| INORGANIC MATERIALS AND CERAMIC MATRIX COMPOSITES |
|
|
|
|
|
| Research Progress on Comprehensive Utilization of Phosphogypsum for Materials: a Review |
| ZHANG Jun1,2, XIE Weimin1,2, DONG Xiongbo3,4,5, YANG Huaming1,2,3,4,5,*
|
1 School of Minerals Processing and Bioengineering, Central South University, Changsha 410083,China
2 Key Laboratory for Mineral Materials and Application of Hunan Province, Central South University, Changsha 410083, China
3 Engineering Research Center of Nano-Geomaterials of Ministry of Education, China University of Geosciences, Wuhan 430074, China
4 Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China
5 Key Laboratory of Functional Geomaterials in China Nonmetallic Minerals Industry, China University of Geosciences, Wuhan 430074, China |
|
|
|
|
Abstract Phosphogypsum is a solid-waste byproduct of the wet-acid process used for producing phosphoric acid. Its main component is calcium sulfate dihydrate, characterized by its high yield and complexity. At present, with stocks of phosphogypsum in China reaching 600 million tons, the massive piling up has led to waste of land resources, deterioration of river water quality, air pollution, and other ecological and environmental problems. However, the comprehensive utilization of phosphogypsum is quite low in China, where it is primarily used to produce low-value-added construction materials. Thus, the research and development of new phosphogypsum-based technologies and products must be accelerated. This paper summarizes the progress of phosphogypsum research in the fields of construction, rare earth extraction, agriculture, chemical industry, and biomedical industry. This was done by analyzing the status quo of studies on comprehensive phosphogypsum utilization and its industrial applications,highlighting issues in the current stage of studies, revealing insights into future developments, and providing a reference for theoretical and technological research on the bulk and high-value utilization of phosphogypsum and its industrial applications.
|
|
Published: 25 August 2023
Online: 2023-08-14
|
|
|
| Fund:National Key R & D Program of China (2017YFB0310903), and the Fundamental Research Funds for the Central Universities of Central South University (2020zzts728, 2022zzts565). |
|
|
1 Rashad A M. Journal of Cleaner Production, 2017, 166, 732.
2 Zhang L Z, Zhang Y X, Zhang X F, et al. Conservation and Utilization of Mineral, 2019, 39(4), 14 (in Chinese).
张利珍,张永兴,张秀峰,等. 矿产保护与利用, 2019, 39(4), 14.
3 Wang J. Journal of Cleaner Production, 2020, 276, 123337.
4 Denisov K, Upolovnikov D, Poletaev I, et al. Earth and Environmental Science, 2021, 723(2), 22042.
5 Sun T Q, Qin X J, Min X M, et al. Guangzhou Chemical Industry, 2021, 49(10), 20 (in Chinese).
孙天琦,秦绪江,闵惜茗,等. 广州化工,2021, 49(10), 20.
6 Zhang H Q, Xu X, Hu C J, et al. China Mining Magazine, 2021, 30(4), 50 (in Chinese).
张汉泉,许鑫,胡超杰,等. 中国矿业, 2021, 30(4), 50.
7 Ye X D. Phosphate & Compound Fertilizer, 2020, 35(7), 1 (in Chinese).
叶学东. 磷肥与复肥, 2020, 35(7), 1.
8 Zhu Z W, He D S, Chen F, et al. Conservation and Utilization of Mine-ral, 2019, 39(4), 19 (in Chinese).
朱志伟,何东升,陈飞,等. 矿产保护与利用, 2019, 39(4), 19.
9 Silva L F O, Oliveira M L S, Crissien T J, et al. Chemosphere, 2022, 286, 131513.
10 Tayibi H, Choura M, López F A, et al. Journal of Environmental Ma-nagement, 2009, 90(8), 2377.
11 Chen X F, Xie E L. Petrochemical Industry Application, 2008(1), 17 (in Chinese).
陈兴福,谢恩良. 石油化工应用, 2008(1), 17.
12 Yu J, Wang L, He H M, et al. Resources Environment & Engineering, 2018, 32(1), 150 (in Chinese).
余军,王磊,贺华明,等. 资源环境与工程, 2018, 32(1), 150.
