危废处理超临界水氧化环境中装置材料腐蚀的研究进展

doi:10.11896/cldb.21100176

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Abstract Supercritical water oxidation technology for waste treatment has the characteristics of high removal efficiency, short residence time and no pollutant and by-products, but because of its harsh reaction conditions, corrosion problems of equipment urgently need to be solved. Especially when the reaction environment is acidic and the reaction materials contain halogen elements, the corrosion is extremely serious. At present, nickel base alloy, titanium alloy, stainless steel and other alloy materials are mainly used to manufacture reactors, but overall and local corrosion is still prone to occur, and may cause reactor leakage or even explosion in serious cases. Therefore, in recent years, researchers have carried out in-depth analysis on the corrosion behavior of different alloys in different types of supercritical water oxidation environment, and then put forward effective protection measures.In this paper, the corrosion behavior and mechanism of nickel base alloy and titanium alloy in acidic solution containing chloride ion, sulfuric acid solution and phosphoric acid solution, as well as stainless steel in acidic solution containing chloride ion and H₂O₂ solution under subcritical and supercritical conditions are summarized. The occurrence of overall corrosion, pitting corrosion, intergranular corrosion and stress corrosion cracking at different temperature zones and reactor locations are summarized. Corrosion protection measures such as liner and coating used in supercritical water oxidation (SCWO) environment of hazardous waste treatment are reviewed. Finally, the development prospect of improving corrosion resistance of superfine alloy materials by surface nanocrystalline technology is prospected.

Key words： supercritical water oxidation corrosion resistant alloy corrosion behavior protection measure high temperature and high pressure

Published: 25 April 2023 Online: 2023-04-24

CLC number:

TB304

Fund:National Natural Science Foundation of China (51601138, 51601137).

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	Articles by authors
	CHEN Siyu
	ZHANG Xian
	LI Teng
	LIU Jing
	WU Kaiming

Cite this article:

CHEN Siyu,ZHANG Xian,LI Teng, et al. Research Progress on Corrosion Behavior of Reactor Plant Materials in Supercritical Water Oxidation Environment of Hazardous Waste Treatment[J]. Materials Reports, 2023, 37(8): 21100176-7.

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http://www.mater-rep.com/EN/10.11896/cldb.21100176 OR http://www.mater-rep.com/EN/Y2023/V37/I8/21100176

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