Materials Reports 2020, Vol. 34 Issue (Z2): 338-343 |
METALS AND METAL MATRIX COMPOSITES |
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Research Progress on the Nanophase Diagram of Au-Pt-Ni Catalyst System |
HU Jieqiong, XIE Ming, CHEN Yongtai, YANG Youcai, FANG Jiheng, FAN Xiaotong, LI Aikun
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State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals, Kunming Institute of Precious Metals, Kunming 650106, China |
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Abstract Au-Pt-Ni system has a strong application background as a fuel cell catalyst. The research on the establishment of nanophase diagram of the Au-Pt-Ni system will provide deeper understanding of the synthesis procedure and stability pattern of the nanocatalyst, along with the diagram of phase equilibrium between the different components at nanoscale. Meanwhile, the synergistic effect of multi-metals on the formation mechanism of nanocatalyst will be illuminated, so as to provide the theoretical insight for design and development of the new types of precious metal based nanocatalyst for direct alcohol fuel cells. However, the research on nanophase diagram is still limited, which limits the design and development of new precious metal alloy catalysts with high activity, stability, anti poisoning and low cost. This manuscript summarizes the research progress of bulk and nanophase diagram of the Au-Pt-Ni system at home and abroad and evaluates the collected thermodynamic parameters of the system, in order to make better use of new types of precious metal based nanocatalyst for direct alcohol fuel cells.
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Published: 08 January 2021
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Fund:This work was financially supported by the National Natural Science Foundation of China (51961016), Yunnan Key Research and Development Program (2019ZE001-1;202002AB080001-1), the National Major Science and Technology Projects of China (2017YFB0305700), National Natural Science Foundation of China Yunnan Joint Fund (U1602271, U1602275), Applied Basic Research Foundation of Yunnan Province (2018FB088). |
About author:: Jieqiong Hu, a senior engineer, graduated from Kunming Institute of Precious Metals with a master's degree in materials science in May 2012. She mainly engaged in construction the phase diagram and thermodynamic database of precious metals alloy. She has published more than 20 research papers as the first author, applied for 19 national invention patents, and authorized one patent as the first inventor, participated in the written of national military standards. She has won 3 provincial awards, hosted and participated in 10 national and provincial major projects, among them hosted 3 projects. Ming Xie, doctoral tutor, researcher. He was awarded the “Special Allowance” by the State Council Government and the “Yunling Scholar” in Yunnan Province. Hosted and participated in the completion of more than 50 major scientific and technological projects such as the national “Eighth Five-Year” scientific and technological research, 863 Plan, National Science and Technology Support Plan, National Foundation Key Projects (NSFC-Yunnan Joint Fund), National Key Military Industry, Ministry of Industry and Information Technology Strong Foundation Project, 2017 national key research and development plan and so on. He has won more than 20 national, provincial and ministerial scientific and technological progress awards (among them there are 3 first prizes), and 1 first prize of Yunnan Science and Technology Progress Science and Technology Innovation Team; more than 40 national invention patents, and more than 200 academic papers published in influential academic journals and conferences at home and abroad. Among them, more than 80 articles were included in SCI and EI; more than 10 national military standards, national standards and enterprise standards were written, and he participated in the writing of Handbook of Powder Metallurgy, Encyclopedia of Materials, Application Manual for Electrical Alloy Pro-ducts, etc. |
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