用于CO2催化加氢In2O3基催化剂的研究进展

doi:10.11896/cldb.21050185

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Abstract Alarge amount of carbon dioxide (CO₂) emitted by humans into the atmosphere has caused many environmental problems and dramatically threatens humankind’s survival. CO₂ catalytic hydrogenation has unique advantages among many CO₂ reduction strategies. The conversion of CO₂ and hydrogen (H₂) into high value-added chemicals has good prospects for application, both in reducing atmospheric CO₂ concentrations and producing economically valuable commodities.
In recent years, indium oxide (In₂O₃) catalysts have received much attention in the academic community as a new and efficient catalyst for the CO₂ hydrogenation to methanol. After activation, the In₂O₃ surface generates a large number of oxygen vacancies, which are periodically generated and annihilated, that inhibit the occurrence of side reactions and hydrogenates CO₂ to methanol with high selectivity. It was reported in the literature that In₂O₃ had a methanol selectivity close to 100% at 200—300 ℃. Especially at higher temperatures, the relatively high methanol selectivity was still maintained. This excellent performance at high temperatures allows In₂O₃ to be used in coupling with zeolite to design bifunctional catalysts for the CO₂ catalytic hydrogenation directly to hydrocarbons.
The drawback of In₂O₃ catalysts is that their low CO₂ conversion limits the methanol yield. The academic community has adopted several strategies to optimize the In₂O₃-based catalysts. There are two main strategies: (1) loading In₂O₃ onto other oxide supports and (2) introducing other metal elements into the In₂O₃ system. Loading In₂O₃ onto other oxide supports can increase the dispersion of In₂O₃ species, increase the content of oxygen vacancies, enhance the ability to adsorb CO₂, and stabilize key intermediate species. Loading In₂O₃ onto ZrO₂ is a typical example of this strategy, which can significantly enhance the intrinsic activity of the catalyst. The introduction of other metallic elements into the In₂O₃ can enhance H₂ dissociative adsorption and H₂ spillover. The introduction of metals such as Pd, Pt, Cu, Rh, Au, Co, and Ni into the In₂O₃ has been reported in the literature with good results.
This review summarized the research advances of In₂O₃-based catalysts for CO₂ hydrogenation, reviewed the structure of In₂O₃, the current status of In₂O₃ for CO₂ hydrogenation, and the design and improvement of new In₂O₃-based catalysts for CO₂ hydrogenation, and provided an outlook on the research ideas and development prospects of In₂O₃-based catalysts for CO₂ hydrogenation, to provide thoughts and references for the future research of In₂O₃ catalytic systems for CO₂ hydrogenation.

Key words： carbon dioxide hydrogenation methanol hydrocarbon indium (Ⅲ) oxide oxygen vacancies hydrogen spillover

Published: 30 November 2021

CLC number:

O643

Fund:National Natural Science Foundation of China (21878116) and Natural Science Foundation of Hubei Province (2019CFA070).

About author:: Longtai Li graduated from Huazhong University of Science and Technology with a B.E. degree in June 2018. He is now a master's student in the School of Environmental Science and Engineering at Huazhong University of Science and Technology, researching under the supervision of Prof. Limin Guo. His current main research area is CO₂ catalytic hydrogenation.
Limin Guo is a professor in the School of Environmental Science and Engineering of Huazhong University of Science and Technology, and an adjunct professor in the China Europe Institute of Clean and Renewable Energy, mainly engaged in applied basic research on adsorption/catalyst preparation, VOCs adsorption/catalytic combustion elimination, CO₂ catalytic hydrogenation, etc. In recent years, he has undertaken more than 20 projects such as the National Natural Science Foundation of China, National Key Research and Development Program, Japan Society for the Promotion of Science, Hubei Outstanding Young Talents Program, National/Provincial Key Laboratory Open Fund, Kyushu University of Japan, and horizontal projects of enterprises. He is currently a member of the sub-committee on Environmental Materials of the Chinese Society for Materials
Research, the vice chairman of the Youth Working Committee of the Hubei Environmental Science Society, and a member of the Youth Editorial Board of Chinese Chemical Letters.
Bin Yang received his Ph.D. degree from School of Environmental Science and Engineering of Huazhong University of Science and Technology in 2020. Then he joined School of Chemistry and Material Science in Hangzhou Institute for Advanced Study as postdoctoral researcher. He is interested in designing and synthesizing novel metal oxides for chemical conversion of carbon dioxide.

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	LI Longtai
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Cite this article:

LI Longtai,ZHANG Chunjie,LUO Xuebin, et al. Recent Advances in In₂O₃-based Catalysts for CO₂ Hydrogenation[J]. Materials Reports, 2021, 35(21): 21071-21078.

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http://www.mater-rep.com/EN/10.11896/cldb.21050185 OR http://www.mater-rep.com/EN/Y2021/V35/I21/21071

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