13 Kacimi L, Simon-Masseron A, Ghomari A, et al. Journal of Hazardous Materials, 2006, 137(1), 129.
14 Da Conceição F T, Bonotto D M. Environmental Pollution, 2006, 139(2), 232.
15 Luther S M, Dudas M J. Journal of Environmental Quality, 1993, 22(1), 103.
16 Taher M A. Resources, Conservation and Recycling, 2007, 52(1), 28.
17 Rentería-Villalobos M, Vioque I, Mantero J, et al. Journal of Hazardous Materials, 2010, 181(1), 193.
18 Hentati O, Abrantes N, Caetano A L, et al. Journal of Hazardous Mate-rials, 2015, 294, 80.
19 Du M X, Wang J M, Dong F Q, et al. Conservation and Utilization of Mineral, 2020, 40(3), 121 (in Chinese).
杜明霞,王进明,董发勤,等. 矿产保护与利用, 2020, 40(3), 121.
20 Chen J Y. Influences on the performance and effective mechanism of phosphogypsum modified with various pretreatment processes. Master's Thesis, Wuhan University of Technology, China, 2012 (in Chinese).
陈嘉懿. 预处理工艺对磷石膏性能的影响及作用机理研究.硕士学位论文,武汉理工大学,2012.
21 Wang J M, Dong F Q, Wang Z J, et al. Physicochemical Problems of Mi-neral Processing, 2020, 56(5), 975.
22 Singh M, Garg M, Verma C L, et al. Construction & Building Materials, 1996, 10(8), 597.
23 Mashifana T P. Procedia Manufacturing, 2019, 35, 641.
24 Ba T B, Xu Y Z, Lu W Y, et al. New Building Materials, 2018, 45(2), 96 (in Chinese).
巴太斌,徐亚中,卢文运,等. 新型建筑材料, 2018, 45(2), 96.
25 Liu D, Wang C, Mei X, et al. Environmental Science and Pollution Research, 2019, 26(29), 30533.
26 Wei X, Zheng G Y, He X Z, et al. Modern Chemical Industry, 2021, 41(9), 101.
魏兴,郑光亚,何宣志,等. 现代化工, 2021, 41(9), 101.
27 Saha A, Lee J, Pancera S M, et al. Langmuir, 2012, 28(30), 11182.
28 Değirmenci N. Construction and Building Materials, 2008, 22(8), 1857.
29 Zhang C Q. Energy Chemical Industry, 2001(3), 18 (in Chinese).
张昌清. 化学工业与工程技术, 2001(3), 18.
30 Hu W L. Study on using modified phosphogypsum as cement retarder. Master's Thesis, Xi'an University of Architecture and Technology, China, 2019 (in Chinese).
胡稳良. 改性磷石膏作为水泥缓凝剂的研究.硕士学位论文,西安建筑科技大学,2019.
31 Hu Y, Gong X M, Zhang H, et al. Development Guide to Building Mate-rials (Part II), 2021, 19(8), 9 (in Chinese).
胡勇,龚小梅,张豪,等. 建材发展导向(下), 2021, 19(8), 9.
32 Shen W, Gan G, Dong R, et al. Journal of Material Cycles and Waste Management, 2012, 14(3), 228.
33 Akın Altun 0, Sert Y. Cement and Concrete Research, 2004, 34(4), 677.
34 Peng Z F, Song X X. Sulphur Phosphorus & Bulk Materials Handling Related Engineering, 2021(1), 35.
彭卓飞,宋小霞. 硫磷设计与粉体工程. 2021(1), 35.
35 Fan W H. Study on phosphogypsum-based building putty and stucco material. Master's Thesis, Chongqing University, China, 2015 (in Chinese).
范文豪. 磷石膏基建筑腻子及粉刷材料的研究.硕士学位论文,重庆大学,2015.
36 Li M, Peng J H, Du Y, et al. Materials Reports, 2010, 24(S1), 436 (in Chinese).
李美,彭家惠,杜勇,等. 材料导报, 2010, 24(S1), 436.
37 He Y X, Wan J D, Hua S D. Environmental Engineering, 2013, 31(S1), 577 (in Chinese).
何玉鑫,万建东,华苏东. 环境工程, 2013, 31(S1), 577.
38 Ma B G, Li Y B, Zhi Z Z, et al.In: The 5th National Conference of Commercial Mortar (5th NCCM). Nanjing, China, 2013, pp. 7 (in Chinese).
