聚苯乙烯/α-磷酸锆多孔材料制备及油水乳液分离研究

doi:10.11896/cldb.21110076

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Abstract Hydrophobic andlipophilic porous materials have the ability to treat and purify oil-bearing wastewater. In this work, polystyrene (PSt) based three-dimensional porous materials (P(St-E)/α-ZrP) were prepared by high internal emulsion template method. Microstructure of the prepared materials were characterized by scanning electron microscope (SEM) and automatic mercury injection instrument. Meanwhile, their oil-water separation performance was tested and analyzed. The results showed that layered nanoparticles α-ZrP was stabilized in the dispersed phase of water in oil emulsion. After polymerization of monomers, α-ZrP inlayed on the skeleton of porous material to form a rough interface. The porous material had the best mechanical and hydrophobic properties with 5% α-ZrP incorporation. The adsorption rate of trichlormethane for P(St-E)/α-ZrP5 was as high as 54.2. P(St-E)/α-ZrP porous materials can efficiently separate non-ionic and cationic stabled oil-water emulsion because of the synergistic effects of size selecting effect and electronegativity of α-ZrP. The porous materials prepared in this work are expected to be used in the purification of wastewater containing emulsified oil, and have broad development prospects in the treatment of oil-bearing wastewater.

Key words： oil-water emulsion α-ZrP polystyrene concentrated emulsion template porous material

Published: 25 August 2023 Online: 2023-08-14

CLC number:

TB34

Fund:Sichuan Provincial Science and Technology Plan Project(2022NSFSC0301).

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	Articles by authors
	HUANG Shijie
	ZHAO Chunxia
	WANG Shuo
	HUANG Haoran
	LI Jiaxin
	LI Hui
	XIANG Dong
	LI Yuntao

Cite this article:

HUANG Shijie,ZHAO Chunxia,WANG Shuo, et al. Preparation of Polystyrene/α-Zirconium Phosphate Porous Materials and Separation of Oil-Water Emulsion[J]. Materials Reports, 2023, 37(16): 21110076-9.

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http://www.mater-rep.com/EN/10.11896/cldb.21110076 OR http://www.mater-rep.com/EN/Y2023/V37/I16/21110076

1 Wang Q J. Applied Mechanics and Materials, 2014, 556, 603.
2 Fu L P, Zhang G C, Ge J J, et al. Colloids and Surfaces A: Physicoche-mical and Engineering Aspects, 2016, 508, 230.
3 Du B, Chen F, Luo R B, et al. ACS Omega, 2019, 4(15), 16508.
4 Liu N, Cao Y Z, Lin X, et al. ACS Applied Materials Interfaces, 2014, 6(15), 12821.
5 Liu Y, Xia M, Wu L L, et al. Industrial & Engineering Chemistry Research, 2019, 58(47), 21649.
6 Guo H S, Yang J, Xu T, et al. ACS Applied Materials & Interfaces, 2019, 11(14), 13704.
7 Greaves D, Boxall J, Mulligan J, et al. Chemical Engineering Science, 2008, 63(18), 4570.
8 Xu C, Yan F, Wang M X, et al. Journal of Membrane Science, 2020, 602, 117974.
9 Liu S Z, Zhang Y, Fan L Q, et al. Materials Reports, 2020, 34(9), 17099(in Chinese).
刘帅卓, 张颖, 范雷倚, 等.材料导报, 2020, 34(9), 17099.
10 Yuan Z S, Ke Z W, Qiu Y H, et al. ACS Applied Materials Interfaces, 2020, 12(41), 46923.
11 Deng X, Zhang J S, Zhang L R, et al. Industrial & Engineering Chemistry Research, 2020, 59(14), 6672.
12 Xu L G, Chen Y N, Liu N, et al. ACS Applied Materials Interfaces, 2015, 7(40), 22264.
13 Deng S Q, Zhao C X, Zhu L B, et al.Journal of Applied Polymer Science, 2021, 139(3),51521.
14 Chen C L, Weng D, Mahmood A, et al. ACS Applied Materials Interfaces, 2019, 11(11), 11006.
15 Azhar U, Huyan C X, Wan X Z, et al. Arabian Journal of Chemistry, 2019, 12(4), 559.
16 Wang H J, Wang W Y, Wang H, et al. Materials Reports, 2017, 31(10), 144(in Chinese).
王洪杰, 王闻宇, 王赫, 等.材料导报, 2017, 31(10), 144.
17 Wang M, Li X. Materials Reports, 2018, 32(4), 1236(in Chinese).
王明, 李星. 材料导报, 2018, 32(4), 1236.
18 Huang Y, Xiao C F, Huang Q L, et al. Journal of Membrane Science, 2018, 568, 87.
19 Cheng X Q, Jiao Y, Sun Z K, et al. ACS Nano, 2021, 15(2), 3500.
20 Kang L, Shi L J, Zeng Q, et al. Separation and Purification Technology, 2021, 279, 119737.
21 Raza A, Ding B, Zainab G, et al. Journal of Materials Chemistry A, 2014, 2(26), 10137.
22 Lin X, Heo J, Jeong H, et al.Journal of Materials Chemistry A, 2016, 4(46), 17970.
23 Lei L, Zhang Q, Shi S X, et al. Langmuir, 2017, 33(43), 11936.
24 Jia X, Sun Z G, Guan C L, et al.Chinese Journal of Colloid & Polymer, 2014, 32(3),141(in Chinese).
贾雪, 孙争光, 官成兰, 等. 胶体与聚合物, 2014, 32(3), 141.
25 Fan X, Fan P, Li S D, et al.Polymer Materials Science & Engineering, 2018, 34(4), 185(in Chinese).
范欣, 范平, 李松栋, 等. 高分子材料科学与工程, 2018, 34(4), 185.
26 Yu C M, Zeng S W, Liu Y Y, et al.Materials Reports, 2021, 35(4),4200(in Chinese).
余传明, 曾圣威, 刘叶原,等. 材料导报, 2021, 35(4), 4200.
27 Guan X, Ngai T. Langmuir, 2021, 37(8), 2843.
28 Sam E K, Liu J, Lv X M. Industrial & Engineering Chemistry Research, 2021, 60(6), 2353.
29 Du J C, Zhang C Y, Pu H, et al. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2019, 573,222.
30 Li S L, Zhao C X, Gou H L, et al.International Journal of Electrochemical Science, 2018, 13, 2661.
31 Bashir A, Ahad S, Malik L A, et al.Industrial & Engineering Chemistry Research, 2020, 59(52), 22353.
32 Yu S L, Xiang H X, Zhou J L, et al. Fibers and Polymers, 2018, 19(4), 812.
33 He J M, Zhang Y, Wang J, et al. Journal of Materials Science, 2020, 55(15), 6708.