ZHANG Daode, et al. Research Progress of Additives for Lead-Carbon Battery Anodes[J]. Materials Reports, 2023, 37(22): 22030203-8.

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http://www.mater-rep.com/EN/10.11896/cldb.22030203 OR http://www.mater-rep.com/EN/Y2023/V37/I22/22030203

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