马保国,李玉博,郅真真,等. 第五届全国商品砂浆学术交流会(5th NCCM).南京,2013, pp. 7.
39 Shen W, Zhou M, Zhao Q. Construction and Building Materials, 2007, 21(7), 1480.
40 Min C, Li X, He S, et al. Construction and Building Materials, 2019, 210, 564.
41 Amrani M, Taha Y, Kchikach A, et al. Journal of Building Engineering, 2020, 30, 101267.
42 Shen W, Zhou M, Ma W, et al. Journal of Hazardous Materials, 2009, 164(1), 99.
43 Chernysh Y, Yakhnenko O, Chubur V, et al. Applied Sciences-basel, 2021, 11(4), 1575.
44 Silva M V, de Rezende L R, Mascarenha M M D A, et al. Resources, Conservation and Recycling, 2019, 144, 123.
45 Wang C Q, Xu Z Z, Mei X D, et al. Engineering Construction, 2021, 53(1), 69 (in Chinese).
王朝强,徐振中,梅绪东,等. 工程建设, 2021, 53(1), 69.
46 Tian T, Yan Y, Hu Z, et al. Construction and Building Materials, 2016, 115, 143.
47 Yin S Q, Li H, Yin X G, et al. Shandong Chemical Industry, 2018, 47(22), 32 (in Chinese).
尹书琴,李航,尹晓刚,等. 山东化工, 2018, 47(22), 32.
48 Rychkov V N, Kirillov E V, Kirillov S V, et al. Journal of Cleaner Production, 2018, 196, 674.
49 Li X Q, Yuan F Y, Yang W H, et al. Phosphate & Compound Fertilizer, 2014, 29(1), 63 (in Chinese).
李秀芹,袁凤英,杨位红,等. 磷肥与复肥, 2014, 29(1), 63.
50 Gaustad G, Williams E, Leader A. Resources, Conservation and Recycling, 2021, 167, 105213.
51 Ou Y. The research of occurrence state of rare-earth element in typical western Szechuan phosphate ore deposit. Master's Thesis, Chengdu University of Technology, China, 2015 (in Chinese).
欧洋. 川西典型磷矿床中稀土元素的赋存状态研究.硕士学位论文,成都理工大学,2015.
52 Walawalkar M, Nichol C K, Azimi G. Hydrometallurgy, 2016, 166, 195.
53 Antonick P J, Hu Z, Fujita Y, et al. The Journal of Chemical Thermodynamics, 2019, 132, 491.
54 Cánovas C R, Chapron S, Arrachart G, et al. Journal of Cleaner Production, 2019, 219, 225.
55 Jarosiński A, Kowalczyk J, Mazanek C. Journal of Alloys and Compounds, 1993, 200(1), 147.
22010110-1156 Preston J S, Cole P M, Craig W M, et al. Hydrometallurgy, 1996, 41(1), 1.
57 Preston J S, DU Preez A C. Mineral Processing and Extractive Metallurgy Review, 1998, 18(2), 175.
58 Al-Thyabat S, Zhang P. Hydrometallurgy, 2015, 153, 30.
59 Hammas-Nasri I, Horchani-Naifer K, Férid M, et al. Minerals Enginee-ring, 2019, 132, 169.
60 Hammas-Nasri I, Horchani-Naifer K, Férid M, et al. International Journal of Mineral Processing, 2016, 149, 78.
61 Masmoudi-Soussi A, Hammas-Nasri I, Horchani-Naifer K, et al. Hydrometallurgy, 2020, 191, 105253.
62 Virolainen S, Repo E, Sainio T. Hydrometallurgy, 2019, 189, 105125.
63 Kurkinen S, Virolainen S, Sainio T. Hydrometallurgy, 2021, 201, 105569.
64 Jalali J, Gaudin P, Ammar E, et al. Journal of Hazardous Materials, 2020, 399, 122821.
65 Degirmenci N. Construction and Building Materials, 2008, 22(6), 1220.
66 Tian T, Zhang C, Zhu F, et al. Transactions of Nonferrous Metals Society of China, 2021, 31(5), 1484.
67 Xu J J, Zhang N M. Phosphate & Compound Fertilizer, 2017, 32(9), 34 (in Chinese).
许敬敬,张乃明. 磷肥与复肥, 2017, 32(9), 34.
68 Zhang L F, Hu H L. Guizhou Agricultural Science, 2020, 48(8), 40 (in Chinese).
张丽芳,胡海林. 贵州农业科学, 2020, 48(8), 40.
69 Fu Q Q, Shen Y H, Gao L Y. Fertilizer & Health, 2020, 47(6), 21 (in Chinese).
付强强,沈彦辉,高璐阳. 肥料与健康, 2020, 47(6), 21.
70 Han K F, Chen Y P, Hu T J, et al. Acta Agriculturae Zhejiangensis, 2018, 30(1), 117 (in Chinese).
韩科峰,陈余平,胡铁军,等. 浙江农业学报, 2018, 30(1), 117.
71 Ji J H, Li X H, Liu X M, et al. Chinese Journal of Applied Ecology, 2019, 30(2), 583 (in Chinese).
冀建华,李絮花,刘秀梅,等. 应用生态学报, 2019, 30(2), 583.
72 Fan W J, Yang L, Lin H T, et al. Shandong Agricultural Science, 2017, 49(9), 114 (in Chinese).
范文静,杨力,林海涛,等. 山东农业科学, 2017, 49(9), 114.
73 Gao W S, Cui X F, Qin X, et al. Deciduous Fruits, 2017, 49(3), 6 (in Chinese).
高文胜,崔秀峰,秦旭,等. 落叶果树, 2017, 49(3), 6.
74 Song X Z, Lin H T, Zhang Y F, et al. Shandong Agricultural Science, 2015, 47(12), 49 (in Chinese).
宋效宗,林海涛,张玉凤,等. 山东农业科学, 2015, 47(12), 49.
75 Gao W S, Qin Xu, Hu Z P, et al. Journal of Agriculture, 2017, 7(6), 63 (in Chinese).
高文胜,秦旭,胡兆平,等. 农学学报, 2017, 7(6), 63.
76 Li F L, Zhang Q, Wang H P, et al. Chinese Agricultural Science Bulletin, 2018, 34(6), 39 (in Chinese).
栗方亮,张青,王煌平,等. 中国农学通报, 2018, 34(6), 39.
77 Li F L, Zhang Q, Wang L M, et al. Fujian Journal of Agricultural Sciences, 2017, 32(7), 768 (in Chinese).
栗方亮,张青,王利民,等. 福建农业学报, 2017, 32(7), 768.
78 Tu Y T, Peng Z P, Huang J C, et al. China Agricultural Science Bulletin, 2019, 35(4), 40 (in Chinese).
涂玉婷,彭智平,黄继川,等. 中国农学通报, 2019, 35(4), 40.
79 Zhan Z Y, Gu S F, Zhan C Y. Environmental Protection and Circular Economy, 2021, 41(3), 61 (in Chinese).
展争艳,顾生芳,展成业. 环境保护与循环经济, 2021, 41(3), 61.
80 Mao S Y, Wei Z X. Agricultural Science-Technology and Information, 2018(4), 30 (in Chinese).
毛森煜,魏周秀. 农业科技与信息, 2018(4), 30.
81 Zhang X D, Li B, Liu G M, et al. Chinese Journal of Eco-Agriculture, 2019, 27(11), 1744 (in Chinese).
张晓东,李兵,刘广明,等. 中国生态农业学报(中英文), 2019, 27(11), 1744.
82 Jiang H H. Saline-alkali soil remediation by the combined application of halotolerant phosphate solubilizing microorganism and rock phosphate. Ph.D. Thesis, Harbin Institute of Technology, China, 2019 (in Chinese).
姜焕焕. 耐盐碱解磷菌与磷石膏联用改良盐碱土的效果与机制.博士学位论文,哈尔滨工业大学,2019.
83 Xu E B, Lu D, Wei L. In:"Environmental Engineering" 2018 National Academic Annual Conference. Beijing, China, 2018, pp. 3 (in Chinese).
徐恩兵,路丁,韦雷.磷石膏和过磷酸钙对盐碱土的改良效果研究:《环境工程》2018年全国学术年会,中国北京,2018, pp. 3.
84 Sun X B. Study on preparation of structure and morphology of calcium sulfate hemihydrate based on phosphogypsum calcium sulfate dihydrate. Ph.D. Thesis, Hefei University of Technology, China, 2020 (in Chinese).
孙祥斌. 基于磷石膏二水硫酸钙制备结构形貌可控半水硫酸钙的研究.博士学位论文,合肥工业大学,2020.
85 Kuttah D, Sato K. Transportation Geotechnics, 2015, 4, 28.
86 Huang Y. Characteristics of heavy metal pollution for soil around phosphogypsum storage yard and study on agricultural application of phosphogypsum. Master's Thesis, Nanchang University, China, 2017 (in Chinese).
黄尧. 磷石膏堆场周边土壤重金属污染特征及磷石膏农用资源化研究.硕士学位论文,南昌大学,2017.
87 Wang X B, Yan X, Li X Y, et al. Scientia Agricultura Sinica, 2019, 52(2), 293 (in Chinese).
王小彬,闫湘,李秀英,等. 中国农业科学, 2019, 52(2), 293.
88 De Castro Pias O H, Tiecher T, Cherubin M R, et al. Agronomy Journal, 2020, 112(2), 675.
89 Li M, Liang H, Sui J F, et al. Phosphate & Compound Fertilizer, 2020, 35(7), 30 (in Chinese).
李铭,梁欢,随婕斐,等. 磷肥与复肥, 2020, 35(7), 30.
90 Du Q, Du C, Jin G Y, et al. Chinese Journal of Tissue Engineering Research, 2017, 21(22), 3541 (in Chinese).
杜倩,杜琛,金贵玉,等. 中国组织工程研究, 2017, 21(22), 3541.
91 Davood K, Debarun D, Kitty K K H, et al. Cellulose, 2020, 27(11), 3319.
92 Shang L, Gao X, Hu Z C, et al. Guizhou Chemical Industry, 2011, 36(2), 3 (in Chinese).
尚雷,高翔,胡宗超,等. 贵州化工, 2011, 36(2), 3.
93 Zhang T T, Wei K B, Zhang Y F, et al. Acta Materiae Compositae Sinica, 2012, 29(2), 79 (in Chinese).
张婷婷,魏克冰,张云飞,等. 复合材料学报, 2012, 29(2), 79.
94 Jin H, Min S, Song Y, et al. Polymer Degradation and Stability, 2010, 95(9), 1856.
95 Varadavenkatesan T, Vinayagam R, Pai S, et al. Progress in Organic Coatings, 2021, 151, 106056.
96 Ma X L, Tan H B, Hou X, et al. New Building Materials, 2021, 48(3), 71 (in Chinese).
马小玲,谭宏斌,侯雄,等. 新型建筑材料, 2021, 48(3), 71.
97 He D S, Zhang Z Q, Zhang H Q, et al. Journal of Wuhan Institute of Technology, 2011, 33(3), 12 (in Chinese).
何东升,张泽强,张汉泉,等. 武汉工程大学学报, 2011, 33(3), 12.
98 Wu Y L. Technology & Development of Chemical Industry, 2012, 41(6), 41 (in Chinese).
吴雨龙. 化工技术与开发, 2012, 41(6), 41.
99 He R L. Sulphuric Acid Industry, 2018(8), 21 (in Chinese).
何润林. 硫酸工业, 2018(8), 21.
100 Li M G, Chen S L, Lei B. Guangzhou Chemical Industry, 2020, 48(17), 15 (in Chinese).
李茂刚,陈仕林,雷波. 广州化工, 2020, 48(17), 15.
101 Luo B, Chen Q J. Popular Standardization, 2019(11), 35 (in Chinese).
罗冰,陈秋菊. 大众标准化, 2019(11), 35.
102 Cárdenas-Escudero C, Morales-Flórez V, Pérez-López R, et al. Journal of Hazardous Materials, 2011, 196, 431.
103 Contreras M, Pérez-López R, Gázquez M J, et al. Waste Management, 2015, 45, 412.
104 Yang J, Ma L, Zheng D, et al. Energy & Fuels, 2018, 32(7), 7857.
105 Yang J, Wei Y, Yang J, et al. Energy, 2019, 168, 126.
106 Zhang W, Zhang F, Ma L, et al. Journal of Cleaner Production, 2020, 259, 120826.
107 Ding W, Chen Q, Sun H, et al. Journal of CO2 Utilization, 2019, 34, 507. |
|
|
|
渝公网安备50019002502923号 © Editorial Office of Materials Reports.
2023, Vol. 37 
